Bis-acetylaceton-tetramethylendiimin | 87046-64-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Bis-acetylaceton-tetramethylendiimin
• 英文别名: 4-[4-(4-Oxopentan-2-ylideneamino)butylimino]pentan-2-one
• CAS: 87046-64-8
• 化学式: C₁₄H₂₄N₂O₂
• 分子量: 252.357
• InChiKey: UDVOETZXBOGXTH-UHFFFAOYSA-N

物化性质

• 沸点：
  379.6±37.0 °C(Predicted)
• 密度：
  0.97±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  18
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  58.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  nickel (II) chloride hexahydrate 、 Bis-acetylaceton-tetramethylendiimin 以 甲醇 、 水 为溶剂， 生成 [Ni(bis(acetylacetonato)butylene-1,4-diimine)]
  参考文献：
  名称：

  Binary Roles of Schiff Bases as Capping Agent and Precursor for Synthesis of Metallic Nickel Ultrafine Nanoparticles

  摘要：

  This study focused on the synthesis and characterization of nickel nanoparticles by simple precipitation method. The various Schiff bases such as ethylenediamine (acacen), 1,3-propylenediamine (acacpn), and butane-1,4-diamine (acacbn) acetyl acetonate were prepared and were used for preparing of nickel-Schiff base complexes and then, these complexes as precursor were reduced in the presence of KBH4, for the first time. In addition, the anti-aggregation effect of prepared Schiff bases was compared with common surfactants and results demonstrated that the huge ligands can be considered as novel surfactants. The obtained nickel nanoparticles were characterized by XRD, TEM, HRTEM, FT-IR, SEM, and EDS.

  DOI：

  10.1080/15533174.2013.862824
• 作为产物：
  描述：

  四亚甲基二胺 、 乙酰丙酮 以 乙醇 为溶剂， 反应 2.0h， 生成 Bis-acetylaceton-tetramethylendiimin
  参考文献：
  名称：

  Panova, G. V.; Potapov, V. M.; Turovets, I. M., Journal of general chemistry of the USSR, 1983, vol. 53, # 7, p. 1452 - 1458

  摘要：

  DOI：

文献信息

• Panova, G. V.; Potapov, V. M.; Turovets, I. M., Journal of general chemistry of the USSR, 1983, vol. 53, # 7, p. 1452 - 1458
  作者：Panova, G. V.、Potapov, V. M.、Turovets, I. M.、Golub, E. G.

  DOI：——

  日期：——
• Binary Roles of Schiff Bases as Capping Agent and Precursor for Synthesis of Metallic Nickel Ultrafine Nanoparticles
  作者：F. Motahari、M.-R. Mozdianfard、F. Soofivand、M. Salavati-Niasari

  DOI：10.1080/15533174.2013.862824

  日期：2015.10.3

  This study focused on the synthesis and characterization of nickel nanoparticles by simple precipitation method. The various Schiff bases such as ethylenediamine (acacen), 1,3-propylenediamine (acacpn), and butane-1,4-diamine (acacbn) acetyl acetonate were prepared and were used for preparing of nickel-Schiff base complexes and then, these complexes as precursor were reduced in the presence of KBH4, for the first time. In addition, the anti-aggregation effect of prepared Schiff bases was compared with common surfactants and results demonstrated that the huge ligands can be considered as novel surfactants. The obtained nickel nanoparticles were characterized by XRD, TEM, HRTEM, FT-IR, SEM, and EDS.