hydroxypentakis(methylamino)cobalt(IX) | 32424-84-3

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 镧系有机物
• 英文名称: hydroxypentakis(methylamino)cobalt(IX)
• CAS: 32424-84-3
• 化学式: C₅H₂₇CoN₅O
• 分子量: 232.295
• InChiKey: UYRWPCQQFKBBKI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  盐酸 、 hydroxypentakis(methylamino)cobalt(IX) 在 lithium perchlorate 作用下， 以 水 为溶剂， 生成 mono(pentakis(methylamino)cobalt(VIII)) monochloride
  参考文献：
  名称：

  Steric effects on the anation reactions of pentaamine complexes of Co(III)

  摘要：

  The kinetics of the anation reactions of [Co(MeNH2)5H2O]3+ with H3PO4/H2PO4-, H3PO3/H2PO3-, Br-, Cl- and CF3OO- and those of [Co(NH3)5H2O]3+ with Br-, Cl- and CF3COO- (for the sake of comparison) have been studied at different temperatures and at I = 1.0 M (LiClO4). This is the first study on the effects of the size of the amines on anation reactions of these complexes. All results are interpreted on the basis of an I(d) mechanism. The span of Kk values for different entering ligands, decreases slightly on going from NH3 to MeNH2, and this is interpreted as the maintenance of a dissociatively activated interchange mechanism on going from NH3 to MeNH2 complexes. Activation enthalpy values decrease for each ligand (CF3COO- excepted) on going from NH3 to MeNH2. This is interpreted on the basis of a weaker ground state Co-OH2 bond for the MeNH2 complex, as compared to the NH3 analogue, that needs less energy to be stretched to the transition sate. The variation of the activation entropy values for the same entering ligand on increasing the amine size confirms this assumption. The overall activation free energies also confirm a greater steric relief, on H2O dissociation, for the MeNH2 complexes.

  DOI：

  10.1016/s0020-1693(00)80375-8
• 作为产物：
  描述：

  (trifluoromethanesulfonato)pentakis(methylamine)cobalt(III)(acetonitrile) 在 水 作用下， 以 高氯酸 为溶剂， 生成 hydroxypentakis(methylamino)cobalt(IX)
  参考文献：
  名称：

  Curtis, Neville J.; Lawrance, Geoffrey A., Inorganic Chemistry, 1986, vol. 25, # 7, p. 1033 - 1037

  摘要：

  DOI：

文献信息

• Lawrance, Geoffrey A.; Schneider, Karen; Van Eldik, Rudi, Inorganic Chemistry, 1984, vol. 23, # 24, p. 3922 - 3925
  作者：Lawrance, Geoffrey A.、Schneider, Karen、Van Eldik, Rudi

  DOI：——

  日期：——
• The kinetics of the Hg2+-assisted chloride release from some [MCl(RNH2)5]2+ complexes (M = Co, Cr)
  作者：Jirong Wang、Donald A. House

  DOI：10.1016/0020-1693(94)04390-h

  日期：1995.5

  Activation parameters associated with the Hg2+-assisted chloride release reaction in 50:50 dioxane:aqueous HClO4(I=0.5 M) from [MCI(RNH(2))(5)](2+) at 25 degrees C in the order (k(Hg), M(-1)S(-1);Delta H*,kJ mol(-1);Delta S*,J K-1 mol(-1) are M=Cr,R=H:5.45X10(-2),74.7,-18;M=Cr,R=Me:1.78x10(-3),70.0,-32;M=Cr,R=Et:1.19x10(-3),86.8,-9;M=Cr,R=nPr:7.06x10(-4),96.3,+17;M=Cr,R=nBu:5.30X10(-4),98.0,+21;M=Co,R=H:8.74x10(-2),70.3,-37;M=Co,R=Me:2.40,74.0,+11;M=Co,R=Et:4.95,69.0,0;M=Co,R=nPr:2.59,69.3,-5;M=Co,R=nBu:2.15,70.2,-3. Similar data in aqueous HClO4 (I=1.0 M) are M=Cr,R=H:9.84x10(-2),64.6,-27;M=Cr,R=Me:2.15x10(-3),93.2,+16.5M=Co,R=H:1.40x10(-1),65.1,-42; M=Co,R=Me:5.00,70.4,+5. The trends in activation entropy would rank MCl(RNH(2))(5)](2+) (R not equal H) at essentially the same position on an interchange mechanistic scale, independent of M, and more associatively restricting than [MCl(NH3)(5)](2+).
• Rotzinger, François P., Inorganic Chemistry, 1991, vol. 30, # 13, p. 2763 - 2772
  作者：Rotzinger, François P.

  DOI：——

  日期：——