1-ferrocenyl-N-isopropylmethanamine | 606100-39-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-ferrocenyl-N-isopropylmethanamine
• 英文别名: [(η5-C5H5)Fe(η5-C5H4CH2NHCHMe2)]；FcCH2NHiPr；cyclopenta-1,3-diene;N-(cyclopenta-1,3-dien-1-ylmethyl)propan-2-amine;iron(2+)
• CAS: 606100-39-4
• 化学式: C₁₄H₁₉FeN
• 分子量: 257.159
• InChiKey: ZQMDEFXMGDOJTR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1-ferrocenyl-N-isopropylmethanamine 、 potassium trichloro(ethylene)platinate(II) 在 丙酮 作用下， 以 水 为溶剂， 生成 trans-[PtCl2(η2-ethene)(η5-C5H5)Fe(η5-C5H4CH2NHCHMe2)]
  参考文献：
  名称：

  Synthesis, characterization, inequivalency of methylene proton and proton lability in the amino ligand of trans-[dichloro{(N-ferrocenyl methyl)amine}(η2-ethene)platinum] complexes

  摘要：

  A series of complexes of the type trans-W[PtCl2(eta(2)-ethene)(N-ferrocenyl methyl)amine)] complexes, N-ferrocenylmethylamine = [(eta(5)-C-5-H-5)Fe(eta(5)-C-5-H4CH2NHR], R = (Me, Pr-i, Bu-s, Bu-t, CH2Ph, (p-OCH3)Ph, (o-(OCH3)Ph, (p-CH3)Ph, (o-CH3)Ph, (m-CH3)Ph, (p-Cl)Ph) have been synthesized and characterized on the basis of elemental analysis, IR, H-1 and C-13 NMR spectroscopic methods. The CpCH2NHR (Cp = (eta(5) -C5H5)Fe(eta(5)-C5H4), region of the H-1 NMR spectrum of the complexes has been investigated and shown to contain inequivalent methylene protons, NH-CH and Pt-195 -N-CH coupling take place. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(02)00334-7
• 作为产物：
  描述：

  [(η5-C5H5)Fe(η5-C5H4CHNCHMe2)] 、 sodium tetrahydroborate 以 甲醇 为溶剂， 生成 1-ferrocenyl-N-isopropylmethanamine
  参考文献：
  名称：

  Synthesis, characterization, inequivalency of methylene proton and proton lability in the amino ligand of trans-[dichloro{(N-ferrocenyl methyl)amine}(η2-ethene)platinum] complexes

  摘要：

  A series of complexes of the type trans-W[PtCl2(eta(2)-ethene)(N-ferrocenyl methyl)amine)] complexes, N-ferrocenylmethylamine = [(eta(5)-C-5-H-5)Fe(eta(5)-C-5-H4CH2NHR], R = (Me, Pr-i, Bu-s, Bu-t, CH2Ph, (p-OCH3)Ph, (o-(OCH3)Ph, (p-CH3)Ph, (o-CH3)Ph, (m-CH3)Ph, (p-Cl)Ph) have been synthesized and characterized on the basis of elemental analysis, IR, H-1 and C-13 NMR spectroscopic methods. The CpCH2NHR (Cp = (eta(5) -C5H5)Fe(eta(5)-C5H4), region of the H-1 NMR spectrum of the complexes has been investigated and shown to contain inequivalent methylene protons, NH-CH and Pt-195 -N-CH coupling take place. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(02)00334-7

文献信息

• Syntheses, crystal, photoluminescence and electrochemical investigation of some new phenylmercury(ii) dithiocarbamate complexes involving ferrocene
  作者：Nanhai Singh、Abhinav Kumar、Rajendra Prasad、Kieran C. Molloy、Mary F. Mahon

  DOI：10.1039/b917871f

  日期：——

  phenylmercury(II) dithiocarbamate complexes incorporating the ferrocenyl moiety (C5H5)Fe(C5H4) (Fc), namely PhHgS2CN(CH2Fc)CH2C6H5, (1), PhHgS2CN(CH2Fc)CH(CH3)2, (2), PhHgS2CN(CH2Fc)(CH2)3CH3, (3) and [PhHgS2CN(CH2Fc)]2(CH2C6H4CH2), (4) have been prepared and characterized by elemental analysis, UV-Vis, IR, 1H and 13C NMR spectroscopies. The crystal structures of 1, 2 and 4 showed a linear core at the

  一系列新的异双金属 苯汞（II）二硫代氨基甲酸酯含有二茂铁基部分（C 5 H 5）Fe（C 5 H 4）的配合物（Fc），即PhHgS 2 CN（CH 2 Fc）CH 2 C 6 H 5，（1），PhHgS 2 CN（CH 2 Fc）CH（CH 3）2，（2），PhHgS 2 CN（CH 2 Fc）（ CH 2）3 CH 3，（3）和[PhHgS 2 CN（CH 2 Fc）] 2（CH 2 C 6 H 4 CH 2），（4已通过元素分析，UV-Vis，IR，1 H和13 C NMR光谱法制备并表征。的晶体结构1，2和4显示了在汞（线性芯II分子的）中心，由所述结合的硫 的原子 二硫代氨基甲酸酯 配体和 碳芳环的原子。在1和2的情况下，弱分子间Hg⋯S相互作用形成“头对尾”二聚体。4形成相似的二聚体结构，形成两对Hg⋯S相互作用以生成四金属单元。通过计算中性原子及其在理论密度函数水平（DFT
• ORGANOMETALLIC FLUCONAZOLE DERIVATES AND THEIR USE AS ANTIMYCOTICS
  申请人：Universität Zürich

  公开号：EP3301100A1

  公开（公告）日：2018-04-04

  The invention relates to compounds characterized by a general formula (1), wherein OM is an organometallic compound. OM is independently selected from the group of an unsubstituted or substituted metal sandwich compound, an unsubstituted or substituted half metal sandwich compound or a metal carbonyl compound.

  该发明涉及一种以一般式(1)为特征的化合物，其中OM是一种有机金属化合物。OM是从未取代或取代的金属三明治化合物、未取代或取代的半金属三明治化合物或金属羰基化合物的组中独立选择的。