3,6,8-Tri-tert-butyl-2-naphthol | 91928-41-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3,6,8-Tri-tert-butyl-2-naphthol
• 英文别名: 3,6,8-Tritert-butylnaphthalen-2-ol
• CAS: 91928-41-5
• 化学式: C₂₂H₃₂O
• 分子量: 312.495
• InChiKey: OWPRVXPSRNJURT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-萘酚 、 异丁烯 在 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 反应 6.0h， 以60%的产率得到3,6,8-Tri-tert-butyl-2-naphthol
  参考文献：
  名称：

  tert-Butylation of 3,6-di-tert-butyl-2-naphthol. Formation of 3,6,8-tri-tert-butyl-2-naphthol

  摘要：

  DOI：

  10.1021/jo00196a040

文献信息

• Method for producing an aldehyde
  申请人：Mitsubishi Chemical Corporation

  公开号：EP0503564A2

  公开（公告）日：1992-09-16

  A method for producing an aldehyde, which comprises reacting an olefinic compound with carbon monoxide and hydrogen in the presence of a Group VIII metal compound and an organic phosphite compound to produce a corresponding aldehyde, wherein an organic phosphite compound of the formula (I): wherein each of R1 and R2 which may be the same or different, is a 2-naphthyl group which may have a substituent, provided that at least one of R1 and R2 is a substituted 2-naphthyl group of the formula (II): wherein R4 is a C1-30 organic group, and each of Rs, R6, R7, R8 and R9 which may be the same or different, is a hydrogen atom or an organic group, and R3 is ① a 2-naphthyl group which may have a substituent, ② a phenyl group which may have a substituent, or ③ an alkyl group which may have a substituent, is used as said organic phosphite compound.

  一种生产醛的方法，包括在第八族金属化合物和有机亚磷酸酯化合物存在下，使烯烃化合物与一氧化碳和氢反应生成相应的醛，其中有机亚磷酸酯化合物为式(I)： 其中 R1 和 R2 可相同或不同，各自为可具有取代基的 2-萘基，条件是 R1 和 R2 中至少有一个是式(II)的取代 2-萘基： 其中 R4 是 C1-30 有机基团，Rs、R6、R7、R8 和 R9 中的每一个可以相同或不同，是氢原子或有机基团，R3 是①一个可以有取代基的 2-萘基，②一个可以有取代基的苯基，或③一个可以有取代基的烷基。
• Hydroformylation process and bisphosphite compound used therein
  申请人：Mitsubishi Chemical Corporation

  公开号：EP0518241A2

  公开（公告）日：1992-12-16

  A hydroformylation process for preparing a hydroformylated product by reacting an olefinic compound with hydrogen and carbon monoxide in the presence of a Group VIII metal catalyst, in the reaction of which there is present a phosphite compound having the formula (I),         A¹⁅O-P(OR¹)(OR²)]n   (I) wherein R¹ and R² are respectively an aromatic hydrocarbon group which may be the same or different and the aromatic hydrocarbon group has at least a hydrocarbon group on a carbon atom adjacent to a carbon atom bonded with an oxygen atom as a substituent; A¹ is an n-valent organic group having an aliphatic hydrocarbon group, a cycloaliphatic hydrocarbon group or an aromatic hydrocarbon group bonded with an adjacent oxygen atom, which may respectively have a substituent; n is an integer of from 2 to 4; and the respective         ⁅O-P(OR¹)(OR²)] group may be the same or different.

  一种加氢甲酰化工艺，在第八族金属催化剂存在下，通过使烯烃化合物与氢气和一氧化碳反应制备加氢甲酰化产物，在反应中存在具有式（I）的亚磷酸酯化合物、 A¹⁅O-P(OR¹)(OR²)]n (I) 其中 R¹ 和 R² 分别是芳香烃基团，可以相同或不同，芳香烃基团在与氧原子键合的碳原子相邻的碳原子上至少有一个烃基作为取代基；A¹ 是具有脂肪族烃基、环脂族烃基或与相邻氧原子键合的芳香烃基的 n 价有机基团，可分别具有取代基；n 是 2 至 4 的整数；以及各自的 ⁅o-p(或¹)(或²) 组可能相同，也可能不同。
• Assignments of the carbon resonances in tert-butylated 2-naphthols by the two-dimensional carbon-relayed hydrogen,carbon-COSY technique
  作者：Horst Kessler、Wolfgang Bermel、Christian Griesinger、Peter Hertl、Edgar Streich、Anton Rieker

  DOI：10.1021/jo00355a005

  日期：1986.3
• Braddock, Christopher D; Tucker, Sonia C; Brown, John M, Bulletin de la Societe Chimique de France, 1997, vol. 134, # 3-4, p. 399 - 410
  作者：Braddock, Christopher D、Tucker, Sonia C、Brown, John M

  DOI：——

  日期：——
• US4501684A
  申请人：——

  公开号：US4501684A

  公开（公告）日：1985-02-26