<(dimethylamino)methyl>methylsilane | 67353-43-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: <(dimethylamino)methyl>methylsilane
• 英文别名: 2-methyl-2-aza-4-silapentane；N,N-dimethyl-1-methylsilylmethanamine
• CAS: 67353-43-9
• 化学式: C₄H₁₃NSi
• 分子量: 103.239
• InChiKey: HWAMGZYKJUHASJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.28
• 重原子数：
  6
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  <(dimethylamino)methyl>methylsilane 、 苯胺 以 N,N-二甲基乙酰胺 为溶剂， 生成 (Dimethylaminomethyl-methyl-silanyl)-phenyl-amine
  参考文献：
  名称：

  Saratov, I. E.; Shpak, I. V.; Reikhsfel'd, V. O., Journal of general chemistry of the USSR, 1981, vol. 51, p. 1755 - 1760

  摘要：

  DOI：
• 作为产物：
  描述：

  <(dimethylamino)methyl>dimethoxymethylsilane 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 反应 2.0h， 生成 <(dimethylamino)methyl>methylsilane
  参考文献：
  名称：

  Saratov, I. E.; Shpak, I. V.; Reikhsfel'd, V. O., Journal of general chemistry of the USSR, 1981, vol. 51, # 2, p. 322 - 329

  摘要：

  DOI：

文献信息

• 1H NMR study of some substituted acyclic silaethanes, 2-silapropanes and 2-methyl-2-silapropanes and their rotameric populations around the SiC bond
  作者：Robert Carleer、Marc J. O. Anteunis

  DOI：10.1002/mrc.1270130406

  日期：1980.4

  AbstractThree series of substituted silaalkanes, (i) SiH3CH2X, (ii) MeSiH2CH2X and (III) Me2SiHCH2X, have been prepared (X=Cl, Br, I, NMe2, OMe, SMe), and the shifts and coupling constants extracted from their1H NMR spectra. Coefficients averaged over three rotameric states can be obtained from the first series which are used for the correction of coupling constants resulting from the presence of the electronegative substituents X. With the aid of the Karplus‐Conroy angular dependence of the interproton coupling constants in silaethane† fragments, corrected for electronegative substitution, approximate rotameric populations in series ii and iii were obtained. Except for X=NMe2, there is always a preference for asynclinalX/CH3relationship, even for sandwiched situations (series III).
• Saratov, I. E.; Shpak, I. V.; Markov, S. A., Journal of general chemistry of the USSR, 1981, vol. 51, p. 1746 - 1749
  作者：Saratov, I. E.、Shpak, I. V.、Markov, S. A.、Lazarev, S. Ya.、Reikhsfel'd, V. O.

  DOI：——

  日期：——
• Saratov, I. E.; Shpak, I. V.; Markov, S. A., Journal of general chemistry of the USSR, 1981, vol. 51, p. 1750 - 1754
  作者：Saratov, I. E.、Shpak, I. V.、Markov, S. A.、Lazarev, S. Ya.、Reikhsfel'd, V. O.

  DOI：——

  日期：——
• CAPATOB I. E.; SHPAK I. V.; REJXSFELD V. O., ZH. OBSHCH. XIMII, 1981, 51, HO 2, 396-404
  作者：CAPATOB I. E.、 SHPAK I. V.、 REJXSFELD V. O.

  DOI：——

  日期：——
• Saratov, I. E.; Shpak, I. V.; Reikhsfel'd, V. O., Journal of general chemistry of the USSR, 1981, vol. 51, # 2, p. 322 - 329
  作者：Saratov, I. E.、Shpak, I. V.、Reikhsfel'd, V. O.

  DOI：——

  日期：——

表征谱图