bis(diisopropylamino)chlorophosphonium-fluorenylide | 87769-86-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: bis(diisopropylamino)chlorophosphonium-fluorenylide
• 英文别名: N-[chloro-[di(propan-2-yl)amino]-fluoren-9-ylidene-λ5-phosphanyl]-N-propan-2-ylpropan-2-amine
• CAS: 87769-86-6
• 化学式: C₂₅H₃₆ClN₂P
• 分子量: 431.001
• InChiKey: LBEKBSGQVMHRLN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.47
• 重原子数：
  29.0
• 可旋转键数：
  6.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  6.48
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  bis(diisopropylamino)chlorophosphonium-fluorenylide 在 盐酸 作用下， 以 乙醚 为溶剂， 以80%的产率得到bis(diisopropylamino)fluorenylchlorophosphonium chloride
  参考文献：
  名称：

  Kolodyazhnyi, O. I.; Ustenko, S. N., Russian Journal of General Chemistry, 1993, vol. 63, # 6, p. 857 - 861

  摘要：

  DOI：
• 作为产物：
  描述：

  fluorenylphosphonous bis(diisopropylamide) 在 四氯化碳 作用下， 以 乙醚 为溶剂， 以80%的产率得到bis(diisopropylamino)chlorophosphonium-fluorenylide
  参考文献：
  名称：

  Kolodyazhnyi, O. I.; Ustenko, S. N., Russian Journal of General Chemistry, 1993, vol. 63, # 6, p. 857 - 861

  摘要：

  DOI：

文献信息

• Appel, Rolf; Schmitz, Rudolf, Chemische Berichte, 1983, vol. 116, # 10, p. 3521 - 3523
  作者：Appel, Rolf、Schmitz, Rudolf

  DOI：——

  日期：——
• Novel Ring Expansion Isomerism of a Fluorenylidenephosphonium
  作者：Neil Burford、Jason A. C. Clyburne、Sergey V. Sereda、T. Stanley Cameron、James A. Pincock、Michael Lumsden

  DOI：10.1021/om00008a025

  日期：1995.8

  The synthesis and conclusive characterization of a series of fluorenyl- and fluorenylidene-tetraalkyldiaminophosphorus compounds (alkyl = ethyl and isopropyl) are described. The phosphines 6 are obtained by reaction of chlorodiaminophosphines with fluorenyllithium and are quantitatively oxidized to the phosphorane 7 by reaction with CCl4. Crystal structures of the isopropyl derivatives are reported. (Crystal data for 6a: C25H37N2P, M = 396.55, P2(1)/n, a = 15.710(5) Angstrom, b = 9.66(1) Angstrom, c 15.93(2) Angstrom, beta = 91.48(6)degrees, V = 2417(7) Angstrom(3), Z = 4, D-c = 1.089 Mg/m(3), R = 0.0538. For 7a: C25H36ClN2P, M = 431.00, P2(1)/c, a = 8.69(1) Angstrom, b = 16.24(1) Angstrom, c = 17.16 (2)Angstrom, beta = 96.0(1)degrees, V = 2409(8) Angstrom(3), Z = 4, D-c = 1.188 Mg/m(3), R = 0.0481.) Contrary to previous reports (with AlCl3) reaction of the phosphoranes with GaCl3 gives the covalent complexes 7-GaCl3. The ethyl derivative is stable, while the isopropyl derivative undergoes a quantitative isomerization to give 9-(diisopropylamino)-10-(diisopropyliminio)-9,10-dihydro-9-phosphaphenanthrene tetrachlorogallate 5[GaCl4] via a novel ring expansion rearrangement. (Crystal data for 5[GaCl4]: C25H36Cl4GaN2P, M = 607.08; P2(1)/n; a = 9.884(3) Angstrom; b = 21.189(4) Angstrom; c 14.639(4) Angstrom; beta 95.12(2)degrees; V = 3054(2) Angstrom(3); Z = 4; D-c = 1.320 Mg/m(3); R = 0.0393.)
• Kolodjazhnyii O. I., Ustenko S. N., Zh. obshh. khimii, 63 (1993) N 6, S 1228-1233
  作者：Kolodjazhnyii O. I., Ustenko S. N.

  DOI：——

  日期：——
• APPEL, R.;SCHMITZ, R., CHEM. BER., 1983, 116, N 10, 3521-3523
  作者：APPEL, R.、SCHMITZ, R.

  DOI：——

  日期：——