1-acetophenone-5,6-diphenyl-1,2,4-triazine-3-yl-hydrazone | 101379-64-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 1-acetophenone-5,6-diphenyl-1,2,4-triazine-3-yl-hydrazone
• 英文别名: Acetophenon-<5.6-diphenyl-1.2.4-triazinyl-(3)-hydrazon>；3-(α-phenyl)ethylidenehydrazino-5,6-diphenyl-1,2,4-triazine；1-phenyl-ethanone (5,6-diphenyl-[1,2,4]triazin-3-yl)-hydrazone；3-(alpha-Phenyl)ethylidenehydrazino-5,6-diphenyl-1,2,4-triazine；5,6-diphenyl-N-(1-phenylethylideneamino)-1,2,4-triazin-3-amine
• CAS: 101379-64-0
• 化学式: C₂₃H₁₉N₅
• 分子量: 365.437
• InChiKey: WEMTZIPIMSSTJY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  28
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  63.1
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  copper(II) nitrate trihydrate 、 1-acetophenone-5,6-diphenyl-1,2,4-triazine-3-yl-hydrazone 以 乙醇 、 水 为溶剂， 生成 3-(α-phenyl)ethylidene-hydrozino-5,6-diphenyl-1,2,4-tetrazine-copper(II)-nitrate * 2 H2O
  参考文献：
  名称：

  Metal chelates of Triazine-Schiff-bases: Complex formation of 3-(?-phenyl)ethylidenehydrazino-5,6-diphenyl-1,2,4-triazine with copper(II)

  摘要：

  Complex formation of copper(II)-ions with 3-(alpha-Phenyl)ethylidenehydrazino-5,6-diphenyl-1,2,4-triazine (BHT) has been investigated using UV-VIS-,IR-, and electrochemical methods. Optimal pH for the 1:1 complex formation (and therefore for analytical applications) was found at 5.4. This complex could be isolated. The acid dissociation constant of the free ligand is pK(a) = 13.60; formation constants for 1:1 and 1:2 complexes were found to be log K1 = 12.0 and log K2 = 10.4, respectively. Polarographic reduction of both the free ligand and the Cu(II)-complexes is irreversible, diffusion controlled and like the stability of the complex pH-dependent.

  DOI：

  10.1007/bf00808671
• 作为产物：
  描述：

  5,6-二苯基-1,2,4-三嗪-3-硫醇 在 一水合肼 、 溶剂黄146 作用下， 以 甲醇 为溶剂， 反应 13.0h， 生成 1-acetophenone-5,6-diphenyl-1,2,4-triazine-3-yl-hydrazone
  参考文献：
  名称：

  Misra; Sen; Sen Gupta, Journal of the Indian Chemical Society, 1989, vol. 66, # 5, p. 322 - 324

  摘要：

  DOI：

文献信息

• Misra; Sen; Sen Gupta, Journal of the Indian Chemical Society, 1989, vol. 66, # 5, p. 322 - 324
  作者：Misra、Sen、Sen Gupta

  DOI：——

  日期：——
• Metal chelates of Triazine-Schiff-bases: Complex formation of 3-(?-phenyl)ethylidenehydrazino-5,6-diphenyl-1,2,4-triazine with copper(II)
  作者：A. Taha、S. El-Shetary、W. Linert

  DOI：10.1007/bf00808671

  日期：1993.2

  Complex formation of copper(II)-ions with 3-(alpha-Phenyl)ethylidenehydrazino-5,6-diphenyl-1,2,4-triazine (BHT) has been investigated using UV-VIS-,IR-, and electrochemical methods. Optimal pH for the 1:1 complex formation (and therefore for analytical applications) was found at 5.4. This complex could be isolated. The acid dissociation constant of the free ligand is pK(a) = 13.60; formation constants for 1:1 and 1:2 complexes were found to be log K1 = 12.0 and log K2 = 10.4, respectively. Polarographic reduction of both the free ligand and the Cu(II)-complexes is irreversible, diffusion controlled and like the stability of the complex pH-dependent.