bis(tridecafluoroheptanoyl)peroxide | 42514-14-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: bis(tridecafluoroheptanoyl)peroxide
• 英文别名: Bis(tridecafluoroheptanoyl) peroxide；2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptanoyl 2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptaneperoxoate
• CAS: 42514-14-7
• 化学式: C₁₄F₂₆O₄
• 分子量: 726.11
• InChiKey: LFCQGZXAGWRTAL-UHFFFAOYSA-N

物化性质

• 沸点：
  244.1±50.0 °C(Predicted)
• 密度：
  1.776±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  44
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  30

安全信息

• 海关编码：
  2915900090

反应信息

• 作为反应物：
  描述：

  bis(tridecafluoroheptanoyl)peroxide 在 水 作用下， 以 1,1,2-三氯三氟乙烷（CFC-113） 为溶剂， 反应 7.0h， 生成 5-(perfluorohexyl)pyrimidine-2,4(1H,3H)-dione
  参考文献：
  名称：

  Facile perfluoroalkylation of uracils and uridines at the C-5 position

  摘要：

  Perfluoroalkylation at the C-5 position of uracil has been achieved in yields of 38-56% by the reaction of its bis(trimethylsilyl) derivative with bis(perfluoroalkanoyl) peroxides and the hydrolytic deprotection of the silylated products. A substituent or nitrogen replacement at C-6 does not interfere with perfluoroalkylation at C-5, but no significant reaction occurs at C-6 when C-5 is blocked.

  DOI：

  10.1016/s0022-1139(00)80396-6
• 作为产物：
  描述：

  全氟庚酰氟 在 sodium percarbonate 作用下， 以 1,1,2-三氯三氟乙烷（CFC-113） 为溶剂， 反应 0.5h， 以97.35%的产率得到bis(tridecafluoroheptanoyl)peroxide
  参考文献：
  名称：

  全氟酰基过氧化物的制备

  摘要：

  本发明涉及全氟酰基过氧化物的制备方法。具体地，所述方法包括步骤：在惰性溶剂中，用全氟酰卤，弱碱和过氧化氢的加合物进行反应，得到全氟酰基过氧化物。本发明的全氟酰基过氧化物在自由基聚合反应中作为引发剂广泛使用。该发明方法安全性能好，操作简单，过氧化物纯度高，收率高。

  公开号：

  CN108794367A

文献信息

• Perfluoroalkylquinones. Synthesis Using Bis(perfluoroalkanoyl) Peroxides, Absorption Bands, and Solubility
  作者：Masaki Matsui、Shigeru Kondoh、Katsuyoshi Shibata、Hiroshige Muramatsu

  DOI：10.1246/bcsj.68.1042

  日期：1995.3

  The reactions of 1,4-benzo-, naphtho-, and 9,10-anthraquinones with bis(perfluoroalkanoyl) peroxides gave the corresponding perfluoroalkylated derivatives. Those of 2-methyl- and 2-[4-(chloroanilino)]-1,4-naphthoquinones with bis(oxaperfluoroalkanoyl) peroxides afforded the dichloromethyl and trifluoromethyl derivatives, respectively. Absorption bands of the perfluoroalkylated naphtho- and anthraquinone dyes showed a slight hypsochromic shift. The solubilities of the perfluoroalkylated anthraquinone dyes into hexane were much more higher than those of the non-perfluoroalkylated ones.

  1,4-苯并蒽醌、萘并蒽醌和 9,10-蒽醌与双（全氟烷酰基）过氧化物的反应生成了相应的全氟烷基化衍生物。2-甲基和 2-[4-(氯苯胺基)]-1,4-萘醌与双(氧代全氟烷酰基)过氧化物的反应分别产生了二氯甲基和三氟甲基衍生物。全氟烷基化萘醌和蒽醌染料的吸收带显示出轻微的低色移。全氟烷基化蒽醌染料在正己烷中的溶解度远高于非全氟烷基化蒽醌染料。
• FLUORINE-CONTAINING POLYMER HAVING HETEROAROMATIC RING
  申请人：Komatsu Yuzo

  公开号：US20090105400A1

  公开（公告）日：2009-04-23

  There is provided a fluorine-containing polymer having an ionic group which has a heteroaromatic ring and is useful as a material comprising various heteroaromatic ring compounds having a stable fluorine-containing heteroaromatic ring, and further a fluorine-containing polymer having a heteroaromatic ring which is useful as a starting material of the above-mentioned polymer or a curing agent. Also, there is provided a fluorine-containing polymer having a heteroaromatic ring such as imidazole in its side chain, a polymer salt thereof, and a polymer composition comprising such a polymer and a polymer salt and a nano filler.

  提供了一种含氟聚合物，其具有带有杂环芳香环的离子基，并且可用作由稳定的含氟杂环芳香环化合物组成的材料，还提供了一种具有杂环芳香环的含氟聚合物，可用作上述聚合物或固化剂的起始材料。此外，还提供了一种具有杂环芳香环（如咪唑）的含氟聚合物及其聚合物盐，以及包含该聚合物、聚合物盐和纳米填料的聚合物组合物。
• Fluoroalkyl group-containing organosilicon oligomer, method for preparing same and surface treating agent
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0487094A1

  公开（公告）日：1992-05-27

  A fluoroalkyl group-containing organosilicon oligomer is represented by the following formula (I) or (IV ) of: wherein R, R₁, R₂, X and Y each are the same or different groups and stand for an alkyl, alkoxy or alkylcarbonyloxy group having 1 to 10 carbon atoms, n represents an integer of 1 to 3, m₁ and m₃ represent an integer of 1 to 10, m₂ represents an integer of 0 to 10, m₄ represents an integer of 1 to 5 and RF represents where A stands for a hydrogen atom, a fluorine atom or a chlorine atom, n₁ represents an integer of 1 to 10 and n₂ represents an integer of 0 to 8. A surface treating agent contains the oligomer defined by the formula (I) or (IV ).

  含氟烷基的有机硅低聚物由下式(I)或(IV )表示： 其中 R、R₁、R₂、X 和 Y 各为相同或不同的基团，代表具有 1 至 10 个碳原子的烷基、烷氧基或烷基羰氧基，n 代表 1 至 3 的整数，m₁ 和 m₃ 代表 1 至 10 的整数，m₂ 代表 0 至 10 的整数，m₄ 代表 1 至 5 的整数，RF 代表 其中 A 代表氢原子、氟原子或氯原子，n₁ 代表 1 至 10 的整数，n₂ 代表 0 至 8 的整数。表面处理剂含有式 (I) 或 (IV ) 所定义的低聚物。
• PERFLUOROALKYLATED NAPHTHALOCYANINE DERIVATIVE, PRODUCTION THEREOF, AND OPTICAL RECORDING MEDIUM
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0491951A1

  公开（公告）日：1992-07-01

  A perfluoroalkylated naphthalocyanine derivative which is excellent in weathering resistance and very highly soluble in various solvents and has a specified structure adapted for film formation; and an optical recording medium produced therefrom which enables recording by means of focused beams of a semiconductor laser. The above derivative is produced by the reaction of a perfluoroalkanoyl peroxide having a specified structure with a naphthalocyanine.

  一种全氟烷基化萘酞菁衍生物，其耐候性极佳，在各种溶剂中的溶解度极高，并具有适于成膜的特定结构；以及由其制成的一种光学记录介质，可通过半导体激光的聚焦光束进行记录。上述衍生物是由具有特定结构的全氟烷酰基过氧化物与萘酞菁反应生成的。
• A polymer comprising fluoroalkyl group, a method of preparation thereof, a surface active agent, a surface treatment agent and a coating composition
  申请人：NOF CORPORATION

  公开号：EP0537669A1

  公开（公告）日：1993-04-21

  A polymer comprising fluoroalkyl group has a structure in which one or two parts of the fluoroalkyl group at the one or both ends of the molecule are linked to a part of alkylene groups or alkylene groups substituted with halogen, a part of alkylene group substituted with functional groups, such as halogen, cyano group, alkylsulfonic acid group, amidoalkylsulfonic acid group, carboxylic acid group, carboxyl group, oxycarbonyl group, ether group, epoxy group and the like, and/or a part of silicone group. A method of preparation of the polymer comprising fluoroalkyl group contains reaction of a fluoroalkanoyl peroxide with a monomer comprising the functional group or a monomer comprising silicone group. A surface active agent comprises fluoroalkyl group and caroxylic acid salt group. A surface treatment agent comprises the polymer comprising fluoroalkyl group, hydrolysis products thereof, hydrolytic condensation products thereof, and mixtures thereof. A coating composition comprises the polymer comprising fluoroalkyl group. The polymer comprising fluoroalkyl group has excellent water repellency, oil repellency and weatherability because the fluoroalkyl group is introduced into the molecule through carbon-carbon linkage.

  包含氟烷基的聚合物具有如下结构：分子一端或两端的氟烷基的一部分或两部分与亚烷基或被卤素取代的亚烷基的一部分、被官能团（如卤素、氰基、烷基磺酸基、氨基烷基磺酸基、羧酸基、羧基、氧羰基、醚基、环氧基等）取代的亚烷基的一部分和/或硅酮基的一部分相连接。包含氟烷基的聚合物的制备方法包括过氧化氟烷酰与包含官能团的单体或包含硅酮基的单体反应。一种表面活性剂包括氟烷基和甲酸盐基。表面处理剂包括含氟烷基的聚合物、其水解产物、水解缩合产物及其混合物。一种涂料组合物，包括含氟烷基的聚合物。含氟烷基的聚合物具有优异的防水性、防油性和耐候性，因为氟烷基是通过碳-碳连接引入分子中的。