phenanthro[5',6':5,6]pyrazino[2,3-b]phenazine | 216-10-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: phenanthro[5',6':5,6]pyrazino[2,3-b]phenazine
• 英文别名: dibenzo[a,c]quinoxalino[2,3-i]phenazine；Dibenzo[a,c]chinoxalino[2,3-i]phenazin；Dibenzo[5,6:7,8]-quinoxalino-[2,3-i]phenazine；2,17,21,28-tetrazaheptacyclo[16.12.0.03,16.04,9.010,15.020,29.022,27]triaconta-1(30),2,4,6,8,10,12,14,16,18,20,22,24,26,28-pentadecaene
• CAS: 216-10-4
• 化学式: C₂₆H₁₄N₄
• 分子量: 382.424
• InChiKey: ZKWBVHXDAUWTJM-UHFFFAOYSA-N

物化性质

• 沸点：
  715.7±25.0 °C(Predicted)
• 密度：
  1.432±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  30
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,3-二氨基吩嗪 、 菲醌 以 溶剂黄146 为溶剂， 反应 5.0h， 以65%的产率得到phenanthro[5',6':5,6]pyrazino[2,3-b]phenazine
  参考文献：
  名称：

  On the Synthesis of Pyrazino[2,3-b]phenazine and 1H-Imidazo[4,5-b]phenazine Derivatives

  摘要：

  Several pyrazino[2,3-D]phenazine derivatives were prepared by the reaction of 2,3-diaminophenazine with different 1,2-diketones. Nucleophilic substitution of 2,3-dibromomethyl-pyrazino[2,3-b]phenazine with propanol, morpholine, and potassium thiocyanate gave 2,3-bis(propoxymethyl)-pyrazino[2,3-b]phenazine 2,3-bis-(4-morpholinylmethyl)-pyrazino[2,3-b]phenazine, and 2,3-bis-(cyanosulfanylmethyl)-pyrazino[2,3-b]phenazine. 2-Aryl-1H-imidazo[4,5-b]phenazine derivatives were synthesized by a one-pot reaction of 1,3-diaminophenazine with different aromatic aldehydes or acids. Reaction of 2,3-diaminophenazine with acetic anhydride and formic acid afforded 1H-imidazo[4,5-b]phenazine and 2-methyl-1H-imidazo[4,5-b]phenazine. Chemical and spectroscopic evidences for the product structures of the new compounds are presented.

  DOI：

  10.1007/pl00010183

文献信息

• Semiconductor composition comprising an inorganic semiconducting material and an organic binder
  申请人：Merck Patent GmbH

  公开号：US10326090B2

  公开（公告）日：2019-06-18

  The present invention relates to a semiconductor composition including an inorganic semiconducting material and an organic binder. The present invention further relates to an electronic device comprising a semiconducting layer consisting of such semiconductor composition.

  本发明涉及一种半导体组合物，包括一种无机半导体材料和一种有机粘合剂。本发明还涉及一种电子装置，该装置包括由这种半导体组合物构成的半导体层。
• Sircar; Dutt, Journal of the Indian Chemical Society, 1923, vol. 1, p. 205
  作者：Sircar、Dutt

  DOI：——

  日期：——
• Organic Thin Film Transistor Material, Organic Thin Film Transistor, Field-Effect Transistor, Switching Element, Organic Semiconductor Material and Organic Semiconductor Film
  申请人：Katakura Rie

  公开号：US20080121873A1

  公开（公告）日：2008-05-29

  An objective is to provide an organic thin film transistor material exhibiting an excellent property as a transistor together with reduced aging degradation, and also to provide an organic thin film transistor, a field-effect transistor, a switching element, an organic semiconductor material and an organic semiconductor film employing the organic thin film transistor material. Disclosed is an organic thin film transistor material possessing a compound represented by the following Formula (1). where A composed of a condensed ring formed with a 6 membered aromatic cycle or a 6 membered aromatic heterocycle represents C—R, N or P; at least one of As is N or P; R represents a hydrogen atom, a halogen atom or a substituent; and R may be bonded with other Rs with each other to form a ring.
• Semiconductor Composition Comprising an Inorganic Semiconducting Material and an Organic Binder
  申请人：Merck Patent GmbH

  公开号：US20170309848A1

  公开（公告）日：2017-10-26

  The present invention relates to a semiconductor composition comprising an inorganic semiconducting material and an organic binder. The present invention further relates to an electronic device comprising a semiconducting layer consisting of such semiconductor composition.
• [EN] SEMICONDUCTOR COMPOSITION COMPRISING AN INORGANIC SEMICONDUCTING MATERIAL AND AN ORGANIC BINDER<br/>[FR] COMPOSITION DE SEMI-CONDUCTEUR COMPRENANT UN MATÉRIAU SEMI-CONDUCTEUR INORGANIQUE ET UN LIANT ORGANIQUE
  申请人：MERCK PATENT GMBH

  公开号：WO2016050335A1

  公开（公告）日：2016-04-07

  The present invention relates to a semiconductor composition comprising an inorganic semiconducting material and an organic binder. The present invention further relates to an electronic device comprising a semiconducting layer consisting of such semiconductor composition.