申请人:Nippon Paint Co., Ltd.
公开号:EP1447460A1
公开(公告)日:2004-08-18
It is an object of the present invention to provide a rust prevention coating agent which can be used even in uses requiring high corrosion-resistant performance because of having corrosion resistance superior to a conventional surface treatment agent, and is excellent in the adhesion to a coating film, and a method of rust-proofing using the same.
A rust prevention coating agent comprising a fluorine and zirconium-containing compound and a guanidine compound and/or salt thereof,
wherein said guanidine compound and/or salt thereof is a compound, having a weight-average molecular weight of 59 to 1000000, expressed by the following general formula (1) and/or salt thereof;
in the formula, Y represents the formula of -C (=NH) -NH- (CH2)m-, -C(=O)-NH-(CH2)m-, or -, -C(=S)-NH-(CH2)m-, m is an integer of 0 to 20, n is a positive integer, k is 0 or 1, X represents hydrogen, an amino group, a hydroxyl group, a methyl group, a phenyl group, a chlorophenyl group or a methylphenyl group (tolyl group), and Z represents hydrogen, an amino group, a hydroxyl group, a methyl group, a phenyl group, a chlorophenyl group, a methylphenyl group (tolyl group) or a polymer, having a weight-average molecular weight of 200 to 1,000,000, being a polymer comprising ,as a repeating unit, one of the polymerization groups represented by the following general formula (2);
in the formula, p is an integer.
本发明的目的是提供一种防锈涂层剂,由于其耐腐蚀性优于传统的表面处理剂,因此即使在要求高耐腐蚀性能的用途中也可使用,而且对涂膜的附着力也很好,并提供一种使用该防锈涂层剂的防锈方法。
一种防锈涂层剂,由含
氟和
锆化合物以及
胍化合物和/或其盐组成、
其中,所述
胍化合物和/或其盐是一种化合物,其重量平均分子量为 59 至 1000000,由以下通式(1)表示和/或其盐;
式中,Y 代表-C(=NH)-NH-(
CH2)m-、-C(=O)-NH-( )m-或-、-C(=S)-NH-( )m-,m 为 0 至 20 的整数,n 为正整数,k 为 0 或 1,X 代表氢、
氨基、羟基、甲基、苯基、
氯苯基或甲基苯基(
甲苯基),Z 代表氢、
氨基、羟基、甲基、苯基、
氯苯基、甲基苯基(
甲苯基)或重量-平均分子量为 200-1,000,000 的聚合物,该聚合物包括以下通式(2)所代表的一个聚合基团作为重复单元;
式中,p 为整数。