1,1'-bis(1-indenyl)dimethylsilane | 240823-63-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 英文名称: 1,1'-bis(1-indenyl)dimethylsilane
• 英文别名: 1-indenyl-2-indenyl-dimethylsilane；1H-inden-1-yl-(1H-inden-2-yl)-dimethylsilane
• CAS: 240823-63-6
• 化学式: C₂₀H₂₀Si
• 分子量: 288.464
• InChiKey: KYQYKVMINKITOC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.22
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,1'-bis(1-indenyl)dimethylsilane 、 iron pentacarbonyl 以 正庚烷 为溶剂， 以6.8%的产率得到
  参考文献：
  名称：

  Synthesis and structure of sila-bridged bis(1-indenyl and tetrahydroindenyl) tetracarbonyl di-iron complex

  摘要：

  Sila-bridged bis(1-indenyl) tetracarbonyl di-iron complexes E[IndFe(CO)](2)(mu,-CO)(2) (E = Me2Si, 1; Me2SiOSiMe2, 2) have been synthesized by the reaction of Fe(CO)(5) and the corresponding sila-bridged bisindenyl ligands. Both 1 and 2 have cis and trans isomers. According to the different crystal shapes a small amount of pure cis isomer 1c and trans isomer 1t were separated mechanically. But only pure trans isomer 2t was obtained by recrystallization. 1 and 2t were hydrogenated in the presence of PtO2 at atmospheric pressure, and the corresponding tetrahydroindenyl complexes 3 and 4t were obtained respectively. After hydrogenation, pure cis isomer 3c and trans isomer 3t were separated by chromatography. The crystal structure of the trans isomer It was determined by X-ray diffraction. It shows that the unfused moieties of six-membered rings of indenyl ligands exist as a conjugated diene system. This explains that 1 and 2 can be readily hydrogenated to the tetrahydro-indenyl complexes even at atmospheric pressure. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00038-7

文献信息

• Synthesis and structure of sila-bridged bis(1-indenyl and tetrahydroindenyl) tetracarbonyl di-iron complex
  作者：Bai-Quan Wang、Shan-Sheng Xu、Xiu-Zhong Zhou

  DOI：10.1016/s0277-5387(97)00038-7

  日期：1997.1

  Sila-bridged bis(1-indenyl) tetracarbonyl di-iron complexes E[IndFe(CO)](2)(mu,-CO)(2) (E = Me2Si, 1; Me2SiOSiMe2, 2) have been synthesized by the reaction of Fe(CO)(5) and the corresponding sila-bridged bisindenyl ligands. Both 1 and 2 have cis and trans isomers. According to the different crystal shapes a small amount of pure cis isomer 1c and trans isomer 1t were separated mechanically. But only pure trans isomer 2t was obtained by recrystallization. 1 and 2t were hydrogenated in the presence of PtO2 at atmospheric pressure, and the corresponding tetrahydroindenyl complexes 3 and 4t were obtained respectively. After hydrogenation, pure cis isomer 3c and trans isomer 3t were separated by chromatography. The crystal structure of the trans isomer It was determined by X-ray diffraction. It shows that the unfused moieties of six-membered rings of indenyl ligands exist as a conjugated diene system. This explains that 1 and 2 can be readily hydrogenated to the tetrahydro-indenyl complexes even at atmospheric pressure. (C) 1997 Elsevier Science Ltd.