1,3-Bis(isocyanatomethyl)cyclohexane, cis- | 10339-98-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,3-Bis(isocyanatomethyl)cyclohexane, cis-
• 英文别名: (1R,3S)-1,3-bis(isocyanatomethyl)cyclohexane
• CAS: 10339-98-7
• 化学式: C₁₀H₁₄N₂O₂
• 分子量: 194.23
• InChiKey: XSCLFFBWRKTMTE-AOOOYVTPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  58.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,3-Bis(isocyanatomethyl)cyclohexane, cis- 、 trans-1,3-Bis(isocyanatomethyl)cyclohexane 、 cis-1,4-bis(isocyanatomethyl)cyclohexane 以33% trans-1,4-bis(isocyanatomethyl)cyclohexane is produced by The Dow Chemical Company的产率得到trans-1,4-bis(isocyanatomethyl)cyclohexane
  参考文献：
  名称：

  Polyamide polymer

  摘要：

  本发明提供聚酰胺，制备聚酰胺的方法以及包含聚酰胺的物品。

  公开号：

  US08236922B2

文献信息

• Polyurethane dispersion and articles prepared therefrom
  申请人：Argyropoulos N. John

  公开号：US20070265388A1

  公开（公告）日：2007-11-15

  The present invention is to a polyurethane dispersion and products produced therefrom wherein the dispersion contains a polyurethane prepolymer produced from the a reaction of an excess of a polyisocyante with an isocyanate reactive molecule wherein the polyisocyante is a bis(isocyanatomethyl)cyclohexane. Preferably the isocyanate comprises (i) trans-1,4-bis(isocyanatomethyl)cyclohexane or (ii) an isomeric mixture of two or more of cis-1,3-bis(isocyanatomethyl)cyclohexane, trans-1,3-bis(isocyanatomethyl)cyclohexane, cis-1,4-bis(isocyanatomethyl)cyclohexane and trans-1,4-bis(isocyanatomethyl)cyclohexane, with the proviso said isomeric mixture comprises at least about 5 weight percent of said trans-1,4-bis(isocyanatomethyl)cyclohexane.

  本发明涉及一种聚氨酯分散液及其制备的产品，其中该分散液含有由多异氰酸酯过量与异氰酸反应生成的聚氨酯预聚物，所述多异氰酸酯是双(异氰酸甲基)环己烷。优选的异氰酸酯包括(i) 反-1,4-双(异氰酸甲基)环己烷或(ii) 由顺-1,3-双(异氰酸甲基)环己烷、反-1,3-双(异氰酸甲基)环己烷、顺-1,4-双(异氰酸甲基)环己烷和反-1,4-双(异氰酸甲基)环己烷中的两种或多种异构体混合而成，但至少包括约5重量％的反-1,4-双(异氰酸甲基)环己烷。
• POLYAMIDE POLYMER
  申请人：Warakomski John M.

  公开号：US20100029894A1

  公开（公告）日：2010-02-04

  The instant invention provides polyamides, processes for making the polyamides, and articles comprising the polyamides.

  本发明提供了聚酰胺、制备聚酰胺的工艺以及包含聚酰胺的制品。
• Two component polyurethane coating compositions comprising isocyanurate compositions from bis (isocyanatomethyl) cyclohexane and from aliphatic diisocyanates
  申请人：Rohm and Haas Company

  公开号：EP2455409A2

  公开（公告）日：2012-05-23

  The present invention provides two-component polyurethane compositions comprising, as one component, polyisocyanate compositions of the isocyanurate of one or more bis(isocyanatomethyl)cyclohexane or, preferably, a mixture of two or more of these, and of the isocyanurate of hexamethylene diisocyanate (HDI trimer),and, as the other component, a mix of a soft polyol having a hydroxyl functionality of from 2.5 to 5.0 and a molecular weight of from 500 to 3,000, and a hard polyol. Such compositions provide coatings, especially clear topcoats, which exhibit excellent scratch and mar and solvent resistance in addition to a good balance of hardness and flexibility without the need for increasing the volatile organic content (VOC) of the compositions. Also provided are compositions of a polyisocyanate compositions of the isocyanurate of one or more bis(isocyanatomethyl)cyclohexane with soft polyol which have lower VOCs.

  本发明提供了双组分聚氨酯组合物，其中一个组分是由一种或多种双（异氰酸酯甲基）环己烷的异氰尿酸酯或最好是两种或多种双（异氰酸酯甲基）环己烷的异氰尿酸酯和六亚甲基二异氰酸酯（HDI 三聚体）的异氰尿酸酯组成的多异氰酸酯组合物，另一个组分是由羟基官能度为 2.5 至 5.0、分子量为 500 至 3 000 的软质多元醇和硬质多元醇组成的混合物。5 至 5.0，分子量为 500 至 3,000 的软质多元醇和硬质多元醇的混合物。这种组合物提供的涂料，尤其是透明面漆，除了硬度和柔韧性的良好平衡外，还具有优异的耐刮伤、耐磨损和耐溶剂性，而无需增加组合物的挥发性有机物含量（VOC）。此外，还提供了一种或多种双（异氰酸酯甲基）环己烷的异氰脲酸酯与软质多元醇的多异氰酸酯组合物，其挥发性有机化合物含量较低。
• Polyurethane resin
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2730599A2

  公开（公告）日：2014-05-14

  Disclosed is a polyurethane resin which is obtained by a reaction between a polyisocyanate component, which contains 1,4-bis(isocyanatomehyl)cyclohexane including not less than 80% by mole of trans isomers, and an active hydrogen compound component.

  本发明公开了一种聚氨酯树脂，它是由含有 1,4-双（异氰酸酯甲基）环己烷（其中反式异构体的摩尔数不少于 80%）的多异氰酸酯组分和活性氢化合物组分反应而得。
• POLYISOCYANATE COMPOSITION, SOLAR CELL MEMBER COVERING MATERIAL, SOLAR CELL MEMBER WITH COVERING LAYER, MICROCAPSULE, AND INK BINDER
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2881442A1

  公开（公告）日：2015-06-10

  A polyisocyanate composition is produced by reaction of bis(isocyanatomethyl) cyclohexane with trimethylolpropane, and contains a trimethylolpropane-monomolecular-body obtained by reaction of three molecules of bis(isocyanatomethyl) cyclohexane with one molecule of trimethylolpropane, and a trimethylolpropane-bimolecular-body obtained by reaction of five molecules of bis(isocyanatomethyl) cyclohexane with two molecules of trimethylolpropane; and the molar ratio of trimethylolpropane-monomolecular-body relative to trimethylolpropane-bimolecular-body (trimethylolpropane-monomolecular-body/trimethylolpropane-bimolecular-body) contained in the polyisocyanate composition is 1.5 or more and 4.5 or less.

  一种聚异氰酸酯组合物是由双(异氰酸基甲基)环己烷与三羟甲基丙烷反应生成的，其中包含由三分子双(异氰酸基甲基)环己烷与一分子三羟甲基丙烷反应生成的三羟甲基丙烷单分子体，以及由五分子双(异氰酸基甲基)环己烷与两分子三羟甲基丙烷反应生成的三羟甲基丙烷双分子体；聚异氰酸酯组合物中所含三羟甲基丙烷单分子体与三羟甲基丙烷双分子体的摩尔比(三羟甲基丙烷单分子体/三羟甲基丙烷双分子体)为 1.5或以上，4.5或以下。