11-(dimethylamino)undecan-1-ol | 29823-94-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 11-(dimethylamino)undecan-1-ol
• 英文别名: 11-Dimethylamino-undecanol-(1)；dimethyl(11-hydroxyundecyl)amine
• CAS: 29823-94-7
• 化学式: C₁₃H₂₉NO
• 分子量: 215.379
• InChiKey: ZSRFQIXJDFLVKZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  15
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  23.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  11-溴-1-十一醇 、 11-(dimethylamino)undecan-1-ol 以 乙醇 为溶剂， 反应 48.0h， 以85%的产率得到di(11-hydroxyundecyl)dimethylammonium bromide
  参考文献：
  名称：

  表面活性剂包封的多金属氧酸盐作为固定化的超分子催化剂，用于高效和选择性氧化反应

  摘要：

  已经开发出一种基于表面活性剂包裹的多金属氧酸盐的有趣的固定化超分子催化剂，用于氧化反应。通过使用原硅酸四乙酯的溶胶-凝胶工艺，羟基封端的表面活性剂包封的多金属氧酸盐配合物已经共价且均匀地结合在具有不变配合物结构的二氧化硅基质上。形成的杂化催化剂在无机簇周围具有确定的疏水性纳米环境，这有利于多金属氧酸盐催化中心与有机底物之间的相容性。已经发现，在氧化过程中底物吸附，反应和产物解吸之间的超分子协同作用对反应动力学具有明显的影响，催化剂的活性大大提高。超分子催化剂在几种不同种类的有机化合物（如烯烃，醇和硫化物）的选择性氧化中有效发挥作用，主要产物是相应的环氧化物，酮，亚砜和砜。更重要的是，通过简单的过滤就可以容易地回收催化剂，并且催化活性可以保持至少五个循环。最后，本发明的策略已被证明是制备适用于各种目的的含有普通多金属氧酸盐的超分子杂化催化剂的一般途径。通过简单的过滤可以很容易地回收催化剂，并

  DOI：

  10.1002/chem.200902261
• 作为产物：
  描述：

  11-氯-十一烷酸 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 生成 11-(dimethylamino)undecan-1-ol
  参考文献：
  名称：

  Solov'ev,V.M. et al., Journal of general chemistry of the USSR, 1961, vol. 31, # 8, p. 2405 - 2411

  摘要：

  DOI：

文献信息

• Compounds
  申请人：SMITH KLINE & FRENCH LABORATORIES LIMITED

  公开号：EP0402062A2

  公开（公告）日：1990-12-12

  Polymers of structure: in which, n is 0 or 1; m is 1 to 20; Z is H or a group X is 0, S, SO₂, amido or sulphonamido; R¹ and R² are the same or different and are each C₁₋₄alkyl; R³ is C₁₋₂₀alkyl; or R¹ to R³ together with the nitrogen atom to which they are attached form a ring, optionally containing one or more further heteroatoms and optionally substituted by a C₁₋₄alkyl group; a, b and c are numbers which indicate the relative molar percentages of the units present in a random distribution in said polymer, (b) being from about 0.5 to about 10 molar percent, and (c) being from about 30 to about 99 molar percent; and Y⊖ is a physiologically acceptable counter ion, processes for their preparation, pharmaceutical compositions containing them and their use in therapy as cholesterol lowering agents.

  结构聚合物 其中 n 为 0 或 1 m 为 1 至 20； Z 是 H 或一个基团 X 是 0、S、SO₂、氨基或磺酰胺基； R¹ 和 R² 相同或不同，且各自为 C₁₋₄ 烷基； R³ 是 C₁₋₂₀烷基；或 R¹ 至 R³ 与它们所连接的氮原子一起形成一个环，该环任选含有一个或多个杂原子，并任选被一个 C₁₋₄烷基取代； a、b 和 c 是表示在所述聚合物中随机分布的单元的相对摩尔百分比的数字，(b) 约为 0.5 至约 10 摩尔百分比，(c) 约为 30 至约 99 摩尔百分比；以及 Y⊖ 是生理上可接受的反离子、 它们的制备工艺、含有它们的药物组合物以及它们在治疗中作为降胆固醇剂的用途。
• CURABLE LIQUID DEVELOPER AND METHOD FOR PRODUCING CURABLE LIQUID DEVELOPER
  申请人：CANON KABUSHIKI KAISHA

  公开号：EP3410217A1

  公开（公告）日：2018-12-05

  A curable liquid developer containing: a toner particle containing a pigment and a binder resin; a toner particle dispersing agent; and a cationically polymerizable liquid monomer, wherein the binder resin contains a polyester resin having an acid value of at least 5 mg KOH/g; the polyester resin contains an alcohol component-derived monomer unit and an acid component-derived monomer unit; the alcohol component-derived monomer unit and the acid component-derived monomer unit contain specific monomer units in specific proportions; and the content of the polyester resin in the binder resin is at least 50 mass% and not more than 100 mass%.

  一种可固化液体显影剂，含有含有颜料和粘合剂树脂的调色剂颗粒；调色剂颗粒分散剂；以及阳离子可聚合液体单体，其中粘合剂树脂含有酸值至少为 5 毫克 KOH/g 的聚酯树脂；聚酯树脂含有醇组分衍生单体单元和酸组分衍生单体单元；醇组分衍生单体单元和酸组分衍生单体单元含有特定比例的特定单体单元；以及 粘合剂树脂中聚酯树脂的含量至少为 50%，不超过 100%。
• Liquid developer and method of producing same
  申请人：CANON KABUSHIKI KAISHA

  公开号：US10175597B2

  公开（公告）日：2019-01-08

  Provided is a liquid developer that gives a high image density, has a high resistance, suppresses the appearance of image blurring, can be reused, is readily cured by ultraviolet radiation, and can accommodate higher process speeds. This liquid developer contains a carrier liquid, a toner particle insoluble in the carrier liquid, and a compound with the following formula (1) [In formula (1), R1 and R2 each independently represent an alkyl group having at least 13 and not more than 23 carbons.].

  本发明提供了一种液体显影剂，它具有高图像密度、高耐受性、抑制图像模糊、可重复使用、易于通过紫外线辐射固化以及可适应更高的加工速度。这种液体显影剂含有载液、不溶于载液的墨粉颗粒和下式（1）的化合物 [在式 (1) 中，R1 和 R2 各自独立地代表一个至少有 13 个碳原子但不超过 23 个碳原子的烷基。］
• Synthesis and antimicrobial properties of polymerizable quaternary ammoniums
  作者：Laurent Caillier、Elisabeth Taffin de Givenchy、Richard Levy、Yves Vandenberghe、Serge Géribaldi、Frédéric Guittard

  DOI：10.1016/j.ejmech.2009.03.031

  日期：2009.8

  Introduction of biocide monomers during the process of polymerization is a promising approach in the development of new permanent non leaching biocide materials. Two series of surfactants monomers, with a quaternary ammonium group as polar head and an acrylic function as the polymerizable moiety, were synthesized and tested to evaluate their surface active properties alongside with their antibacterial and antifungal properties. Four microbial strains were used to perform the study: Pseudomonas aeruginosa, Staphylococcus aureus. Candida albicans and Aspergillus niger. The biocidal efficacy measured by bacterial and fungal growth inhibition expressed as MIC (Minimal Inhibitory Concentration) and MLC (Minimal Lethal Concentration) values was discussed as a function of molecular parameters. All the synthesized surfactant monomers presented bactericidal and fungicidal activities. Increasing the spacer between the acrylic part and the ammonium group has a favourable effect on the MIC and MLC results. (C) 2009 Elsevier Masson SAS. All rights reserved.
• Quaternary salts of aminoalkyl esters of benzoic acid
  作者：A. P. Arendaruk、A. P. Skoldinov、N. V. Smirnova、V. M. Solov'ev、D. A. Kharkevich

  DOI：10.1007/bf00778445

  日期：1972.1