Tetramethylammonium-tert-butylat | 17671-11-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Tetramethylammonium-tert-butylat
• 英文别名: 2-Methylpropan-2-olate;tetramethylazanium；2-methylpropan-2-olate;tetramethylazanium
• CAS: 17671-11-3
• 化学式: C₄H₉O*C₄H₁₂N
• 分子量: 147.261
• InChiKey: RBFUQQCIMVAVRI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.47
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  23.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Tetramethylammonium-tert-butylat 、 N-tosyl-(2,2-dimethyl)-pent-4-enylamine 在 双(乙腈)氯化钯(II) 、 (R)-2-(6-benzhydrylpyridin-2-yl)-4-phenyl-4,5-dihydrooxazole 、 Selectfluor 作用下， 以 乙腈 为溶剂， 以69%的产率得到
  参考文献：
  名称：

  使用CsOCF3作为三氟甲醇源，钯（II）催化未活化烯烃的对映选择性氨基三氟甲氧基化

  摘要：

  已开发出使用容易获得且稳定的CsOCF 3作为三氟甲醇源的未活化烯烃的不对称Pd II催化的分子内氨基三氟甲氧基化反应，可提供高收率的多种对映异构体富集的含β-取代的OCF 3的哌啶。在吡啶-恶唑啉（Pyox）配体中引入空间庞大的基团对于提高反应的反应性和对映选择性至关重要。另外，该反应具有良好的官能团相容性和温和的反应条件。

  DOI：

  10.1002/anie.201813591
• 作为产物：
  描述：

  四甲基氯化铵 、 叔丁醇 生成 Tetramethylammonium-tert-butylat
  参考文献：
  名称：

  Sekiguchi,H.; Tsourkas-Rapacouli,P., Bulletin de la Societe Chimique de France, 1974, p. 2585 - 2588

  摘要：

  DOI：

文献信息

• COMPOUND HAVING ALICYCLIC STRUCTURE, (METH)ACRYLIC ACID ESTER, AND PROCESS FOR PRODUCTION OF THE (METH)ACRYLIC ACID ESTER
  申请人：Tanaka Shinji

  公开号：US20110009661A1

  公开（公告）日：2011-01-13

  Provided are an alicyclic structure-containing compound, a (meth)acrylate, and a method for producing the ester. The compound and the ester are useful as a monomer and the like for a photoresist used in semiconductor manufacturing and excellent in solubility, compatibility, defect reduction, roughness improvement, and the like, realized by using an alicyclic structure-containing compound containing a linking group having an ester bond and/or a linking group having an ether bond, a (meth)acrylate derived from the alicyclic structure-containing compound, and a method for producing the ester.

  提供了一种含有脂环结构的化合物，一种（甲基）丙烯酸酯，以及一种生产酯的方法。该化合物和酯可用作半导体制造中用于光刻胶的单体等，并通过使用含有酯键的连接基团和/或含有醚键的连接基团的脂环结构化合物衍生的（甲基）丙烯酸酯，以及生产酯的方法，实现了在溶解性、相容性、缺陷减少、粗糙度改善等方面表现出色。
• Composition of vinyl ether group-containing (meth) acrylic acid ester and production method thereof
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：US20020143120A1

  公开（公告）日：2002-10-03

  It is an object of the present invention to provide a vinyl ether group-containing (meth)acrylic ester, which has both radical polymerizability and cation polymerizability, improved in storage stability and stability in handling without impairing its polymerizability or, in other words, provide a stabilized vinyl ether group-containing (meth)acrylic ester. Another object is to provide a method of producing a stabilized vinyl ether group-containing (meth)acrylic ester composition. A further object is to provide a method of stably handing, a method of economically and stably producing and a method of purifying a vinyl ether group-containing (meth)acrylic ester. A vinyl ether group-containing (meth)acrylic ester composition which comprises a radical polymerization inhibitor and a vinyl ether group-containing (meth)acrylic ester represented by the following general formula (1): CH2=CR1-COO—R2-O—CH═CH—R3  (1) in the formula, R1 represents a hydrogen atom or a methyl group, R2 represents an organic residue and R3 represents a hydrogen atom or an organic residue.

  本发明的目的是提供一种含乙烯基醚基的(甲基)丙烯酸酯，它同时具有自由基聚合性和阳离子聚合性，在不影响其聚合性的情况下，提高了储存稳定性和处理稳定性，或者换句话说，提供一种稳定的含乙烯基醚基的(甲基)丙烯酸酯。另一个目的是提供一种生产稳定的含乙烯基醚基（甲基）丙烯酸酯组合物的方法。另一个目的是提供一种稳定处理含乙烯基醚基（甲基）丙烯酸酯的方法、一种经济稳定地生产含乙烯基醚基（甲基）丙烯酸酯的方法和一种提纯含乙烯基醚基（甲基）丙烯酸酯的方法。 一种含乙烯基醚基（甲基）丙烯酸酯组合物，它包括自由基聚合抑制剂和由以下通式（1）表示的含乙烯基醚基（甲基）丙烯酸酯： CH2=CR1-COO-R2-O-CH═CH-R3 (1) 式中，R1 代表氢原子或甲基，R2 代表有机残基，R3 代表氢原子或有机残基。
• Composition of vinyl ether group containing (meth)acrylic acid ester and production method thereof
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP1201641B1

  公开（公告）日：2013-08-14
• COMPOSITION OF VINYL ETHER GROUP CONTAINING (METH) ACRYLIC ACID ESTER AND PRODUCTION METHOD THEREOF
  申请人：Yurugi Keiji

  公开号：US20070049768A1

  公开（公告）日：2007-03-01

  It is an object of the present invention to provide a vinyl ether group-containing, (meth)acrylic ester, which has both radical polymerizability and cation polymerizability, improved in storage stability and stability in handling without impairing its polymerizability or, in other words, provide a stabilized vinyl ether group-containing (meth)acrylic ester. Another object is to provide a method of producing a stabilized vinyl ether group-containing (meth)acrylic ester composition. A further object is to provide a method of stably handing, a method of economically and stably producing and a method of purifying a vinyl ether group-containing (meth)acrylic ester. A vinyl ether group-containing (meth)acrylic ester composition which comprises a radical polymerization inhibitor and a vinyl ether group-containing (meth)acrylic ester represented by the following general formula (1): CH2=CR1-COO—R2-0-CH—CH—R3  (1) in the formula, R1 represents a hydrogen atom or a methyl group, R2 represents an organic residue and R3 represents a hydrogen atom or an organic residue.
• US5914427A
  申请人：——

  公开号：US5914427A

  公开（公告）日：1999-06-22