Synthesis and Characterization of Fluorodinitroamine, FN(NO<sub>2</sub>)<sub>2</sub>
作者:Karl O. Christe、William W. Wilson、Guillaume Bélanger-Chabot、Ralf Haiges、Jerry A. Boatz、Martin Rahm、G. K. Surya Prakash、Thomas Saal、Mathias Hopfinger
DOI:10.1002/anie.201410507
日期:2015.1.19
NF3 and N(NO2)3 are known compounds, whereas the mixed fluoronitroamines, FN(NO2)2 and F2NNO2, have been unknown thus far. One of these, FN(NO2)2, has now been prepared and characterized by multinuclear NMR and Raman spectroscopy. FN(NO2)2 is the first known example of an inorganic fluoronitroamine. It is a thermally unstable, highly energetic material formed by the fluorination of the dinitramide