N1,N4-didecylbenzene-1,4-diamine | 4734-68-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N1,N4-didecylbenzene-1,4-diamine
• 英文别名: 1-N,4-N-didecylbenzene-1,4-diamine
• CAS: 4734-68-3
• 化学式: C₂₆H₄₈N₂
• 分子量: 388.681
• InChiKey: YQYATJREFHIMON-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.9
• 重原子数：
  28
• 可旋转键数：
  20
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N1,N4-didecylbenzene-1,4-diamine 在 potassium carbonate 、 三乙胺 作用下， 以 四氢呋喃 、 甲醇 、 二氯甲烷 、 水 为溶剂， 反应 18.0h， 生成 N,N'-(1,4-phenylene)bis(N-decyl-2-hydroxyacetamide)
  参考文献：
  名称：

  A Sm(II)-Mediated Cascade Approach to Dibenzoindolo[3,2-b]carbazoles: Synthesis and Evaluation

  摘要：

  Previously unstudied dibenzoindolo[3,2-b]carbazoles have been prepared by two-directional, phase tag-assisted synthesis utilizing a connective-Pummerer cyclization and a SmI2-mediated tag cleavage-cyclization cascade. The use of a phase tag allows us to exploit unstable intermediates that would otherwise need to be avoided. The novel materials were characterized by X-ray, cyclic voltammetry, UV-vis spectroscopy, TGA, and DSC. Preliminary studies on the performance of OFET devices are also described.

  DOI：

  10.1021/ol500841b
• 作为产物：
  描述：

  N,N'-(1,4-phenylene)bis(decanamide) 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 反应 18.0h， 生成 N1,N4-didecylbenzene-1,4-diamine
  参考文献：
  名称：

  A Sm(II)-Mediated Cascade Approach to Dibenzoindolo[3,2-b]carbazoles: Synthesis and Evaluation

  摘要：

  Previously unstudied dibenzoindolo[3,2-b]carbazoles have been prepared by two-directional, phase tag-assisted synthesis utilizing a connective-Pummerer cyclization and a SmI2-mediated tag cleavage-cyclization cascade. The use of a phase tag allows us to exploit unstable intermediates that would otherwise need to be avoided. The novel materials were characterized by X-ray, cyclic voltammetry, UV-vis spectroscopy, TGA, and DSC. Preliminary studies on the performance of OFET devices are also described.

  DOI：

  10.1021/ol500841b

文献信息

• A Sm(II)-Mediated Cascade Approach to Dibenzoindolo[3,2-<i>b</i>]carbazoles: Synthesis and Evaluation
  作者：Matthew T. Levick、Iain Grace、Sheng-Yao Dai、Nicholas Kasch、Christopher Muryn、Colin Lambert、Michael L. Turner、David J. Procter

  DOI：10.1021/ol500841b

  日期：2014.4.18

  Previously unstudied dibenzoindolo[3,2-b]carbazoles have been prepared by two-directional, phase tag-assisted synthesis utilizing a connective-Pummerer cyclization and a SmI2-mediated tag cleavage-cyclization cascade. The use of a phase tag allows us to exploit unstable intermediates that would otherwise need to be avoided. The novel materials were characterized by X-ray, cyclic voltammetry, UV-vis spectroscopy, TGA, and DSC. Preliminary studies on the performance of OFET devices are also described.