1,1-diallyl-2,3,4,5-tetraphenylsilole | 944724-19-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1,1-diallyl-2,3,4,5-tetraphenylsilole
• 英文别名: 2,3,4,5-Tetraphenyl-1,1-bis(prop-2-enyl)silole；2,3,4,5-tetraphenyl-1,1-bis(prop-2-enyl)silole
• CAS: 944724-19-0
• 化学式: C₃₄H₃₀Si
• 分子量: 466.698
• InChiKey: KBCRYCHIGPAGEG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.12
• 重原子数：
  35
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,1-diallyl-2,3,4,5-tetraphenylsilole 在 dihydrogen hexachloroplatinate 三氯硅烷 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Highly luminescent glycocluster: silole-core carbosilane dendrimer having peripheral globotriaose

  摘要：

  A novel glycocluster periphery functionalized by globotriaose (Ga1 sigma 1-4Ga1 beta 1-4Gc beta 1- ) possessing a silole moiety as a luminophor was synthesized. The photoluminescence spectrum of the glycocluster in pure water showed extremely strong emission at 475 nm. Analogous intense emission of the silole dendrimer was also observed in a lower water fraction of water/acetone mixture. The water fraction of the silole dendrimer solution strongly affected the emission intensity; however, these luminescences were constantly detected at around 475 nm. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.04.100
• 作为产物：
  描述：

  二苯基乙炔 在 lithium 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 反应 8.0h， 生成 1,1-diallyl-2,3,4,5-tetraphenylsilole
  参考文献：
  名称：

  Highly luminescent glycocluster: silole-core carbosilane dendrimer having peripheral globotriaose

  摘要：

  A novel glycocluster periphery functionalized by globotriaose (Ga1 sigma 1-4Ga1 beta 1-4Gc beta 1- ) possessing a silole moiety as a luminophor was synthesized. The photoluminescence spectrum of the glycocluster in pure water showed extremely strong emission at 475 nm. Analogous intense emission of the silole dendrimer was also observed in a lower water fraction of water/acetone mixture. The water fraction of the silole dendrimer solution strongly affected the emission intensity; however, these luminescences were constantly detected at around 475 nm. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.04.100

文献信息

• Highly luminescent glycocluster: silole-core carbosilane dendrimer having peripheral globotriaose
  作者：Ken Hatano、Hiroaki Aizawa、Hiroo Yokota、Akihiro Yamada、Yasuaki Esumi、Hiroyuki Koshino、Tetsuo Koyama、Koji Matsuoka、Daiyo Terunuma

  DOI：10.1016/j.tetlet.2007.04.100

  日期：2007.6

  A novel glycocluster periphery functionalized by globotriaose (Ga1 sigma 1-4Ga1 beta 1-4Gc beta 1- ) possessing a silole moiety as a luminophor was synthesized. The photoluminescence spectrum of the glycocluster in pure water showed extremely strong emission at 475 nm. Analogous intense emission of the silole dendrimer was also observed in a lower water fraction of water/acetone mixture. The water fraction of the silole dendrimer solution strongly affected the emission intensity; however, these luminescences were constantly detected at around 475 nm. (c) 2007 Elsevier Ltd. All rights reserved.