oxetane dimethanol divinyl ether | 1060769-86-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环丁烷
• 英文名称: oxetane dimethanol divinyl ether
• 英文别名: 3,3-bis(vinyloxymethyl)oxetane；3,3-bis(ethenoxymethyl)oxetane
• CAS: 1060769-86-9
• 化学式: C₉H₁₄O₃
• 分子量: 170.208
• InChiKey: HOFHXVDIJXEBAV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3,3-氧杂环丁烷二甲醇 、 乙酸乙烯酯 在 bis(1,5-cyclooctadiene)diiridium(I) dichloride sodium carbonate 、 丙酸 作用下， 以 甲苯 为溶剂， 以90%的产率得到oxetane dimethanol divinyl ether
  参考文献：
  名称：

  Vinyl ether compounds and polymerizable compositions

  摘要：

  揭示了一种含氧杂环乙烯醚化合物，包括一个或多个芳香或非芳香碳环和/或两个或更多个乙烯醚结构，例如Formula公式的化合物： 其中环Z1为非芳香碳环；Ra为Formula公式的乙烯基： 其中R1、R2和R3中的每一个是氢或C1-C4烷基；Wa为单键或具有(m+1)价的有机基团；X1为例如烃基；"m"和"q"各自为1或2；"p"为0至5。还揭示了一种含脂环氧基的乙烯醚化合物，其Formula为： 其中环Z2为非芳香碳环；Rb为Formula公式的乙烯基： 其中R4、R5和R6中的每一个为氢或C1-C4烷基；Wb为单键或具有(r+1)价的有机基团；Rc和Rd为氢或烷基；"r"和"s"为1或2。

  公开号：

  EP1972622A3

文献信息

• CATIONICALLY POLYMERIZABLE RESIN COMPOSITION AND CURED OBJECT OBTAINED THEREFROM
  申请人：Funaki Yoshinori

  公开号：US20120077946A1

  公开（公告）日：2012-03-29

  Disclosed is a cationically polymerizable resin composition which includes an oxetane-ring-containing vinyl ether compound (A) and/or an alicyclic-epoxy-containing vinyl ether compound (B); and an oligomer or polymer (C) having a molecular weight of 500 or more, being liquid at 0° C., and containing at least one of structures represented by following Formulae (1a) to (1f), wherein R x represents hydrogen atom or methyl group; R 1 to R 3 each independently represent a hydrocarbon group having 1 to 5 carbon atoms; “a” is an integer of from 0 to 5; and “b” is 1 or 2. This cationically polymerizable resin composition has a low viscosity, is easy to work, cures extremely rapidly upon irradiation with light, and can give a cured object excellent in flexibility, thermal stability, and bendability after heat treatment.

  本发明公开了一种阳离子聚合树脂组合物，包括含氧杂环环氧基乙烯醚化合物（A）和/或含脂环氧基乙烯醚化合物（B）；以及具有分子量为500或更高、在0℃下为液态，并含有下式（1a）至（1f）所表示的结构中至少一种的寡聚物或聚合物（C），其中Rx代表氢原子或甲基基团；R1至R3各自独立地表示具有1至5个碳原子的烃基；“a”为0至5的整数；“b”为1或2。该阳离子聚合树脂组合物具有低粘度、易于加工，经光辐照后固化极快，经热处理后可以给出具有优异的柔性、热稳定性和可弯曲性的固化物。
• CATION-POLYMERIZABLE RESIN COMPOSITION AND CURED PRODUCT THEREOF
  申请人：Yoshida Tsukasa

  公开号：US20120027342A1

  公开（公告）日：2012-02-02

  Provided is a cationically polymerizable resin composition which has a low viscosity, is easy to work, and is extremely rapidly cured upon irradiation with light to give a cured product excellent in optical transparency, flexibility, thermal stability, and post-heating bendability. The cationically polymerizable resin composition includes an oxetane-ring-containing vinyl ether compound (A) and/or an alicyclic-epoxy-group-containing vinyl ether compound (B); an oligomer or polymer (C) containing, in the molecule, at least one selected from oxetane group, epoxy group, hydroxyl group, vinyl ether group, and an aliphatic or alicyclic unsaturated hydrocarbon group and having a molecular weight of 500 or more; and an oxetane compound (D) containing no vinyl ether group and having 6 or more carbon atoms.

  提供了一种阳离子聚合树脂组合物，具有低粘度、易于操作，并在光照辐射下极快地固化，形成的固化产物具有优异的光学透明度、柔韧性、热稳定性和后热弯曲性。该阳离子聚合树脂组合物包括含氧杂环环氧基乙烯醚化合物(A)和/或含脂环氧基团的乙烯醚化合物(B)；分子中含有至少一种氧杂环基、环氧基、羟基、乙烯基醚基和脂肪或脂环烯烃基且分子量为500或更高的低聚物或聚合物(C)；以及不含乙烯基醚基且碳原子数为6或更多的氧杂环化合物(D)。
• Cationically polymerizable resin composition and cured object obtained therefrom
  申请人：Funaki Yoshinori

  公开号：US08975349B2

  公开（公告）日：2015-03-10

  Disclosed is a cationically polymerizable resin composition which includes an oxetane-ring-containing vinyl ether compound (A) and/or an alicyclic-epoxy-containing vinyl ether compound (B); and an oligomer or polymer (C) having a molecular weight of 500 or more, being liquid at 0° C., and containing at least one of structures represented by following Formulae (1a) to (1f), wherein Rx represents hydrogen atom or methyl group; R1 to R3 each independently represent a hydrocarbon group having 1 to 5 carbon atoms; “a” is an integer of from 0 to 5; and “b” is 1 or 2. This cationically polymerizable resin composition has a low viscosity, is easy to work, cures extremely rapidly upon irradiation with light, and can give a cured object excellent in flexibility, thermal stability, and bendability after heat treatment.

  揭示了一种阳离子聚合树脂组合物，其包括含有氧杂环环氧基的乙烯醚化合物（A）和/或含有脂环氧基的乙烯醚化合物（B）;以及具有分子量为500或更高，在0℃液态，并含有以下式（1a）至（1f）所表示的结构中至少一个的寡聚物或聚合物（C），其中Rx代表氢原子或甲基基团；R1至R3各自独立地表示具有1至5个碳原子的烃基；“a”是从0到5的整数；“b”为1或2。该阳离子聚合树脂组合物具有低粘度，易于加工，在受光照射后极快地固化，并且在热处理后可以给出具有优异的柔韧性、热稳定性和可弯性的固化物。
• CURABLE COMPOSITION, CURED PRODUCT THEREOF, OPTICAL MEMBER AND OPTICAL DEVICE
  申请人：DAICEL CORPORATION

  公开号：US20150212300A1

  公开（公告）日：2015-07-30

  An object of the present invention is to provide a curable composition that can be cured satisfactorily and can form a cured product having a high glass transition temperature as maintained and having high mechanical strength. A curable composition includes a siloxane (A), a cycloaliphatic epoxide (B), and a curing agent (C). The siloxane (A) contains at least two epoxy groups per molecule. The cycloaliphatic epoxide (B) in the curable composition is preferably a compound represented by Formula (I): wherein X is selected from a single bond and a linkage group.

  本发明的目的是提供一种可治愈组合物，该组合物可以被满意地治愈，并且可以形成一个具有高玻璃转移温度和高机械强度的固化产物。该可固化组合物包括硅氧烷（A）、环状脂肪族环氧化合物（B）和固化剂（C）。硅氧烷（A）每个分子含有至少两个环氧基团。可固化组合物中的环状脂肪族环氧化合物（B）最好是由式（I）表示的化合物：其中X选自单键和连接基团。
• CURABLE EPOXY RESIN COMPOSITION AND CURED PRODUCT THEREOF, DIOLEFIN COMPOUND AND PRODUCTION METHOD THEREFOR, AND PRODUCTION METHOD FOR DIEPOXY COMPOUND
  申请人：DAICEL CORPORATION

  公开号：US20160122466A1

  公开（公告）日：2016-05-05

  An object of the present invention is to provide a curable epoxy resin composition, which is cured to provide a cured product having a high glass-transition temperature and particularly having excellent balance between heat resistance and transparency. The present invention relates to a curable epoxy resin composition comprising an alicyclic epoxy compound (A) represented by the following formula (1) and a curing agent (B), or a curable epoxy resin composition comprising an alicyclic epoxy compound (A) represented by the following formula (1) and a curing catalyst (C). wherein R 1 to R 22 , which may be the same or different, each represent a hydrogen atom, a methyl group or an ethyl group; and m and n, which may be the same or different, each represent an integer of 1 to 4.

  本发明的目的是提供一种可固化的环氧树脂组合物，其固化后形成具有高玻璃转变温度和特别具有热稳定性和透明度之间优异平衡的固化产物。本发明涉及一种可固化的环氧树脂组合物，包括由以下式（1）表示的脂环族环氧化合物（A）和固化剂（B），或包括由以下式（1）表示的脂环族环氧化合物（A）和固化催化剂（C）的可固化环氧树脂组合物。其中，R1到R22，可以相同也可以不同，分别表示氢原子、甲基基团或乙基基团；m和n，可以相同也可以不同，分别表示1到4的整数。