3-methylbenzo[e][1,3]thiazine-2,4-dione | 13119-33-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 英文名称: 3-methylbenzo[e][1,3]thiazine-2,4-dione
• 英文别名: 3-methyl-benzo[e][1,3]thiazine-2,4-dione；3-Methyl-benzo1,3-thiazin-2,4-dion；3-Methyl-benzo1.3-thiazin-2,4-dion；2,4-Dioxo-3-methyl-3,4-dihydro-2H-1.3-benzothiazin；3-Methyl-2,4-dioxo-3,4-dihydro-2H-1,3-benzothiazin；3-Methyl-2,4-dioxodihydro-5,6-benzo-1,3-thiazin；3-Methyl-1,3-benzothiazine-2,4-dione
• CAS: 13119-33-0
• 化学式: C₉H₇NO₂S
• 分子量: 193.226
• InChiKey: SXKWTESFUNKJMK-UHFFFAOYSA-N

物化性质

• 熔点：
  119 °C
• 沸点：
  350.5±25.0 °C(Predicted)
• 密度：
  1.382±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  62.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-methylbenzo[e][1,3]thiazine-2,4-dione 以9.5%的产率得到异硫氰酸甲酯
  参考文献：
  名称：

  Comparison of the thermal and mass-spectrometric fragmentation of 2,4-thioxo(oxo)dihydro-5,6-benzo-1,3-thiazines

  摘要：

  DOI：

  10.1007/bf00513256
• 作为产物：
  描述：

  硫代水杨酸 在 盐酸 作用下， 以 水 为溶剂， 生成 3-methylbenzo[e][1,3]thiazine-2,4-dione
  参考文献：
  名称：

  Kretov,A.E.; Bespalyi,A.S., Journal of general chemistry of the USSR, 1963, vol. 33, p. 206 - 209

  摘要：

  DOI：

文献信息

• FUNGICIDAL MIXTURES
  申请人：Gregory Vann

  公开号：US20100240619A1

  公开（公告）日：2010-09-23

  Disclosed is a fungicidal composition comprising (a) at least one compound selected from the compounds of Formula 1 N-oxides, and salts thereof, wherein R 1 , R 2 , A, G, W, Z 1 , X, J, and n are as defined in the disclosure, and (b) at least one additional fungicidal compound. Also disclosed is a method for controlling plant diseases caused by fungal plant pathogens comprising applying to the plant or portion thereof, or to the plant seed, a fungicidally effective amount of the aforesaid composition. Also disclosed is a composition comprising component (a) of aforesaid composition and at least one insecticide. Also disclosed are compounds of Formula 1A, 1B and 1C, wherein R 1 , R 2 , A, G, W, Z 1 , X, J, n, Z 3 , M and J 1 are as defined in the disclosure.

  公开了一种含真菌化合物，包括：(a)至少一种选自公式1 N-氧化物的化合物，以及它们的盐类，其中R1，R2，A，G，W，Z1，X，J和n如公开所述定义，以及（b）至少一种额外的含真菌化合物。还公开了一种控制由真菌植物病原体引起的植物病害的方法，包括将有效量的前述组合物施用于植物或其部分，或施用于植物种子。还公开了一种组合物，包括前述组合物的组分(a)和至少一种杀虫剂。还公开了公式1A，1B和1C的化合物，其中R1，R2，A，G，W，Z1，X，J，n，Z3，M和J1如公开所述定义。
• One - pot synthesis of novel sulfur and selenium heterocycles by directed ortho-lithiation
  作者：S. W. Wright

  DOI：10.1002/jhet.5570380330

  日期：2001.5

  phosgene and the 1,2-dioxo-2-phenyl-2,3-dihydrobenzo[e][1,4,2]dithiazine-3-one ring system with thiophosgene. Use of selenium in place of sulfur afforded the novel analogous selenium heterocycles, however in the case of benzamides the use of selenium and phosgene afforded benzo[d]isoselenazol-3-ones unexpectedly.

  报道了通过直接锂化和用硫和光气顺序处理由苯甲酰胺合成苯并[ e ] [1,3]噻嗪-2,4-二酮的方法。使用硫光气可得到2-硫氧代-2,3-二氢-苯并[ e ] [1,3]噻嗪-4-酮。该方法在苯磺酰胺上的应用提供了以前未知的带有光气和1,2-二氧-2-的1,1-二氧-1,2-二氢-1,4-二硫-2-氮杂-萘-3-环体系-苯基-2,3-二氢苯并[ e ] [1,4,2]二噻嗪-3-具有硫光气的环系统。用硒代替硫提供了新颖的类似硒杂环，但是在苯甲酰胺的情况下，使用硒和光气意外地得到了苯并[ d ]异硒烯唑-3-酮。
• FUNGICIDAL HETEROCYCLIC COMPOUNDS
  申请人：Pasteris Robert James

  公开号：US20110224258A1

  公开（公告）日：2011-09-15

  Disclosed are compounds of Formula 1, including all geometric and stereoisomers, tautomers, N-oxides, and salts thereof, wherein R 1 , R 2 , R 3 , R 4 , R 5 , A, W, X, G, Z, J and n are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling plant disease caused by a fungal pathogen comprising applying an effective amount of a compound or a composition of the invention.

  本发明涉及一种公式1的化合物，包括其所有的几何和立体异构体、互变异构体、N-氧化物和盐，其中R1、R2、R3、R4、R5、A、W、X、G、Z、J和n的定义如本文所述。本发明还涉及包含公式1化合物的组合物，以及控制由真菌病原体引起的植物病害的方法，包括施用本发明中化合物或组合物的有效量。
• FUNGICIDAL OXIMES AND HYDRAZONES
  申请人：Hanagan Mary Ann

  公开号：US20130030002A1

  公开（公告）日：2013-01-31

  Disclosed are compounds of Formula 1, including all stereoisomers, N-oxides, and salts thereof, wherein E, X, G, W 2 and Z are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling plant disease caused by a fungal pathogen comprising applying an effective amount of a compound or a composition of the invention. Also disclosed are compounds of Formula 1A including all stereoisomers, N-oxides, and salts thereof, wherein E, X, G and Z 1 are as defined in the disclosure. Also disclosed is the use of the compounds of Formula 1A as intermediates for preparing compounds of Formula 1.

  本发明涉及公式1的化合物，包括所有立体异构体、N-氧化物和其盐，其中E、X、G、W2和Z如本公开说明书中所定义。还涉及含有公式1化合物的组合物以及控制由真菌病原体引起的植物病害的方法，包括施用本发明化合物或组合物的有效量。还涉及公式1A的化合物，包括所有立体异构体、N-氧化物和其盐，其中E、X、G和Z1如本公开说明书中所定义。还涉及将公式1A的化合物用作制备公式1化合物的中间体的用途。
• FUNGICIDAL AZOCYCLIC AMIDES
  申请人：Hanagan Mary Ann

  公开号：US20130261154A1

  公开（公告）日：2013-10-03

  Disclosed are compounds of Formula 1, including all stereoisomers, N-oxides, and salts thereof, wherein E, X, G, J, Z, and Q are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling plant disease caused by a fungal pathogen comprising applying an effective amount of a compound or a composition of the invention.

  本发明揭示了公式1的化合物，包括所有立体异构体，N-氧化物和其盐，其中E，X，G，J，Z和Q的定义如披露所述。本发明还揭示了含有公式1化合物的组合物，并且揭示了控制由真菌病原体引起的植物病害的方法，包括施用本发明的化合物或组合物的有效量。