(R)-(η(5)-1-hydroxydiphenylmethyl-2-methyl-4-phenylcyclopentadienyl)di(carbonyl)methylsulfonyliron | 239468-54-3

• 英文名称: (R)-(η(5)-1-hydroxydiphenylmethyl-2-methyl-4-phenylcyclopentadienyl)di(carbonyl)methylsulfonyliron
• 英文别名: (S)-(η(5)-1-hydroxydiphenylmethyl-2-methyl-4-phenylcyclopentadienyl)di(carbonyl)methylsulfonyliron
• CAS: 239468-54-3；239477-46-4
• 化学式: C₂₈H₂₄FeO₅S
• 分子量: 528.409
• InChiKey: XJKFSMHPYWKTID-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (S)-(η(5)-1-hydroxydiphenylmethyl-2-methyl-4-phenylcyclopentadienyl)di(carbonyl)methyliron 、 二氧化硫 以 二氧化硫 为溶剂， 以91%的产率得到(R)-(η(5)-1-hydroxydiphenylmethyl-2-methyl-4-phenylcyclopentadienyl)di(carbonyl)methylsulfonyliron
  参考文献：
  名称：

  Synthesis and Characterization of Planar-Chiral Cyclopentadienyliron Complexes (S)- and (R)-{η⁵-[1-Ph₂(OH)C-2-Me-4-PhC₅H₂]}Fe(CO)₂R (R = C⋮CPh, Me, SO₂Me)

  摘要：

  The first enantiomerically pure planar-chiral cyclopentadienyliron complexes, (S)- and (R)-eta(5)-(CpFe)-Fe-c(CO)(2)R [Cp-c = 1-hydroxydiphenylmethyl-2-methyl-4-phenylcyclopentadienyl; R = C=CPh (6), Me (8)], in which the locus of chirality is in the cyclopentadienyl center, were synthesized from (CpFe)-Fe-a(CO)(2)I (4a: Cp-a = 1-(-)-menthoxycarbonyl-2-methyl-4-phenylcyclopentadienyl) and (CpFe)-Fe-b(CO)(2)I (4b: Cp-b = 1-(+)-menthoxycarbonyl-2-methyl-4-phenylcyclopentadienyl) and were isolated as a diastereomerically pure form by fractional recrystallization. The molecular structures of 4a and 4b, including the absolute configuration, have been established by an X-ray crystallographic analysis based on the configuration of the (-)- and (+)-menthyl groups.

  DOI：

  10.1021/om9810347