Azanium;oxido-diphenoxy-sulfanylidene-lambda5-phosphane | 95033-30-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 英文名称: Azanium;oxido-diphenoxy-sulfanylidene-lambda5-phosphane
• 英文别名: azanium;oxido-diphenoxy-sulfanylidene-λ5-phosphane
• CAS: 95033-30-0
• 化学式: C₁₂H₁₀O₃PS*H₄N
• 分子量: 283.288
• InChiKey: FESOBPGWBWZBNC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.11
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Azanium;oxido-diphenoxy-sulfanylidene-lambda5-phosphane 、 二丁基二氯化锡 以 苯 为溶剂， 以93%的产率得到
  参考文献：
  名称：

  Monothiophosphorylation of Diorganotin Dichlorides. Synthesis and Characterization

  摘要：

  Reactions of diorganotin dichlorides with ammonium dialkyl monothiophosphates in refluxing benzene in 1:2 molar ratio yield diorganotin bis(dialkyl monothiophosphate). These compounds are soluble in common organic solvents. Molecular weight determinations show that these compounds are associated in solution and the degree of association is concentration dependent. The new compounds have been characterized by elemental analyses as well as spectroscopic (IR, H-1, C-13, P-31 and Sn-119) studies. On the basis of these data, chelate structures have been proposed.

  DOI：

  10.1081/sim-120017778

文献信息

• US4099954A
  申请人：——

  公开号：US4099954A

  公开（公告）日：1978-07-11
• Monothiophosphorylation of Diorganotin Dichlorides. Synthesis and Characterization
  作者：Adnan A.S. El‐Khaldy

  DOI：10.1081/sim-120017778

  日期：2003.1.6

  Reactions of diorganotin dichlorides with ammonium dialkyl monothiophosphates in refluxing benzene in 1:2 molar ratio yield diorganotin bis(dialkyl monothiophosphate). These compounds are soluble in common organic solvents. Molecular weight determinations show that these compounds are associated in solution and the degree of association is concentration dependent. The new compounds have been characterized by elemental analyses as well as spectroscopic (IR, H-1, C-13, P-31 and Sn-119) studies. On the basis of these data, chelate structures have been proposed.