hexyldecylamine | 20246-72-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: hexyldecylamine
• 英文别名: Decylhexylamin；n-Hexyldecylamine；N-hexyldecan-1-amine
• CAS: 20246-72-4
• 化学式: C₁₆H₃₅N
• mdl: MFCD19021573
• 分子量: 241.461
• InChiKey: NRVPFVVEJARADO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  17
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  正己胺 、 癸醇 在 gold nanoparticles supported on titanium dioxide (TiO₂) 作用下， 以 甲苯 为溶剂， 140.0 ℃ 、506.66 kPa 条件下， 反应 63.0h， 以50%的产率得到hexyldecylamine
  参考文献：
  名称：

  乙醇与酒精的高效清洁金催化一锅选择性N烷基化

  摘要：

  原子有效的直接N烷基化：在二氧化钛负载的金催化剂体系上，通过无水氢的自动转移途径，通过等摩尔的醇与胺等摩尔环境下的纯N烷基选择性N-烷基化反应，在没有添加剂的情况下，收率良好至优异（参见方案）。

  DOI：

  10.1002/chem.201001848

文献信息

• [EN] BISMUTH METALLIC (0) NANOPARTICLES, PROCESS OF MANUFACTURING AND USES THEREOF<br/>[FR] NANOPARTICULES DE BISMUTH MÉTALLIQUE (0), PROCÉDÉ DE FABRICATION ET UTILISATIONS DE CELLES-CI
  申请人：CONSERVATOIRE NAT DES ARTS ET METIERS CNAM

  公开号：WO2020007822A1

  公开（公告）日：2020-01-09

  The present invention relates to a process for manufacturing stable and monodisperse biocompatible bismuth metallic (0) nanoparticles, in aqueous solution, using a water-soluble bismuth precursor, a water-soluble reducing agent and a coating agent. The process can be carried out in continuous flow. The invention also relates to corresponding stable biocompatible bismuth metallic (0) nanoparticles having hydrophilic, hydrophobic or fluorophilic properties and uses thereof, especially medical applications thereof such as theranostic applications.

  本发明涉及一种制备稳定且单分散的生物相容性铋金属（0）纳米颗粒的工艺，使用水溶性铋前体、水溶性还原剂和包覆剂在水溶液中进行。该工艺可以在连续流中进行。该发明还涉及相应的具有亲水性、疏水性或亲氟性特性的稳定生物相容性铋金属（0）纳米颗粒及其用途，特别是医疗应用，如治疗应用。
• Fluorescent Sensor and Methods
  申请人：Snee Preston T.

  公开号：US20120094390A1

  公开（公告）日：2012-04-19

  Binding an analyte can cause a change in fluorescence emission of a sensor. The change in fluorescence can be related to the amount of analyte present. The sensor can include a semiconductor nanocrystal linked to a fluorescent moiety. Upon excitation, the fluorescent moiety can transfer energy to the semiconductor nanocrystal, or vice versa.

  分析物的结合可以导致传感器的荧光发射发生变化。荧光的变化可以与分析物的数量相关。传感器可以包括与荧光基团相连的半导体纳米晶体。在激发时，荧光基团可以将能量转移到半导体纳米晶体，反之亦然。
• Novel cyclic ureas as dermal penetration enhancers
  申请人：Merck & Co., Inc.

  公开号：EP0222664A2

  公开（公告）日：1987-05-20

  Certain novel cyclic ureas are disclosed herein as dermal penetration enhancers of drug absorption. Also disclosed herein are compositions, methods of treatment and processes for preparing said cyclic urea compounds.

  本文公开了某些新型环状脲类化合物，它们是促进药物吸收的皮肤渗透剂。 本文还公开了所述环状脲类化合物的组合物、治疗方法和制备工艺。
• Organopolysiloxane having amide group, and cosmetic material containing same
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2280040A1

  公开（公告）日：2011-02-02

  Provided are an organopolysiloxane that exhibits good dispersion stability within not only organic oil agents but also cosmetic materials that contain a powder, and is able to produce a cosmetic material that exhibits excellent skin affinity, an organopolysiloxane that does not impart a sticky feeling, and exhibits excellent skin affinity and skin adhesion, and a cosmetic material including such an organopolysiloxane. The organopolysiloxane is represented by formula (1) below: in which R1 represents a hydrocarbon group such as an alkyl group, R2 represents a group represented by formula (3) or formula (4) below: in which either R4 represents a specific hydrocarbon group and R5 represents a hydrogen atom or a specific hydrocarbon group, or alternatively, at least one of R4 and R5 represents a hydroxyalkyl group, and A represents a group containing an organosilyl group or organosiloxane residue.

  本发明提供了一种有机聚硅氧烷，该有机聚硅氧烷不仅在有机油剂中，而且在含有粉末的化妆品材料中都具有良好的分散稳定性，并且能够生产出具有优异皮肤亲和性的化妆品材料；一种不会产生粘腻感，并且具有优异皮肤亲和性和皮肤粘附性的有机聚硅氧烷；以及一种包括这种有机聚硅氧烷的化妆品材料。有机聚硅氧烷用下式（1）表示： 其中 R1 代表烃基，如烷基，R2 代表下式（3）或式（4）所代表的基团： 其中 R4 代表一个特定的烃基，R5 代表一个氢原子或一个特定的烃基，或者 R4 和 R5 中至少有一个代表羟烷基，以及 A 代表含有有机硅基团或有机硅氧烷残基的基团。
• ORGANOPOLYSILOXANE HAVING AMIDE GROUP, AND COSMETIC MATERIAL CONTAINING SAME
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP2921518A1

  公开（公告）日：2015-09-23

  Provided are an organopolysiloxane that exhibits good dispersion stability within not only organic oil agents but also cosmetic materials that contain a powder, and is able to produce a cosmetic material that exhibits excellent skin affinity, an organopolysiloxane that does not impart a sticky feeling, and exhibits excellent skin affinity and skin adhesion, and a cosmetic material including such an organopolysiloxane. The organopolysiloxane is represented by formula (1) below: in which R1 represents a hydrocarbon group such as an alkyl group, R2 represents a group represented by formula (3) or formula (4) below: in which either R4 represents a specific hydrocarbon group and R5 represents a hydrogen atom or a specific hydrocarbon group, or alternatively, at least one of R4 and R5 represents a hydroxyalkyl group, and A represents a group containing an organosilyl group or organosiloxane residue.

  本发明提供了一种有机聚硅氧烷，该有机聚硅氧烷不仅在有机油剂中，而且在含有粉末的化妆品材料中都具有良好的分散稳定性，并且能够生产出具有优异皮肤亲和性的化妆品材料；一种不会产生粘腻感，并且具有优异皮肤亲和性和皮肤粘附性的有机聚硅氧烷；以及一种包括这种有机聚硅氧烷的化妆品材料。有机聚硅氧烷用下式（1）表示： 其中 R1 代表烃基，如烷基，R2 代表下式（3）或式（4）所代表的基团： 其中 R4 代表特定的烃基，R5 代表氢原子或特定的烃基，或者 R4 和 R5 中至少有一个代表羟烷基，以及 A 代表含有有机硅基团或有机硅氧烷残基的基团。