N-phthalimido-N-succinimido-1,2-ethane | 21491-30-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: N-phthalimido-N-succinimido-1,2-ethane
• 英文别名: N-(β-Phthalimidoethyl)-succinimid；2-[2-(2,5-Dioxopyrrolidin-1-yl)ethyl]isoindole-1,3-dione
• CAS: 21491-30-5
• 化学式: C₁₄H₁₂N₂O₄
• 分子量: 272.26
• InChiKey: MZPQAMMLIPNUFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N-phthalimido-N-succinimido-1,2-ethane 在 双氧水 作用下， 以 水 为溶剂， 生成
  参考文献：
  名称：

  SYNTHÈSE DE NOUVEAUX INITIATEURS. GÉNÉRATION IN SITU DE COMPOSÉS PEROXYGÈNES PAR ACTION DU PERCARBONATE DE SODIUM. APPLICATION [Agrave] LA DESTRUCTION DE TOXIQUES ORGANOPHOSPHORES ET/OU SOUFRES

  摘要：

  New initiators 1-7, analogues of tetra-acetylethylenediamine, have been prepared and their use in the in situ generation of peroxyacids by reaction with sodium peroxycarbonate described. The kinetics of perhydrolysis of these initiators in aqueous solution under different conditions of temperature and pH, as well as the use of these new "complex peroxygenated systems" in the destruction of organophosphorus and sulfur toxins and pollutants, have been studied.

  DOI：

  10.1080/10426500008042098
• 作为产物：
  描述：

  1-(2-溴乙基)吡咯烷-2,5-二酮 、 potassium phtalimide 在 四丁基溴化铵 作用下， 以 乙腈 为溶剂， 反应 5.0h， 以80%的产率得到N-phthalimido-N-succinimido-1,2-ethane
  参考文献：
  名称：

  SYNTHÈSE DE NOUVEAUX INITIATEURS. GÉNÉRATION IN SITU DE COMPOSÉS PEROXYGÈNES PAR ACTION DU PERCARBONATE DE SODIUM. APPLICATION [Agrave] LA DESTRUCTION DE TOXIQUES ORGANOPHOSPHORES ET/OU SOUFRES

  摘要：

  New initiators 1-7, analogues of tetra-acetylethylenediamine, have been prepared and their use in the in situ generation of peroxyacids by reaction with sodium peroxycarbonate described. The kinetics of perhydrolysis of these initiators in aqueous solution under different conditions of temperature and pH, as well as the use of these new "complex peroxygenated systems" in the destruction of organophosphorus and sulfur toxins and pollutants, have been studied.

  DOI：

  10.1080/10426500008042098

文献信息

• SYNTHÈSE DE NOUVEAUX INITIATEURS. GÉNÉRATION <i>IN SITU</i> DE COMPOSÉS PEROXYGÈNES PAR ACTION DU PERCARBONATE DE SODIUM. APPLICATION [Agrave] LA DESTRUCTION DE TOXIQUES ORGANOPHOSPHORES ET/OU SOUFRES
  作者：Claude Lion、Louis Da Conceição、Mir Hedayatullah

  DOI：10.1080/10426500008042098

  日期：2000.6.1

  New initiators 1-7, analogues of tetra-acetylethylenediamine, have been prepared and their use in the in situ generation of peroxyacids by reaction with sodium peroxycarbonate described. The kinetics of perhydrolysis of these initiators in aqueous solution under different conditions of temperature and pH, as well as the use of these new "complex peroxygenated systems" in the destruction of organophosphorus and sulfur toxins and pollutants, have been studied.