indium(III) diisopropyldithiocarbamate | 85883-33-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: indium(III) diisopropyldithiocarbamate
• 英文别名: indium tris(N,N-diisopropyldithiocarbamate)；indium(III) tris(di-i-propyldithiocarbamate)；Indium diisopropyldithiocarbamate；N,N-di(propan-2-yl)carbamodithioate;indium(3+)
• CAS: 85883-33-6
• 化学式: C₂₁H₄₂InN₃S₆
• 分子量: 643.801
• InChiKey: NSEFUVBADHUYBF-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  7.38
• 重原子数：
  31
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  182
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  indium(III) diisopropyldithiocarbamate 以 neat (no solvent) 为溶剂， 生成 indium(III) sulfide
  参考文献：
  名称：

  铟 (III) 的 N,N'-二烷基二硫代氨基甲酸酯螯合物：替代合成路线和热力学表征

  摘要：

  摘要 制备铟(III)、In(S 2 CNR 2 ) 3 (R = CH 3 , C 2 H 5 , n -C 3 H 7 , i -C 3 H) 的 N , N '-二烷基二硫代氨基甲酸酯配合物的替代合成路线如图7所示，从金属元素和单卤化铟中建立了n -C 4 H 9 和i -C 4 H 9 )，InX(X = Cl、Br和I)。考虑到最初产生的 XIn(S 2 C–NR 2 ) 2 的配体再分配反应，涉及 InX 的拟议反应机制可能源自 InX 插入四烷基秋兰姆二硫化物的硫-硫键。In(S 2 CNR 2 ) 3 (R = CH 3 , C 2 H 5 , n -C 3 H 7 , i -C 3 H 7 , n -C 4 H 9 和 i -C 4 H 的热分解9 ) 通过热重技术研究化合物，其中检测到两种途径，这取决于二烷基二硫代氨基甲酸根配体。第一步导致金属铟，或者在 2 S 3 中，作为

  DOI：

  10.1016/s0040-6031(98)00646-7
• 作为产物：
  描述：

  indium 、 di-iso-propylammonium di-iso-propyl dithocarbamate 在 sodium hydroxide 作用下， 以 盐酸 、 丙酮 为溶剂， 以70.9%的产率得到indium(III) diisopropyldithiocarbamate
  参考文献：
  名称：

  Thermochemical parameters of dialkyldithiocarbamate chelates of indium(III)

  摘要：

  A series of dialkyldithiocarbamate chelates of indium(III) of the general formula In(S2CNR2)(3), (R = C2H5, n-C3H7, i-C3H7, n-C4H9 and i-C4H9), were prepared from the reaction of hydrochloric acid solution of metallic indium and the corresponding dialkylammonium salt of the ligand at pH = 3-4, giving yields better than 78%. The standard molar enthalpies of formation of crystalline dialkyldithiocarbamate chelates of In(III), were determined through reaction-solution calorimetry in acetone, at 298.15 K. The corresponding standard molar enthalpies of sublimation were estimated by means of differential scanning calorimetry. By combining of the values from these enthalpies, the standard molar enthalpies of formation in the gas were obtained. From the standard molar enthalpies of formation of the gaseous chelates the homolytic 191.9 +/- 3.6, 167.9 +/- 3.1, 136.4 +/- 2.5, 174.3 +/- 3.0 and 189.1 +/- 3.9 kJ mol(-1), and heterolytic 938.1 +/- 3.6, 961.9 +/- 3.1, 993.5 +/- 2.7, 1003.0 +/- 3.0 and 1047.3 +/- 3.9 kJ mol(-1), mean indium-sulphur bond-dissociation enthalpies were calculated. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0040-6031(99)00322-6

文献信息

• ——
  作者：A. G. Souza、M. M. Oliveira、I. M. G. Santos、M. M. Conceição、L. M. Nunes、J. C. Machado

  DOI：10.1023/a:1013971031425

  日期：——

  The kinetics of thermal decomposition of solid In(S2CNR2)(3) complexes, (R=CH3, C2H5, n-C3H7, i-C3H7, n-C4H9 and i-C4H9), has been studied using isothermal and non-isothermal thermogravimetry. Superimposed TG/DTG/DSC curves show that thermal decomposition reactions occur in the liquid phase, except for the In(S2CNMe2)(3) and In(S2CNPr2i)(3) compounds.
• Lindmark, Alan F.; Fay, Robert C., Inorganic Chemistry, 1983, vol. 22, # 14, p. 2000 - 2006
  作者：Lindmark, Alan F.、Fay, Robert C.

  DOI：——

  日期：——
• Bhattacharya, S.; Seth, Miss Neena; Gupta, V. D., Zeitschrift fur Naturforschung, B: Chemical Sciences, 1994, vol. 49, # 2, p. 193 - 198
  作者：Bhattacharya, S.、Seth, Miss Neena、Gupta, V. D.、Noeth, H.、Thomann, M.

  DOI：——

  日期：——
• N,N′-Dialkyldithiocarbamate chelates of indium(III): alternative synthetic routes and thermodynamics characterization
  作者：Marcelo M. Oliveira、Giuliana M. Pessoa、Ludmilla C. Carvalho、Clovis Peppe、Antonio G. Souza、Claudio Airoldi

  DOI：10.1016/s0040-6031(98)00646-7

  日期：1999.3

  Abstract Alternative synthetic routes to prepare N , N ′-dialkyldithiocarbamate complexes of indium(III), In(S 2 CNR 2 ) 3 (R = CH 3 , C 2 H 5 , n -C 3 H 7 , i -C 3 H 7 , n -C 4 H 9 and i -C 4 H 9 ) from the metallic element and from indium monohalides, InX(X = Cl, Br and I) were established. The proposed mechanism of reaction involving InX considering a ligand redistribution reaction of XIn(S 2 C–NR

  摘要 制备铟(III)、In(S 2 CNR 2 ) 3 (R = CH 3 , C 2 H 5 , n -C 3 H 7 , i -C 3 H) 的 N , N '-二烷基二硫代氨基甲酸酯配合物的替代合成路线如图7所示，从金属元素和单卤化铟中建立了n -C 4 H 9 和i -C 4 H 9 )，InX(X = Cl、Br和I)。考虑到最初产生的 XIn(S 2 C–NR 2 ) 2 的配体再分配反应，涉及 InX 的拟议反应机制可能源自 InX 插入四烷基秋兰姆二硫化物的硫-硫键。In(S 2 CNR 2 ) 3 (R = CH 3 , C 2 H 5 , n -C 3 H 7 , i -C 3 H 7 , n -C 4 H 9 和 i -C 4 H 的热分解9 ) 通过热重技术研究化合物，其中检测到两种途径，这取决于二烷基二硫代氨基甲酸根配体。第一步导致金属铟，或者在 2 S 3 中，作为
• Thermochemical parameters of dialkyldithiocarbamate chelates of indium(III)
  作者：Antonio Gouveia Souza、Marcelo Moizinho Oliveira、Amanda Duarte Gondim、Pedro Oliver Dunstan、Dulce Maria de A. Melo

  DOI：10.1016/s0040-6031(99)00322-6

  日期：2000.1

  A series of dialkyldithiocarbamate chelates of indium(III) of the general formula In(S2CNR2)(3), (R = C2H5, n-C3H7, i-C3H7, n-C4H9 and i-C4H9), were prepared from the reaction of hydrochloric acid solution of metallic indium and the corresponding dialkylammonium salt of the ligand at pH = 3-4, giving yields better than 78%. The standard molar enthalpies of formation of crystalline dialkyldithiocarbamate chelates of In(III), were determined through reaction-solution calorimetry in acetone, at 298.15 K. The corresponding standard molar enthalpies of sublimation were estimated by means of differential scanning calorimetry. By combining of the values from these enthalpies, the standard molar enthalpies of formation in the gas were obtained. From the standard molar enthalpies of formation of the gaseous chelates the homolytic 191.9 +/- 3.6, 167.9 +/- 3.1, 136.4 +/- 2.5, 174.3 +/- 3.0 and 189.1 +/- 3.9 kJ mol(-1), and heterolytic 938.1 +/- 3.6, 961.9 +/- 3.1, 993.5 +/- 2.7, 1003.0 +/- 3.0 and 1047.3 +/- 3.9 kJ mol(-1), mean indium-sulphur bond-dissociation enthalpies were calculated. (C) 2000 Elsevier Science B.V. All rights reserved.