| 1616726-28-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 1616726-28-3
• 化学式: C₁₁H₁₉NSeSi
• 分子量: 272.324
• InChiKey: RVNDXTHCFAROBT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.92
• 重原子数：
  14.0
• 可旋转键数：
  3.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  、 1,5-双(二苯基膦)戊烷 、 copper (I) acetate 、 甲苯 反应 0.5h， 以44%的产率得到[Cu₂(p-SeC₆H₄NMe₂)₂(1,5-bis(diphenylposphino)pentane)₂]*2(toluene)
  参考文献：
  名称：

  Synthesis, characterization and optical properties of a series of binuclear copper chalcogenolato complexes

  摘要：

  A series of isolated binuclear copper(I) thiolate and selenolate complexes [Cu-2(ER)(2)(dpppt)(2)] (1, E = S, R = C4H3S; 2, E = S, R = p-C6H4OMe; 3, E = Se, R = C6H5; 4, E = Se, R = p-C6H4SMe; 5, E = Se, R = p-C6H4NMe2) was synthesized. It was found that the luminescence of these complexes could be modulated by the chalcogenolate ligands. The five complexes show optical transitions with HOMO-LUMO gaps of ca. 2.95 eV (1), 2.82 eV (2), 2.99 eV (3), 2.95 eV (4) and 2.64 eV (5), respectively. Two of them (2 and 5) show a significant luminescence at room temperature at 465 or 480 nm, respectively. This might most probably result from the influence of the electron donating nature of the substituents -OMe and -NMe2. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2014.05.009