1,1'-(naphthalene-1,7-diylbis(oxy))bis(N,N,N',N'-tetraethylphosphanediamine) | 863650-18-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,1'-(naphthalene-1,7-diylbis(oxy))bis(N,N,N',N'-tetraethylphosphanediamine)
• CAS: 863650-18-4
• 化学式: C₂₆H₄₆N₄O₂P₂
• 分子量: 508.624
• InChiKey: WEMWBMSHCNWZEE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.42
• 重原子数：
  34.0
• 可旋转键数：
  16.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  31.42
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  1,1'-(naphthalene-1,7-diylbis(oxy))bis(N,N,N',N'-tetraethylphosphanediamine) 在 sulfur 作用下， 以 乙腈 为溶剂， 反应 1.5h， 生成 1,7-bis(tetraethyldiaminothiophosphoryloxy)naphthalene
  参考文献：
  名称：

  Cyclobisphosphorylation of 1,7-Dihydroxynaphthalene with Phosphorous Triamides

  摘要：

  Cyclobisphosphorylation of dihydroxynaphthalenes was studied with the aim to prepare organophosphorus aromatic compounds containing intramolecular cavities. The design and the structural and chemical features of cyclobisphosphites prepared from unsymmetrical 1,7-dihydroxynaphthalene are considered. New data are reported on regioselective cyclophosphorylation of 1,7-dihydroxynaphthalene by disproportionation of its bis(diamidophosphorylated) derivatives.

  DOI：

  10.1023/b:rugc.0000025169.12605.2e
• 作为产物：
  描述：

  1,7-二羟基萘 、 六乙基亚磷酸胺 以 乙腈 为溶剂， 生成 1,1'-(naphthalene-1,7-diylbis(oxy))bis(N,N,N',N'-tetraethylphosphanediamine)
  参考文献：
  名称：

  Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use

  摘要：

  The dismutation ofarylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined.

  DOI：

  10.1134/s1070363206020046

文献信息

• Phosphomacrocyclic systems based on 2,2′-dihydroxy-1,1′-dinaphtylmethane
  作者：P. V. Slitikov、E. N. Rasadkina、Ya. A. Korunova、L. K. Vasyanina、E. E. Nifant’ev

  DOI：10.1134/s1070363210050099

  日期：2010.5

  For the first time phosphomacrocyclic systems were synthesized based on 2,2'-dihydroxy-1,1'-dinaphthylmethane, other aromatic diols, and phosphorous hexaethyltriamide. Spontaneous transformation of the obtained macrocycles into the more stable 1,3,2-dioxaphosphacyn and cyclobisamidophosphite was established.