2-[(E)-Tricyclo[7.3.1.0^2,7]tridec-2(7)-en-13-yliminomethyl]-phenol

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-[(E)-Tricyclo[7.3.1.0^2,7]tridec-2(7)-en-13-yliminomethyl]-phenol
• 英文别名: 2-(13-tricyclo[7.3.1.02,7]tridec-2(7)-enyliminomethyl)phenol
• 化学式: C₂₀H₂₅NO
• 分子量: 295.425
• InChiKey: USZLVICCEDTGEY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  32.6
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N-[(13-anti)-tricyclo[7.3.1.0^2,7]tridec-2(7)-en-13-yl]methanamide 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 反应 3.0h， 生成 2-[(E)-Tricyclo[7.3.1.0^2,7]tridec-2(7)-en-13-yliminomethyl]-phenol
  参考文献：
  名称：

  摘要：

  Hydroamination of tricyclo[7.3.1.0(2,7)]tridec-2(7)-en-13-one according to Leukart reaction furnished (tricyclo[7.3.1.0(2,7)]tridec-2(7)-en-13-yl)methanamides stereoisomeric at C-13 atom. The corresponding epoxides were prepared therefrom. The unsaturated and epoxidized methanamides were hydrolyzed into amines that were converted into Schiff bases. The configurations of substances were established.

  DOI：

  10.1023/a:1020941207804

文献信息

• ——
  作者：V. I. Vysotskii、O. V. Patrusheva、T. A. Vysotskaya、V. V. Isakov

  DOI：10.1023/a:1020941207804

  日期：——

  Hydroamination of tricyclo[7.3.1.0(2,7)]tridec-2(7)-en-13-one according to Leukart reaction furnished (tricyclo[7.3.1.0(2,7)]tridec-2(7)-en-13-yl)methanamides stereoisomeric at C-13 atom. The corresponding epoxides were prepared therefrom. The unsaturated and epoxidized methanamides were hydrolyzed into amines that were converted into Schiff bases. The configurations of substances were established.