(guanidinium)[Bi(ethylenediaminetetraacetate)H2O] | 229014-61-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (guanidinium)[Bi(ethylenediaminetetraacetate)H2O]
• 英文别名: (gu)[Bi(edta)(H2O)]
• CAS: 229014-61-3；108854-96-2
• 化学式: Bi*CH₆N₃*C₁₀H₁₂N₂O₈*H₂O
• 分子量: 575.288
• InChiKey: DFFDURCMALKWRN-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -11.6
• 重原子数：
  26.0
• 可旋转键数：
  11.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  276.13
• 氢给体数：
  3.0
• 氢受体数：
  10.0

反应信息

• 作为反应物：
  描述：

  、 (guanidinium)[Bi(ethylenediaminetetraacetate)H2O] 以 neat (no solvent, solid phase) 为溶剂， 生成
  参考文献：
  名称：

  A new molecular precursor route for the synthesis of Bi–Y, Y–Nb and Bi-doped Y–Nb oxides at moderate temperatures

  摘要：

  Yttrium-based multimetallic oxides containing bismuth and/or niobium were prepared by a method starting from pre-isolated stable water-soluble precursors which are complexes with the ethylenediaminetetraacetate ligand (edta). The cubic Bi1-xYxO1.5 (x = 0.22, 0.25 and 0.3) and Y3NbO7 oxides were obtained in a pure form in a range of moderate temperatures (600-650 degrees C). This preparation method also allowed to stabilize at room temperature, without quenching, the tetragonal YNbO4 oxide in a distorted form (T'-phase) by calcining the precursor at 800 degrees C. When heated up to 1000 degrees C, this metastable T'-phase transforms into the metastable "high-temperature" T oxide, which converts on cooling down to room temperature into the thermodynamically stable monoclinic M oxide. Doping the YNbO4 oxide with Bi3+ cations (0.5% and 1% Bi with respect to total Bi + Y amount) led at 800 degrees C to a mixture of the T'-phase and the thermodynamically stable monoclinic one. At 900 degrees C, the almost pure monoclinic structure was obtained. (c) 2007 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2007.01.027
• 作为产物：
  描述：

  bismuth subcarbonate 、 乙二胺四乙酸 、 水 、 碳酸胍 以 水 为溶剂， 生成 (guanidinium)[Bi(ethylenediaminetetraacetate)H2O]
  参考文献：
  名称：

  A new molecular precursor route for the synthesis of Bi–Y, Y–Nb and Bi-doped Y–Nb oxides at moderate temperatures

  摘要：

  Yttrium-based multimetallic oxides containing bismuth and/or niobium were prepared by a method starting from pre-isolated stable water-soluble precursors which are complexes with the ethylenediaminetetraacetate ligand (edta). The cubic Bi1-xYxO1.5 (x = 0.22, 0.25 and 0.3) and Y3NbO7 oxides were obtained in a pure form in a range of moderate temperatures (600-650 degrees C). This preparation method also allowed to stabilize at room temperature, without quenching, the tetragonal YNbO4 oxide in a distorted form (T'-phase) by calcining the precursor at 800 degrees C. When heated up to 1000 degrees C, this metastable T'-phase transforms into the metastable "high-temperature" T oxide, which converts on cooling down to room temperature into the thermodynamically stable monoclinic M oxide. Doping the YNbO4 oxide with Bi3+ cations (0.5% and 1% Bi with respect to total Bi + Y amount) led at 800 degrees C to a mixture of the T'-phase and the thermodynamically stable monoclinic one. At 900 degrees C, the almost pure monoclinic structure was obtained. (c) 2007 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2007.01.027

文献信息

• Shchelokov, R. N.; Mikhailov, Yu. N.; Mistryukov, V. E., Doklady Chemistry, 1987, vol. 292 - 297, p. 162 - 164
  作者：Shchelokov, R. N.、Mikhailov, Yu. N.、Mistryukov, V. E.、Sergeev, A. V.

  DOI：——

  日期：——