junipediol A

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: junipediol A
• 英文别名: Junipediol A；2-(4-hydroxy-3-methoxyphenyl)propane-1,3-diol
• 化学式: C₁₀H₁₄O₄
• 分子量: 198.219
• InChiKey: UIDMTMWJXFPCFC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.4
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  69.9
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  乙酸酐 、 junipediol A 在 吡啶 作用下， 反应 24.0h， 以22 mg的产率得到Acetic acid 3-acetoxy-2-(4-carboxyoxy-3-methoxy-phenyl)-propyl ester
  参考文献：
  名称：

  A New Irregular Phenylpropanoid fromApollonias barbujana

  摘要：

  In addition to the known compounds (±)-threo-guaiacylglycerol and the phenethyl alcohols, 3-methoxy-4-dihydroxyphenethyl alcohol and 3,4-dimethoxyphenethyl alcohol, a new irregular phenylpropanoid 2-(3-methoxy-4-hydroxyphenyl)-1,3-propanediol was isolated from the ethanolic extract of the leaves of Apollonias barbujana (Lauraceae). Their structures were elucidated on the basis of spectroscopic methods and chemical transformations.

  DOI：

  10.1055/s-2006-959365
• 作为产物：
  描述：

  junipediol A 2-O-β-D-glucopyranoside 在 hesperidinase 作用下， 以 水 为溶剂， 反应 480.0h， 以3 mg的产率得到junipediol A
  参考文献：
  名称：

  Water-soluble constituents of caraway: aromatic compound, aromatic compound glucoside and glucides

  摘要：

  From the water-soluble portion of the methanolic extract of caraway (fruit of Carum carvi L.), an aromatic compound, an aromatic compound glucoside and a glucide were isolated together with 16 known compounds. Their structures were clarified as 2-methoxy-2-(4'-hydroxyphenyl)ethanol, junipediol A 2-O-beta-D-glucopyranoside and L-fucitol, respectively. (C) 2002 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0031-9422(02)00288-1

文献信息

• Water-soluble constituents of caraway: aromatic compound, aromatic compound glucoside and glucides
  作者：Tetsuko Matsumura、Toru Ishikawa、Junichi Kitajima

  DOI：10.1016/s0031-9422(02)00288-1

  日期：2002.10

  From the water-soluble portion of the methanolic extract of caraway (fruit of Carum carvi L.), an aromatic compound, an aromatic compound glucoside and a glucide were isolated together with 16 known compounds. Their structures were clarified as 2-methoxy-2-(4'-hydroxyphenyl)ethanol, junipediol A 2-O-beta-D-glucopyranoside and L-fucitol, respectively. (C) 2002 Published by Elsevier Science Ltd.
• A New Irregular Phenylpropanoid from<i>Apollonias barbujana</i>
  作者：C. Pérez、L. Almonacid、J. Trujillo、A. González、S. Alonso、E. Navarro

  DOI：10.1055/s-2006-959365

  日期：1995.12

  In addition to the known compounds (±)-threo-guaiacylglycerol and the phenethyl alcohols, 3-methoxy-4-dihydroxyphenethyl alcohol and 3,4-dimethoxyphenethyl alcohol, a new irregular phenylpropanoid 2-(3-methoxy-4-hydroxyphenyl)-1,3-propanediol was isolated from the ethanolic extract of the leaves of Apollonias barbujana (Lauraceae). Their structures were elucidated on the basis of spectroscopic methods and chemical transformations.