(+/-)-cis-2-Brom-cyclohexancarbonsaeure | 1194-83-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: (+/-)-cis-2-Brom-cyclohexancarbonsaeure
• 英文别名: (1R,2R)-2-bromocyclohexane-1-carboxylic acid
• CAS: 1194-83-8；1972-44-7；5469-29-4
• 化学式: C₇H₁₁BrO₂
• 分子量: 207.067
• InChiKey: NDMRQGSTDXPLEP-NTSWFWBYSA-N

物化性质

• 熔点：
  109.0-109.8 °C(Solv: ligroine (8032-32-4))
• 沸点：
  301.9±35.0 °C(Predicted)
• 密度：
  1.556±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (+/-)-cis-2-Brom-cyclohexancarbonsaeure 、 溶剂黄146 、 alkaline earth salt of/the/ methylsulfuric acid 生成 (+/-)-trans-2-Brom-cyclohexancarbonsaeure
  参考文献：
  名称：

  Addition of Hydrogen Halides to α,β-Unsaturated Acids¹

  摘要：

  DOI：

  10.1021/ja01611a057
• 作为产物：
  描述：

  (5R,6E,8E,10E,13S,14S,15R,16Z)-15-羟基-5-甲氧基-14,16-二甲基-3,22,24-三羰基-2-氮杂二环[18.3.1]二十四碳-1(23),6,8,10,16,20-六烯-13-基N-(环己基羰基)-D-丙氨酸酸酯 在 氢氧化钾 、 氢溴酸 、 溶剂黄146 作用下， 生成 (+/-)-cis-2-Brom-cyclohexancarbonsaeure
  参考文献：
  名称：

  57.对烯酸的研究。第十六部分。环状不饱和酸的加成反应和互变异构变化以及对α-甲基戊烯酸的类似观察

  摘要：

  DOI：

  10.1039/jr9350000258

文献信息

• Bucherer; Dahlem, Journal fur praktische Chemie (Leipzig 1954), 1934, vol. <2> 140, p. 251,268
  作者：Bucherer、Dahlem

  DOI：——

  日期：——
• Effects induced in marbles by water-repellent compounds: the NMR contribution
  作者：M. Alesiani、S. Capuani、B. Maraviglia、R. Giorgi、P. Baglioni

  DOI：10.1007/bf03166184

  日期：2002.10

  The purpose of this paper is to investigate nuclear magnetic resonance (NMR) applications to porous materials widely employed in artistic and historical monuments and largely studied in the Cultural Heritage conservation field, with the aim of studying structural variations induced in the porous matrix by the application of strengthening and water-repellent agents. Carrara marble and Candoglia marble samples, both in the native state and after treatment, were studied and data from relaxation time measurements were compared. Results collected on treated samples are reported and explained in terms of the relation between spin-lattice relaxation time and the structure of the porous materials. Traditional techniques were employed in addition to NMR analysis on marble samples for the evaluation of the preservative performances of three agents generally employed in the restoration yards. Comparative images showing untreated samples with the treated ones were obtained suggesting very useful applications for the determination of treatment effectiveness.
• 57. Investigations of the olefinic acids. Part XVI. Additive reactions and tautomeric changes of cyclic unsaturated acids, and analogous observations on α-methylpentenoic acids
  作者：E. J. Boorman、R. P. Linstead

  DOI：10.1039/jr9350000258

  日期：——
• Addition of Hydrogen Halides to α,β-Unsaturated Acids¹
  作者：Wyman R. Vaughan、Robert L. Craven、Randel Q. Little、A. Charles Schoenthaler

  DOI：10.1021/ja01611a057

  日期：1955.3