N2-2-hydroxybenzalmethylene-O,O'-diethylphosphorohydrazonothionate | 443783-15-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: N2-2-hydroxybenzalmethylene-O,O'-diethylphosphorohydrazonothionate
• CAS: 443783-15-1
• 化学式: C₁₁H₁₇N₂O₃PS
• 分子量: 288.307
• InChiKey: DUJHNBHAQPEDLW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.61
• 重原子数：
  18.0
• 可旋转键数：
  7.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  63.08
• 氢给体数：
  2.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  N2-2-hydroxybenzalmethylene-O,O'-diethylphosphorohydrazonothionate 、 copper(II) acetate monohydrate 以 甲醇 为溶剂， 以67%的产率得到
  参考文献：
  名称：

  SYNTHESIS, STRUCTURE, AND BIOLOGICAL ACTIVITIES OF THEO,O′-DIETHYLPHOSPHOROHYDRAZONOTHIONATE LIGAND AND COMPLEXES WITH NICKEL(II), COPPER(II), AND ZINC(II)

  摘要：

  N-2-2-Hydroxybenzalmethylenc-O,O'-diethylphosphorohydra- zonothionate (HL) and its three complexes (ML2.H2O) with nickel(II), copper(II) and zinc(II) have been prepared and identified. The crystal structure of NiL2.H2O has been determined. Crystal data: triclinic, space group P1, a=12.064(4), b=8.692(2), c=7.184(2) Angstrom, alpha=101.34(3), beta=94.92(3), gamma=103.81(0)degrees, Z=1, V=710.3(3) Angstrom(3), D-c=1.448 g.cm(-3), mu=1.65 mm(-1), R=0.065, R-w=0.068. The coordination geometry of Ni(II) in the complex is almost a square-planar. The test results of biological activity have shown that these compounds possess some activities of scavenging superoxide free radicals, as acaricides and insecticides.

  DOI：

  10.1081/sim-120003790

文献信息

• SYNTHESIS, STRUCTURE, AND BIOLOGICAL ACTIVITIES OF THE<i>O</i>,<i>O</i>′-DIETHYLPHOSPHOROHYDRAZONOTHIONATE LIGAND AND COMPLEXES WITH NICKEL(II), COPPER(II), AND ZINC(II)
  作者：Xinde Zhu、Chenggang Wang、Wen Dong、Fahui Song、Zongqiu Hu、Yuanlin Dang、Hongmei Li、Zhaojie Liu

  DOI：10.1081/sim-120003790

  日期：2002.4.29

  N-2-2-Hydroxybenzalmethylenc-O,O'-diethylphosphorohydra- zonothionate (HL) and its three complexes (ML2.H2O) with nickel(II), copper(II) and zinc(II) have been prepared and identified. The crystal structure of NiL2.H2O has been determined. Crystal data: triclinic, space group P1, a=12.064(4), b=8.692(2), c=7.184(2) Angstrom, alpha=101.34(3), beta=94.92(3), gamma=103.81(0)degrees, Z=1, V=710.3(3) Angstrom(3), D-c=1.448 g.cm(-3), mu=1.65 mm(-1), R=0.065, R-w=0.068. The coordination geometry of Ni(II) in the complex is almost a square-planar. The test results of biological activity have shown that these compounds possess some activities of scavenging superoxide free radicals, as acaricides and insecticides.