1-imino-2-phenyl-1H-inden-3-amine | 4995-90-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 英文名称: 1-imino-2-phenyl-1H-inden-3-amine
• 英文别名: 1-imino-2-phenyl-1H-indene-3-amine；3-Amino-1-imino-2-phenyl-inden；3-Amino-1-imino-2-phenyl-inden-(2)；3-Amino-1-imino-2-phenylinden；3-imino-2-phenylinden-1-amine
• CAS: 4995-90-8
• 化学式: C₁₅H₁₂N₂
• 分子量: 220.274
• InChiKey: TYRCYFNVVCLSBB-UHFFFAOYSA-N

物化性质

• 熔点：
  180-181 °C
• 沸点：
  408.2±45.0 °C(Predicted)
• 密度：
  1.20±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  49.9
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-imino-2-phenyl-1H-inden-3-amine 在 盐酸 作用下， 以 乙醇 、 水 为溶剂， 反应 44.0h， 生成 苯茚二酮
  参考文献：
  名称：

  Synthesis and properties of macroheterocyclic compounds containing 1-imino-2-phenyl-1H-inden-3-amine fragments

  摘要：

  DOI：

  10.1134/s107036321407010x

文献信息

• Macrocyclic Compounds with 2-Phenylindene Fragments. Synthesis and Properties
  作者：G. R. Berezina

  DOI：10.1134/s1070363218060154

  日期：2018.6

  By the reaction of 1-imino-2-phenyl-1H-indene-3-amine with 1,4-naphthylenediamine and 1,4-diaminonaphthalenesulfonic acid linear products of 1 : 2 and 2 : 1 condensation as well as macrocyclic compounds were synthesized.

  通过1-亚氨基-2-苯基-1H-茚-3-胺与1,4-萘二胺和1,4-二氨基萘磺酸的反应，缩合后的线性产物为1：2和2：1，以及大环化合物合成的。
• Synthesis and investigation of physicochemical properties of macrocyclic compounds with fragments of n,n′-diamines of biaryl series
  作者：G. R. Berezina、K. D. Kuptsova、N. M. Berezina

  DOI：10.1134/s1070428015020220

  日期：2015.2

  Linear condensation products and macrocyclic compounds of symmetric structure were synthesized by reacting of aminoimino-2-phenylindandione with biphenyl-4,4'-diamine, 4,4'-sulfandiyldianiline, and 4,4'-oxydianiline. The obtained compounds were characterized by IR, UV, and H-1 NMR spectroscopy.
• Thermodynamics of the Dissolution of Macrocyclic Compounds Based on 2-Phenylindene with Naphthylenediamine Fragments in DMF and Ethanol
  作者：G. R. Berezina

  DOI：10.1134/s0036024419050054

  日期：2019.5

  The solubilities of compounds based on 1-imino-2-phenyl-1H-indene-3-amine with 1,4-diaminonaphthalene and 1,4-diaminonaphthalene-5-sulfonic acid fragments in DMF and ethanol at 298-318 K are studied via isothermal saturation with spectrophotometric monitoring of their concentrations. Patterns of the dissolution of 1:2, 2:1, and 2:2 products of condensation in DMF and ethanol are discussed. The thermodynamic parameters of the dissolution of the synthesized compounds were calculated.
• Macroheterocyclic Compounds with Thiadiazole Fragments. Synthesis and Properties
  作者：G. R. Berezina

  DOI：10.1134/s1070363218010139

  日期：2018.1

  The reactions of 1-imino-2-phenyl-1H-inden-3-amine with 3,5-diamino-1,2,4- and 2,5-diamino-1,3,4- thiadiazoles were used to synthesize linear 1: 2 and 2: 1 condensation products, as well as symmetrical macroheterocyclic compounds. The synthesized compounds were characterized by IR, UV, and (1)De NMR spectroscopy.
• Thermodynamics of the Dissolution of Macroheterocyclic 2-Phenylindene Derivatives with Thiadiazole Fragments in Dimethylformamide and Ethanol
  作者：G. R. Berezina、N. M. Berezina

  DOI：10.1134/s0036024418080071

  日期：2018.8

  The dissolution of compounds based on 1-imino-2-phenyl-1H-inden-3-amine with fragments of 3, 5-diamino- 1,2,4- and 2,5-diamino-1,3,4-thiadiazoles in DMF and ethanol is investigated by means of isothermal saturation with spectrophotometric concentration monitoring in the temperature range of 298-318 K. Characteristics of the dissolution of the products of condensation with compositions 1 : 2, 2 : 1, and 2 : 2 in individual solvents are presented. Thermodynamic parameters of the dissolution of the synthesized compounds are calculated.