Trichloro-methanesulfinic acid tert-butylamide | 187835-90-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: Trichloro-methanesulfinic acid tert-butylamide
• 英文别名: N-tert-butyl-1,1,1-trichloromethanesulfinamide
• CAS: 187835-90-1
• 化学式: C₅H₁₀Cl₃NOS
• 分子量: 238.566
• InChiKey: XZBAANMDDMFFLM-UHFFFAOYSA-N

物化性质

• 沸点：
  246.6±50.0 °C(Predicted)
• 密度：
  1.457±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  48.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,3-二甲基-1,3-丁二烯 、 Trichloro-methanesulfinic acid tert-butylamide 在 base 作用下， 以 苯 为溶剂， 反应 80.0h， 生成
  参考文献：
  名称：

  A new synthesis of N-sulfinylamines via β-elimination of chloroform from trichloromethanesulfinamides

  摘要：

  The synthesis of various N-monosubstituted trichloromethanesulfinamides by two alternative and novel procedures is described. All these compounds have been found to undergo base-induced elimination of chloroform with formation of the corresponding N-sulfinylamines. Reaction proceeds smoothly under mild conditions. Copyright (C) 1996 Published by Elsevier Science Ltd

  DOI：

  10.1016/s0040-4039(96)02351-9
• 作为产物：
  描述：

  三氯甲基磺酰氯 、 叔丁胺 在 三乙胺 、 三甲氧基磷 作用下， 以 二氯甲烷 为溶剂， 以71%的产率得到Trichloro-methanesulfinic acid tert-butylamide
  参考文献：
  名称：

  A new synthesis of N-sulfinylamines via β-elimination of chloroform from trichloromethanesulfinamides

  摘要：

  The synthesis of various N-monosubstituted trichloromethanesulfinamides by two alternative and novel procedures is described. All these compounds have been found to undergo base-induced elimination of chloroform with formation of the corresponding N-sulfinylamines. Reaction proceeds smoothly under mild conditions. Copyright (C) 1996 Published by Elsevier Science Ltd

  DOI：

  10.1016/s0040-4039(96)02351-9

文献信息

• A new synthesis of N-sulfinylamines via β-elimination of chloroform from trichloromethanesulfinamides
  作者：Samuel Braverman、Marina Cherkinsky

  DOI：10.1016/s0040-4039(96)02351-9

  日期：1997.1

  The synthesis of various N-monosubstituted trichloromethanesulfinamides by two alternative and novel procedures is described. All these compounds have been found to undergo base-induced elimination of chloroform with formation of the corresponding N-sulfinylamines. Reaction proceeds smoothly under mild conditions. Copyright (C) 1996 Published by Elsevier Science Ltd