申请人:Bayer Aktiengesellschaft
公开号:US04873026A1
公开(公告)日:1989-10-10
New process for the preparation of 1-aminonaphthalene-2,4,7-trisulphonic acid and, if appropriate, 1,7-Cleve's acid, in which 1-nitronaphthalene is reacted by the Piria method with bisulphites in a manner which is known per se, the sulphamate mixture obtained in this Piria reaction is sulphonated with sulphur trioxide in sulphuric acid to give 1-aminonaphthalene-2,4,7-trisulphonic acid and, if appropriate, this is hydrolysed to 1,7-Cleve's acid by heating in aqueous sulphuric acid.
制备1-氨基萘-2,4,7-三磺酸和如适当的话,1,7-Cleve酸的新工艺,其中1-硝基萘通过Piria方法与亚硫酸氢盐反应,得到硫酰胺混合物,然后将该Piria反应中获得的硫酰胺混合物在硫酸中与三氧化硫磺化,得到1-氨基萘-2,4,7-三磺酸和如适当的话,通过在水合硫酸中加热水解得到1,7-Cleve酸。