3,3'-(1E,1'E)-propane-1,3-diylbis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)diphenol | 1165451-22-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 3,3'-(1E,1'E)-propane-1,3-diylbis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)diphenol
• CAS: 1165451-22-8
• 化学式: C₁₇H₁₈N₂O₂
• 分子量: 282.342
• InChiKey: DFNKWHHMXCFTLH-KLCVKJMQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.03
• 重原子数：
  21.0
• 可旋转键数：
  6.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  65.18
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  3,3'-(1E,1'E)-propane-1,3-diylbis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)diphenol 、 nickel(II) acetate tetrahydrate 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Unusual copper(II) coordination mode from a potential Schiff-base reaction

  摘要：

  The Schiff-base ligands (1-3) formed from the reaction of 3-hydroxybenzaldehyde with three alkyl diamines have been synthesised and characterised. They are stable both in solution and in the solid state for several weeks, with no degradation to the starting amines and aldehyde observed. The reactions of the three Schiff-base ligands with various MX2 salts (M = Cu, Ni or Zn; X = chloride, perchlorate or acetate) resulted in the cleavage of the imine bond and formation of metal-amine complexes, as well as the entrapment of a two coordinate CuCl2 molecule within the lattice in one particular case. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.10.029

文献信息

• Unusual copper(II) coordination mode from a potential Schiff-base reaction
  作者：Mary F. Mahon、John McGinley、A. Denise Rooney、John M.D. Walsh

  DOI：10.1016/j.ica.2008.10.029

  日期：2009.5

  The Schiff-base ligands (1-3) formed from the reaction of 3-hydroxybenzaldehyde with three alkyl diamines have been synthesised and characterised. They are stable both in solution and in the solid state for several weeks, with no degradation to the starting amines and aldehyde observed. The reactions of the three Schiff-base ligands with various MX2 salts (M = Cu, Ni or Zn; X = chloride, perchlorate or acetate) resulted in the cleavage of the imine bond and formation of metal-amine complexes, as well as the entrapment of a two coordinate CuCl2 molecule within the lattice in one particular case. (C) 2008 Elsevier B. V. All rights reserved.