N-(2-vinyloxyethyl)-N'-cyclohexylidene-1,2-ethylenediamine | 1235452-83-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(2-vinyloxyethyl)-N'-cyclohexylidene-1,2-ethylenediamine
• 英文别名: N-cyclohexylidene-N'-(2-vinyloxyethyl)ethane-1,2-diamine；2-(cyclohexylideneamino)-N-(2-ethenoxyethyl)ethanamine
• CAS: 1235452-83-1
• 化学式: C₁₂H₂₂N₂O
• 分子量: 210.319
• InChiKey: RLUHBYQEIOUKAT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  33.6
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N-(2-vinyloxyethyl)-1,2-ethylenediamine 、 环己酮 以 苯 为溶剂， 以83%的产率得到N-(2-vinyloxyethyl)-N'-cyclohexylidene-1,2-ethylenediamine
  参考文献：
  名称：

  Condensation of N-(2-vinyloxyethyl)ethane-1,2-diamine with carbonyl compounds

  摘要：

  Condensation of N-(2-vinyloxyethyl)ethane-1,2-diamine with aromatic aldehydes gave mixtures of 2-aryl-1-(2-vinyloxyethyl)imidazolidines and N-arylmethylidene-N'-(2-vinyloxyethyl)ethane-1,2-diamines in an overall yield of 79-84%, while analogous condensation with cyclic and acyclic ketones resulted in the formation of only the corresponding Schiff bases (yield 53-83%).

  DOI：

  10.1134/s107042801004007x

文献信息

• Anticorrosion properties of products of N-(2-Vinyloxyethyl)-1,2-ethylenediamine condensation with carbonyl compounds
  作者：B. F. Kukharev、V. K. Stankevich、G. R. Klimenko、N. A. Lobanova、E. N. Kovalyuk、A. Yu. Negoda、V. V. Stankevich、E. V. Bragin

  DOI：10.1134/s1070427210090302

  日期：2010.9

  N-(2-Vinyloxyethyl)-N'-cyclohexylidene-1,2-ethylenediamine and N,N',N"-tris-[2-(2-vinyloxyethyl)aminoethyl]hexahydro-1,3,5-triazine were synthesized by reactions of N-(2-vinyloxyethyl)-1,2-ethylenediamine with cyclohexanone and formaldehyde with yields of 91 and 90%, respectively. The IR and (1)H and (13)C NMR spectral data and the results of studying their anticorrosion properties are given.