naphtho[1,2-d]-1,3-dioxole | 234-15-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: naphtho[1,2-d]-1,3-dioxole
• 英文别名: 2H-Naphtho[1,2-D][1,3]dioxole；benzo[g][1,3]benzodioxole
• CAS: 234-15-1
• 化学式: C₁₁H₈O₂
• 分子量: 172.183
• InChiKey: PDBLJVROGRYXEU-UHFFFAOYSA-N

物化性质

• 沸点：
  76-78 °C(Press: 0.2 Torr)
• 密度：
  1.277±0.06 g/cm3(Predicted)
• 熔点：
  96-98 °C

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  naphtho[1,2-d]-1,3-dioxole 在 cerium(III) sulfate 作用下， 以 硫酸 、 水 为溶剂， 生成
  参考文献：
  名称：

  Holton, Dolores M.; Murphy, David, Journal of the Chemical Society. Perkin transactions II, 1980, p. 1757 - 1760

  摘要：

  DOI：
• 作为产物：
  描述：

  2-羟基萘甲醛 在 sodium periodate 、 叔丁基二甲基氯硅烷 、 三乙胺 作用下， 以 甲醇 、 甲苯 为溶剂， 生成 naphtho[1,2-d]-1,3-dioxole
  参考文献：
  名称：

  Synthesis of Fused Aromatic [1,3]Dioxoles from 2-Hydroxymethylphenols

  摘要：

  在非极性溶剂（甲苯、四氯化碳）中，添加TBDMSCl的条件下，螺环氧化环己二烯酮的重排反应最好进行，从而形成苯并[1,3]二恶烷。此外，还描述了将其应用于萘和四氢萘衍生物的合成过程。

  DOI：

  10.1055/s-1997-1037

文献信息

• 3-AMINOXALYL-AMINOBENZAMIDE DERIVATIVES AND INSECTICIDAL AND MITICIDAL AGENTS CONTAINING SAME AS ACTIVE INGREDIENT
  申请人：Usui Shuichi

  公开号：US20120022263A1

  公开（公告）日：2012-01-26

  The present invention herein provides a 3-aminooxalylaminobenzamide derivative which is used as an insecticide or miticide. The 3-aminooxalylaminobenzamide derivative is one represented by the following general formula [1]: (R 1 and R 2 each represent, for instance, a C 1 to C 3 alkoxy group or a C 1 to C 3 haloalkoxy group; R 3 and R 4 each represent, for instance, a C 1 to C 8 alkyl group or a C 1 to C 8 haloalkyl group; R 5 represents, for instance, a C 1 to C 5 haloalkyl group; R 6 and R 7 each represent, for instance, a hydrogen atom or a C 1 to C 5 alkyl group; Y represents, for instance, a hydrogen atom or a halogen atom; Z represents, for instance, a hydrogen atom; n is an integer ranging from 0 to 4 and m is an integer ranging from 0 to 2).

  本发明提供了一种用作杀虫剂或杀螨剂的3-氨基草酰胺基苯甲酰衍生物。 3-氨基草酰胺基苯甲酰衍生物由以下通用式[1]表示： （R1和R2分别表示，例如，C1到C3烷氧基或C1到C3卤代烷氧基；R3和R4分别表示，例如，C1到C8烷基或C1到C8卤代烷基；R5表示，例如，C1到C5卤代烷基；R6和R7分别表示，例如，氢原子或C1到C5烷基；Y表示，例如，氢原子或卤原子；Z表示，例如，氢原子；n是一个范围从0到4的整数，m是一个范围从0到2的整数）。
• [EN] BENZO [C] PHENANTHRIDINES AS ANTIMICROBIAL AGENTS<br/>[FR] BENZO[C]PHÉNANTHRIDINES COMME AGENTS ANTIMICROBIENS
  申请人：UNIV RUTGERS

  公开号：WO2010083436A1

  公开（公告）日：2010-07-22

  The present invention provides compounds of formula I: formula (I) wherein X1- X4 and R1-R12 have any of the values defined in the specification, as well as salts and prodrugs thereof, which inhibit major molecular mechanisms associated with bacterial cell division and proliferation so as to be useful for the treatment and/or prevention of bacterial infections. The invention also provides compositions comprising these compounds as well as methods for using these compounds to inhibit bacterial cell division and proliferation and to treat bacterial infections.

  本发明提供了以下式I的化合物：式(I)其中X1-X4和R1-R12具有规范中定义的任何值，以及其盐和前药，这些化合物抑制与细菌细胞分裂和增殖相关的主要分子机制，因此可用于治疗和/或预防细菌感染。该发明还提供了包含这些化合物的组合物，以及使用这些化合物抑制细菌细胞分裂和增殖并治疗细菌感染的方法。
• AGRICULTURAL AND HORTICULTURAL CHEMICAL AGENT HAVING NOVEL IMIDAZOPYRIDINE-2-CARBOXAMIDE DERIVATIVE AS ACTIVE INGREDIENT
  申请人：Agro-Kanesho Co., Ltd.

  公开号：EP3985004A1

  公开（公告）日：2022-04-20

  Provided is a compound useful as an active ingredient of an agricultural and horticultural chemical agent, in particular, an agricultural and horticultural pest control agent such as an agricultural and horticultural insecticide or an agricultural and horticultural mite control agent. The compound is an imidazopyridine-2-carboxamide derivative or its N-oxide or salt represented by the following formula (1) : in the formula, R1 and R2 are, for example, C1-3 alkyl groups, X is, for example, an oxygen atom or a sulfur atom, A1, A2, A3, A4, and A5 are each independently a nitrogen atom or C-R3, R3 is, for example, a hydrogen atom or a C1-3 haloalkyl group, and R4 is, for example, a C1-3 alkyl group or a C1-3 haloalkyl group.

  本发明提供了一种可用作农业和园艺化学制剂活性成分的化合物，特别是农业和园艺害虫防治剂，如农业和园艺杀虫剂或农业和园艺螨虫防治剂。该化合物是一种咪唑吡啶-2-甲酰胺衍生物或其 N-氧化物或盐，由下式（1）代表： 式中，R1和R2例如是C1-3烷基，X例如是氧原子或硫原子，A1、A2、A3、A4和A5各自独立地是氮原子或C-R3，R3例如是氢原子或C1-3卤代烷基，R4例如是C1-3烷基或C1-3卤代烷基。
• Mycoattractants and mycopesticides
  申请人：——

  公开号：US20020146394A1

  公开（公告）日：2002-10-10

  The present invention utilizes the pre-sporulation (preconidial) mycelial stage of entomopathogenic fungi as insect attractants and/or pathogens. The fungus can be cultivated on grain, wood, agricultural wastes or other cellulosic material, attracting the insect and optionally introducing insect-specific pathogenic fungi. More than one fungus and substrate can be used in combination. The matrix of preconidial fungi can optionally be dried, freeze-dried, cooled and/or pelletized and packaged and reactivated for use as an effective insect attractant and/or biopesticide. Attractant extracts of the preconidial entomopathogenic mycelium are disclosed.

  本发明利用昆虫病原真菌的孢子前（子囊前）菌丝阶段作为昆虫引诱剂和/或病原体。可以在谷物、木材、农业废弃物或其他纤维素材料上培养真菌，吸引昆虫，并选择性地引入昆虫特异性病原真菌。可以结合使用一种以上的真菌和基质。前壳真菌的基质可以选择干燥、冷冻干燥、冷却和/或造粒、包装和重新激活，以用作有效的昆虫引诱剂和/或生物杀虫剂。已公开了前生昆虫病原真菌菌丝体的引诱剂提取物。
• Non-toxic corrosion-protection pigments based on manganese
  申请人：——

  公开号：US20040011252A1

  公开（公告）日：2004-01-22

  Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

  以锰为基础的缓蚀颜料含有三价或四价锰/价稳定剂复合物。一种无机或有机材料可用于稳定三价或四价锰离子，从而形成一种可少量溶解、溶解度低或不溶于水的化合物，具体取决于预期用途。选择特定的稳定剂是为了控制三价锰或四价锰在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。锰/价稳定剂组合的选择是基于锰配位化学的基本原理。文中介绍了许多锰价稳定剂组合，其性能与传统的六价铬或四价铅体系相当。需要强调的是，提供本摘要是为了符合要求提供摘要的规则，以便检索者或其他读者快速确定技术公开的主题。提交本摘要的前提是，本摘要不用于解释或限制权利要求的范围或含义。