N,N'-bis(2-hydroxy-1-naphthaldehyde)-1,4-bis(o-aminothiophenol)butane | 172665-97-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N,N'-bis(2-hydroxy-1-naphthaldehyde)-1,4-bis(o-aminothiophenol)butane
• 英文别名: 1-[[2-[4-[2-[(2-Hydroxynaphthalen-1-yl)methylideneamino]phenyl]sulfanylbutylsulfanyl]phenyl]iminomethyl]naphthalen-2-ol
• CAS: 172665-97-3
• 化学式: C₃₈H₃₂N₂O₂S₂
• 分子量: 612.816
• InChiKey: JTXITLNUAZTRJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  44
• 可旋转键数：
  11
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  116
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N,N'-bis(2-hydroxy-1-naphthaldehyde)-1,4-bis(o-aminothiophenol)butane 、 copper diacetate 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  某些大环多齿铜（II），镍（II）和钴（II）配合物的合成，光谱和氧化还原行为

  摘要：

  中性四齿二胺的铜（II）配合物，以及由上述二胺和水杨醛或2-羟基-苯胺衍生的新型二元六齿席夫碱的一系列铜（II），镍（II）和钴（II）配合物已经制备了1-萘醛，并通过元素分析，磁化率以及红外光谱和电子光谱研究对其进行了表征。还研究了铜（II）和钴（II）配合物的电化学行为以及所有铜（II）配合物的ESR光谱参数。配体场强随螯合物环尺寸从六增加到七而增加。ESR光谱数据表明，铜（II）配合物呈现单体扭曲的八面体或拟四面体结构。乙腈中的II / Cu I和Co II / Co I对。

  DOI：

  10.1016/0277-5387(95)00182-r
• 作为产物：
  描述：

  1,4-bis(o-aminophenylthio)butane 、 2-羟基-1-萘甲醛 以 甲醇 、 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 8.0h， 以40%的产率得到N,N'-bis(2-hydroxy-1-naphthaldehyde)-1,4-bis(o-aminothiophenol)butane
  参考文献：
  名称：

  Synthesis, characterization and catalytic behavior in the Suzuki reaction of Schiff base and its complexes and the optical properties of nickel complex used in the fabrication of a photodiode

  摘要：

  Schiff base ligand N,N'-bis(2-hydroxy-1-naphtaldehydene)-1,4-bis(o-amino phenilthio)butane (L) derived from 2-hydroxy-1-naphthaldehyde and 1,4-bis(o-amino thiophenol)butane was synthesized and characterized by FTIR-ATR, H-1 NMR, MS, TGA/DTA, elemental analysis, UV-Vis Spectroscopy. The reactions of the ligand with different transition metal(11) salts under reflux system condition afforded a series of metal complexes such as Cu(II), Co(III), Ni(II), Pd(II). Palladium-catalyzed Suzuki cross-coupling reactions employing Schiff-base as ligand toward a various of substituted arylbromides and boronic acids were pursued. The conversions obtained and yields with different arylbromides were calculated and summarized.The transmission and absorbance spectra of the Ni(II) complex were taken by UV-Vis spectrophotometer, and direct and indirect band gap values were determined by optical method. A photodiode was fabricated by forming a thin film on n-Si wafer and evaporating Au contact onto the film. It was seen that the structure has a good rectification. The electrical properties of the diode were calculated using current voltage measurements. Furthermore, the effect of light on current voltage measurements of the structure was examined using a solar simulator with AM1.5 filter at various illumination intensities. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.02.038
• 作为试剂：
  描述：

  4-溴苯乙酮 、 苯硼酸 在 N,N'-bis(2-hydroxy-1-naphthaldehyde)-1,4-bis(o-aminothiophenol)butane 、 palladium diacetate 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 15.0h， 以83%的产率得到联苯单乙酮
  参考文献：
  名称：

  Synthesis, characterization and catalytic behavior in the Suzuki reaction of Schiff base and its complexes and the optical properties of nickel complex used in the fabrication of a photodiode

  摘要：

  Schiff base ligand N,N'-bis(2-hydroxy-1-naphtaldehydene)-1,4-bis(o-amino phenilthio)butane (L) derived from 2-hydroxy-1-naphthaldehyde and 1,4-bis(o-amino thiophenol)butane was synthesized and characterized by FTIR-ATR, H-1 NMR, MS, TGA/DTA, elemental analysis, UV-Vis Spectroscopy. The reactions of the ligand with different transition metal(11) salts under reflux system condition afforded a series of metal complexes such as Cu(II), Co(III), Ni(II), Pd(II). Palladium-catalyzed Suzuki cross-coupling reactions employing Schiff-base as ligand toward a various of substituted arylbromides and boronic acids were pursued. The conversions obtained and yields with different arylbromides were calculated and summarized.The transmission and absorbance spectra of the Ni(II) complex were taken by UV-Vis spectrophotometer, and direct and indirect band gap values were determined by optical method. A photodiode was fabricated by forming a thin film on n-Si wafer and evaporating Au contact onto the film. It was seen that the structure has a good rectification. The electrical properties of the diode were calculated using current voltage measurements. Furthermore, the effect of light on current voltage measurements of the structure was examined using a solar simulator with AM1.5 filter at various illumination intensities. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.02.038