lead(II) picrate | 6477-64-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: lead(II) picrate
• 英文别名: lead picrate；picric acid ; lead picrate；Pb picrate；Picrinsaeure; Bleipicrat；6,8-dinitro-1,3,4,2λ2-benzodioxazaplumbin-4-ium 4-oxide
• CAS: 6477-64-1；25721-38-4
• 化学式: 2C₆H₂N₃O₇*Pb
• 分子量: 663.396
• InChiKey: RSEYKXHXKFYCJJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  17.0
• 可旋转键数：
  3.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  152.48
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  lead(II) picrate 、 1,3-thiacalix[4]arene-bis-crown[6] ether 以 二氯甲烷 、 水 为溶剂， 生成 [Pb(1,3-thiacalix[4]arene-bis-crown[6] ether)](2+)
  参考文献：
  名称：

  硫杯芳烃的离子识别：硫杯[4]芳烃-双冠[n]醚对碱金属和重金属离子的结合

  摘要：

  通过提取实验检查了两种硫杯 [4] 芳烃-双冠 [n] 衍生物（n = 5 和 6）的结合特性。测定所得配合物在甲醇中的稳定性常数。用硫原子取代桥接 CH2 基团导致碱金属离子的萃取和络合水平大大降低，但不影响冠醚系列内的选择性。从thiacalix[4]arene-bis-crown[n]醚到它们的calix[4]arene-bis-crown[n]对应物时，与重金属离子的配合物的稳定性没有显着变化；因此，无法得出关于这些阳离子与硫原子之间可能相互作用的明确结论。

  DOI：

  10.1023/b:rucb.0000046253.11118.9e
• 作为产物：
  描述：

  苦味酸 在 水 、 lead(II) oxide 作用下， 生成 lead(II) picrate
  参考文献：
  名称：

  DE386617

  摘要：

  公开号：

文献信息

• Synthesis, characterization and extraction studies of a new vic-dioxime and its complexes containing bis(diazacrown ether) moieties
  作者：Ahmet Bilgin、Beytullah Ertem、Fatma Dinç Ağın、Yaşar Gök、Selami Karslıoğlu

  DOI：10.1016/j.poly.2006.05.023

  日期：2006.11

  A mononuclear nickel(II) and copper(II) complexes with a metal:ligand ratio of 1:2 for H2L were also synthesized. The mononuclear cobalt(III) complex of H2L has been isolated with L′ = pyridine, together with chlorine as an axial ligand. In addition, a cobalt(III) complex containing the BF2+ bridge macrocycle was synthesized using a precursor hydrogen-bridged cobalt(III) complex via the template effect

  一种新的连二肟配体的含双（diazadioxa-12-冠-4乙氧基）单位（ħ 2大号）已经由cyanogendi-反应合成Ñ氧化物与3,4-双（2- 10 - [（4- -甲基苯基）磺酰基] -1,7-二氧杂-4,10-二氮杂环十二烷-4-基}乙氧基）苯胺，它是通过还原4-[（4-甲基苯基）磺酰基] -10- [2-（ （4-硝基-2- 2- [10-苯基磺酰基）-1，7-二氧杂-4，10-二氮杂环十二烷-4-基]乙氧基}苯氧基）乙基] -1，7二氧杂-4，10-二氮杂十二烷基。还合成了H 2 L的金属：配体比为1：2的单核镍（II）和铜（II）配合物。H 2 L的单核钴（III）配合物已经用L′＝吡啶以及氯作为轴向配体分离出了R 2。此外，使用前体氢桥联钴（III）配合物通过模板效应合成了包含BF2 +桥大环的钴（III）配合物。的提取能力1，3，6和10也被在1,2-二氯乙烷通过使用几个碱（锂评价+，钠+，K
• Synthesis of (2-hydroxo-5-chlorophenylaminoisonitrosoacetyl)phenyl ligands and their complexes: Spectral, thermal and solvent-extraction studies
  作者：Fatma Karipcin、Bülent Dede、Mustafa Cengiz

  DOI：10.1134/s0036023610040078

  日期：2010.4

  Four different types of new ligands Ar[COC(NOH)R](n) (Ar=biphenyl, n = 1 H(2)L(1); Ar=biphenyl, n = 2 H(4)L(2); Ar=diphenylmethane, n = 1 H(2)L(3); Ar=diphenylmethane, n = 2 H(4)L(4); R=2-amino-4-chlorophenol in all ligands) have been obtained from 1 equivalent of chloroketooximes Ar[COC(NOH)Cl](n) (HL1-H2L4) and 1 equivalent of 2-amino-4-chlorophenol (for H(2)L(1) and H(2)L(3)) or 2 equivalent of 2-amino-4-chlorophenol (for H(4)L(2) and H(4)L(4)). (Mononuclear or binuclear cobalt(II), nickel(II), copper(II) and zinc(II) complexes were synthesized with these ligands.) These compounds have been characterized by elemental analyses, AAS, infra-red spectra and magnetic susceptibility measurements. The ligands have been further characterized by (1)H NMR. The results suggest that the dinuclear complexes of H(2)L(1) and H(2)L(3) have a metal:ligand ratio of 1:2; the mononuclear complexes of H(4)L(2) and H(4)L(4) have a metal:ligand ratio of 1:1 and dinuclear complexes H(4)L(2) and H(4)L(4) have a metal:ligand ratio of 2:1. The binding properties of the ligands towards selected transition metal ions (Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Pb(II), Cd(II), Hg(II)) have been established by extraction experiments. The ligands show strong binding ability towards mercury(II) ion. In addition, the thermal decomposition of some complexes is studied in nitrogen atmosphere
• Extraction of lead picrate by 18-crown-6 ether into various diluents: Examples of sub-analysis of overall extraction equilibrium based on component equilibria
  作者：Yoshihiro Kudo、Yuu Takahashi、Chiya Numako、Shoichi Katsuta

  DOI：10.1016/j.molliq.2014.01.017

  日期：2014.6

  Extraction constants for lead picrate, PbPic(2), with 18-crown-6 ether (L) from aqueous solutions at a narrow range of ionic strength (I) into eleven diluents were determined at 298 K by AAS measurements. These constants were defined as K-ex=[PbLPic(2)](0)/([Pb2+][L](0)[Pic(-)](2)) and K-ex +/-=[PbLPic(+)](0)[Pic(-)](0)/([Pb2+][L](0)[Pic(-)](2)), where the subscript "o" denotes the organic phase (or diluent). The ratio, K-ex/K-ex +/-, gave an ion-pair formation constant for PbLPic(o)(+) + Pic(o)(-)=PbLPic(2,o) at the averaged value of ionic strength (I-o) of the organic phase. A plot of log K-ex +/- versus log k(D.pc) yielded a straight line with the slope of 2.1 in a series of the diluents employed; K-D,K-Pic refers to an apparent distribution constant of Pic- between the aqueous and organic phases and its values were experimentally determined. The slope indicated that K-ex +/- is mainly controlled by the square of K-D,K-PIc when a thermodynamic cycle is assumed. The extraction constant based on the cycle was expressed as K-ex +/-=(K-D,K-Pic)(KD,MKML,orgK1,org)-K-2, where KD,MKM,L,orgK1,org denotes the product of other component equilibrium-constants. Moreover, the relation of log K-D.Pic=alog (I-o/I) + b was experimentally found at a approximate to 1 and then an example of b was expressed theoretically. It was shown that Pb(II) can be separated from mixtures with Cd(II) in unit operation. (C) 2014 Elsevier B.V. All rights reserved.
• Lignose,A.-G., Chemisches Zentralblatt, 1924, vol. 95, # I, p. 2632
  作者：Lignose,A.-G.

  DOI：——

  日期：——
• Ionic recognition by thiacalixarenes: binding of alkali and heavy metal ions by thiacalix[4]arene-bis-crown[n] ethers
  作者：S. Bouhroum、F. Arnaud-Neu、Z. Asfari、J. Vicens

  DOI：10.1023/b:rucb.0000046253.11118.9e

  日期：2004.7

  examined through extraction experiments. The stability constants of the resulting complexes in methanol were determined. The replacement of the bridging CH2 groups by sulfur atoms leads to a strong decrease in both extraction and complexation levels of alkali metal ions but does not affect the selectivity within the series of crown ethers. The stability of complexes with heavy metal ions does not change

  通过提取实验检查了两种硫杯 [4] 芳烃-双冠 [n] 衍生物（n = 5 和 6）的结合特性。测定所得配合物在甲醇中的稳定性常数。用硫原子取代桥接 CH2 基团导致碱金属离子的萃取和络合水平大大降低，但不影响冠醚系列内的选择性。从thiacalix[4]arene-bis-crown[n]醚到它们的calix[4]arene-bis-crown[n]对应物时，与重金属离子的配合物的稳定性没有显着变化；因此，无法得出关于这些阳离子与硫原子之间可能相互作用的明确结论。