cyclo-O,O-[bis(naphthalene-1,7-diyl diethylamidothiophosphate)]

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: cyclo-O,O-[bis(naphthalene-1,7-diyl diethylamidothiophosphate)]
• 英文别名: 3-N,3-N,14-N,14-N-tetraethyl-3,14-bis(sulfanylidene)-2,4,13,15-tetraoxa-3lambda5,14lambda5-diphosphapentacyclo[14.6.2.25,8.07,12.019,23]hexacosa-1(22),5,7,9,11,16(24),17,19(23),20,25-decaene-3,14-diamine；3-N,3-N,14-N,14-N-tetraethyl-3,14-bis(sulfanylidene)-2,4,13,15-tetraoxa-3λ5,14λ5-diphosphapentacyclo[14.6.2.25,8.07,12.019,23]hexacosa-1(22),5,7,9,11,16(24),17,19(23),20,25-decaene-3,14-diamine
• 化学式: C₂₈H₃₂N₂O₄P₂S₂
• 分子量: 586.653
• InChiKey: ZUPYGYBQEOXNJN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.2
• 重原子数：
  38
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  108
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  1,7-二羟基萘 在 sulfur 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 反应 4.0h， 生成 cyclo-O,O-[bis(naphthalene-1,7-diyl diethylamidothiophosphate)]
  参考文献：
  名称：

  摘要：

  DOI：

  10.1023/a:1011392017095

文献信息

• Cyclo[bis(1,7-naphthylenedialkylamidophosphites)]
  作者：Eduard E. Nifantyev、Elena N. Rasadkina、Yuliya B. Evdokimova、Adam I. Stash、Vitaly K. Belsky、Larisa K. Vasyanina

  DOI：10.1002/hc.10143

  日期：——

  The possibility of regioselective cyclobisphosphorylation of nonsymmetrical bisphenols was shown for the 1,7-dihydroxynaphthalene–phosphorous acid triamide system. The structure and essential chemical properties of the first nonsymmetrical phosphacyclophane were studied. New data demonstrating peculiar features of bisphenol diamidophosphites were obtained. © 2003 Wiley Periodicals, Inc. Heteroatom

  1,7-二羟基萘-亚磷酸三酰胺体系显示了非对称双酚区域选择性环双磷酸化的可能性。研究了第一种非对称磷环芳烷的结构和基本化学性质。获得了证明双酚二酰胺亚磷酸酯特殊特征的新数据。© 2003 Wiley Periodicals, Inc. 杂原子化学 14:404–412, 2003; 在线发表于 Wiley InterScience (www.interscience.wiley.com)。DOI 10.1002/hc.10143
• Cyclobisphosphorylation of 1,7-Dihydroxynaphthalene with Phosphorous Triamides
  作者：E. N. Rasadkina、Yu. B. Evdokimenkova、A. I. Stash、V. K. Bel'skii、L. K. Vasyanina、E. E. Nifant'ev

  DOI：10.1023/b:rugc.0000025169.12605.2e

  日期：2004.1

  Cyclobisphosphorylation of dihydroxynaphthalenes was studied with the aim to prepare organophosphorus aromatic compounds containing intramolecular cavities. The design and the structural and chemical features of cyclobisphosphites prepared from unsymmetrical 1,7-dihydroxynaphthalene are considered. New data are reported on regioselective cyclophosphorylation of 1,7-dihydroxynaphthalene by disproportionation of its bis(diamidophosphorylated) derivatives.
• ——
  作者：E. E. Nifantiev、E. N. Rasadkina、Yu. B. Evdokimenkova

  DOI：10.1023/a:1011392017095

  日期：——
• Phosphomacrocyclic systems based on 2,2′-dihydroxy-1,1′-dinaphtylmethane
  作者：P. V. Slitikov、E. N. Rasadkina、Ya. A. Korunova、L. K. Vasyanina、E. E. Nifant’ev

  DOI：10.1134/s1070363210050099

  日期：2010.5

  For the first time phosphomacrocyclic systems were synthesized based on 2,2'-dihydroxy-1,1'-dinaphthylmethane, other aromatic diols, and phosphorous hexaethyltriamide. Spontaneous transformation of the obtained macrocycles into the more stable 1,3,2-dioxaphosphacyn and cyclobisamidophosphite was established.