trans-4-(N-(4-methoxyphenyl)amino)stilbene | 777091-83-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: trans-4-(N-(4-methoxyphenyl)amino)stilbene
• 英文别名: 4-(4-methoxyphenyl)aminostilbene；N-(4-methoxyphenyl)-4-[(E)-2-phenylethenyl]aniline
• CAS: 777091-83-5
• 化学式: C₂₁H₁₉NO
• 分子量: 301.388
• InChiKey: LKGNSYSFQQAGGK-BQYQJAHWSA-N

物化性质

• 沸点：
  472.2±34.0 °C(Predicted)
• 密度：
  1.147±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  21.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  trans-4-(N-(4-methoxyphenyl)amino)stilbene 以 四氢呋喃 、 正己烷 为溶剂， 生成 cis-4-(N-(4-methoxyphenyl)amino)stilbene
  参考文献：
  名称：

  Substituent-Dependent Photoinduced Intramolecular Charge Transfer in N-Aryl-Substituted trans-4-Aminostilbenes

  摘要：

  The photochemical behavior of trans-4-(N-arylamino)stilbene (1, aryl = 4-substituted phenyl) in solvents more polar than THF is strongly dependent on the substituent in the N-aryl group. This is attributed to the formation of a twisted intramolecular charge transfer (TICT) state for those with a methoxy (10M), methoxycarbonyl (1CO), or cyano (1CN) substituent but not for those with a methyl (1Me), hydrogen (1H), chloro (1Cl), or trifluoromethyl (1CF) substituent. On the basis of the ring-bridged model compounds 3-6, the TICT states for 1CN and 1CO result from the twisting of the anilino-benzonitrilo C-N bond, but for 10M it is from the twisting of the stilbenyl-anilino C-N bond, both of which are distinct from the TICT states previously proposed for N,N-dimethylaminostilbenes.

  DOI：

  10.1021/ja047604d
• 作为产物：
  描述：

  4-溴-反-二苯乙烯 、 甲氧苯胺 在 tris(dibenzylideneacetone)dipalladium (0) 、 R-(+)-1,1'-联萘-2,2'-双二苯膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 以84%的产率得到trans-4-(N-(4-methoxyphenyl)amino)stilbene
  参考文献：
  名称：

  Substituent-Dependent Photoinduced Intramolecular Charge Transfer in N-Aryl-Substituted trans-4-Aminostilbenes

  摘要：

  The photochemical behavior of trans-4-(N-arylamino)stilbene (1, aryl = 4-substituted phenyl) in solvents more polar than THF is strongly dependent on the substituent in the N-aryl group. This is attributed to the formation of a twisted intramolecular charge transfer (TICT) state for those with a methoxy (10M), methoxycarbonyl (1CO), or cyano (1CN) substituent but not for those with a methyl (1Me), hydrogen (1H), chloro (1Cl), or trifluoromethyl (1CF) substituent. On the basis of the ring-bridged model compounds 3-6, the TICT states for 1CN and 1CO result from the twisting of the anilino-benzonitrilo C-N bond, but for 10M it is from the twisting of the stilbenyl-anilino C-N bond, both of which are distinct from the TICT states previously proposed for N,N-dimethylaminostilbenes.

  DOI：

  10.1021/ja047604d

文献信息

• Aldehyde intermediates for the preparation of pyrenylamine derivatives
  申请人：Ricoh Company, Ltd.

  公开号：US05344985A1

  公开（公告）日：1994-09-06

  A pyrenylamine derivative having an unsaturated bond of formula (I), which can be employed as an organic photoconductive material for use in electrophotography: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, W, l, m, n j and k are specifically defined the specification, an aldehyde compound of formula (II), which is an intermediate for preparing the pyrenylamine derivative: ##STR2## and methods of producing the pyrenylamine derivative and the aldehyde compound are disclosed.

  具有式(I)不饱和键的吡啶胺衍生物，可作为有机光导材料用于静电复印：其中R.sup.1、R.sup.2、R.sup.3、R.sup.4、R.sup.5、W、l、m、n、j和k在规范中具体定义，具有式(II)的醛化合物，用于制备吡啶胺衍生物的中间体：并公开了制备吡啶胺衍生物和醛化合物的方法。
• Pyrenylamine derivatives
  申请人：Ricoh Company, Ltd.

  公开号：US05459275A1

  公开（公告）日：1995-10-17

  An electrophotographic photoconductor comprises an electroconductive substrate and a photoconductive layer formed thereon comprising as an effective component at least one pyrenylamine derivative of formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, W, j, k, l, m and n are specifically defined in the specification. Furthermore, a novel pyrenylamine derivative for use in the above electrophotographic photoconductor, an aldehyde compound, which is an intermediate for producing the pyrenylamine derivative, and methods of preparing the pyrenylamine derivative and the aldehyde compound are disclosed.

  一种电子照相导电体包括一个导电基底和在其上形成的光导层，所述光导层包括至少一种具有式（I）的芘胺衍生物作为有效成分：其中R1、R2、R3、R4、R5、W、j、k、l、m和n在说明书中具体定义。此外，还公开了一种用于上述电子照相导电体的新型芘胺衍生物，一种醛化合物，该醛化合物是制备芘胺衍生物的中间体，以及制备芘胺衍生物和醛化合物的方法。
• US5344985A
  申请人：——

  公开号：US5344985A

  公开（公告）日：1994-09-06
• US5459275A
  申请人：——

  公开号：US5459275A

  公开（公告）日：1995-10-17
• US5457232A
  申请人：——

  公开号：US5457232A

  公开（公告）日：1995-10-10