5-chloronorborn-2-ene | 4313-36-4

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 5-chloronorborn-2-ene
• 英文别名: 5-chloro-norborn-2-ene；5-Chlor-norborn-2-en；Chloro-5-bicyclo<1.2.2>heptene-2；2-Chlor-bicyclo<2.2.1>hept-5-en；Norbornenylchlorid；5-Chlorobicyclo[2.2.1]hept-2-ene
• CAS: 4313-36-4
• 化学式: C₇H₉Cl
• mdl: MFCD00218723
• 分子量: 128.601
• InChiKey: PSCJIEZOAFAQRM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.714
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  5-chloronorborn-2-ene 、 mercury(2+);1,1,1-trifluoro-N-oxido-N-(trifluoromethyl)methanamine 生成 N-[[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]oxy]-1,1,1-trifluoro-N-(trifluoromethyl)methanamine
  参考文献：
  名称：

  BOOTH, B. L.;HASZELDINE, R. N.;NWADINIGWE, C. A., J. CHEM. SOC. PERKIN TRANS., 1982, N 3, 835-839

  摘要：

  DOI：
• 作为产物：
  描述：

  2,5-降冰片二烯 、 盐酸 生成 5-chloronorborn-2-ene
  参考文献：
  名称：

  RISCH, N.;EMIG, P.;SCHEFFLER, G.;POHLE, H.;HENKEL, G., ARZNEIMITTEL-FORSCH., 1982, 32, N 11, 1409-1411

  摘要：

  DOI：

文献信息

• Antivirally active N-cycloalkyl alkanol compounds
  申请人：SANWA KAGAKU KENKYUSHO CO., LTD.

  公开号：EP0558321A1

  公开（公告）日：1993-09-01

  The compounds are of the general formula or where R₁ is -OH, amino or -SH, R₂ is H, α- or β-naphthyl or optionally substituted phenyl, R₃ is mono-, di- or tricycloalkyl of C6-16, optionally substituted, R₄₋₇ are H or alkyl, R₈₋₉ are alkyl or may form a 6-membered ring or a 5-membered ring with R₆ and R₇, R₁₀ and R₁₁ are alkyl, and n is 0 or an integer. Synthesis examples are given, and for the preparation of starting materials. Pharmaceutical compositions for oral, topical or injectable administration contain the compounds or their acceptable salts. The compounds have excellent antiviral activity as illustrated against herpes virus and may also be effective against influenza, DNA, RNA and HIV viruses.

  这些化合物的一般式为或其中R₁为-OH，氨基或-SH，R₂为H，α-或β-萘基或可选择性取代的苯基，R₃为C6-16的单环、双环或三环烷基，可选择性取代，R₄₋₇为H或烷基，R₈₋₉为烷基或可与R₆和R₇形成6元环或5元环，R₁₀和R₁₁为烷基，n为0或整数。给出了合成示例，以及制备起始材料的方法。口服、局部或注射给药的制剂包含这些化合物或它们的可接受盐。这些化合物对疱疹病毒具有出色的抗病毒活性，并且可能对流感、DNA、RNA和HIV病毒也有效。
• Multilayer film for packaging
  申请人：——

  公开号：US20010014384A1

  公开（公告）日：2001-08-16

  A multilayer film for packaging which is superior in, such as extensible elasticity, ability for adhering onto various surfaces, transparency, clear cutting performance, heat-sealability, resistance to fogging, resistance to break-through and ability for restoring from finger pressing and which comprises outer layers made of the outer layer resin composition (I) or (II) given below and an inner layer made of an inner layer resin composition composed of a higher melting component (III) and a softening component (IV) interposed between the outer layers, wherein the resin composition (I) comprises 59.5-99.5% by weight of (A) an ethylene/&agr;-olefin copolymer component, which is composed of at least one copolymer of ethylene and an &agr;-olefin having 3-20 carbon atoms and which has a melt flow rate (MFR) of 0.1-10 g/10 min. and a density of 0.850 g/cm 3 -0.910 g/cm 3 ; 0-40% by weight of (B) a high-pressure process low density polyethylene having a density of 0.915-0.930 g/cm 3 , and 0.5-10% by weight of (C) an anti-fogging agent, and wherein the resin composition (II) comprises 99.5-90% by weight of (D) an ethylene/vinyl acetate copolymer, which is a copolymer of ethylene and vinyl acetate and has a vinyl acetate content of 10-30% by weight and an MFR of 0.5-30 g/10 min., and 0.5-10% by weight of (C) anti-fogging agent.

  一种用于包装的多层薄膜，具有伸缩弹性、能够附着在各种表面上、透明、易于切割、热封性能、防雾性能、防穿透性和能够从手指按压中恢复等优点，包括由下列外层树脂组分(I)或(II)制成的外层和由高熔点组分(III)和软化组分(IV)组成的内层树脂组分组成的内层，其中树脂组分(I)包括：59.5-99.5重量％的(A)乙烯/α-烯烃共聚物组分，由乙烯和一种具有3-20个碳原子的α-烯烃的至少一种共聚物组成，具有熔融流速(MFR)为0.1-10 g/10 min.和密度为0.850 g/cm3-0.910 g/cm3；0-40重量％的(B)高压过程低密度聚乙烯，密度为0.915-0.930 g/cm3；0.5-10重量％的(C)防雾剂；树脂组分(II)包括：99.5-90重量％的(D)乙烯/醋酸乙烯共聚物，是乙烯和醋酸乙烯的共聚物，醋酸乙烯含量为10-30重量％，MFR为0.5-30 g/10 min.；0.5-10重量％的(C)防雾剂。
• Method for producing an olefin type copolymer having a cyclic structure
  申请人：MARUZEN PETROCHEMICAL CO., LTD.

  公开号：US20020058767A1

  公开（公告）日：2002-05-16

  A method for producing an olefin type copolymer having a cyclic structure, which comprises copolymerizing ethylene (M1) and dicyclopentadiene or tricyclopentadiene (M2), and, as optionally introduced, a cyclic olefin (M3), wherein, as a catalyst, a catalyst comprising a metallocene compound (A) of the following formula [1]: H 2 C(R′ m CP)(R″ n Cp)Mx 2 [1] wherein M is zirconium or hafnium, Cp is a group having a cyclopentadienyl skeleton, each of R′ and R″ is a hydrocarbon group having 1 to 10 carbon atoms, each of two X's which may be the same or different from each other, is a halogen atom, a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group, an alkylamino group, an alkoxy group, an aryloxy group of the formula —O—Ar—Y p (wherein Ar is an aromatic ring, Y is a halogen atom, a hydrogen atom, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group, an alkoxy group, an alkylamino group, a cyano group or a nitro group, and p is an integer of from 1 to 5), a thioalkyl group, or a thioaryl group of the formula —S—Ar—Y p (wherein Ar, Y and p are as defined above), and each of m and n is an integer of from 0 to 4, provided that m and n are not equal, and m+n is an integer of from 3 to 6, and an aluminoxane (B), is used.

  一种制备具有环状结构的烯烃共聚物的方法，包括共聚乙烯（M1）和二环戊二烯或三环戊二烯（M2），以及作为可选引入的环状烯烃（M3），其中，作为催化剂使用以下式子（1）的金属茂化合物（A）：H2C(R′mCP)(R″nCp)Mx2（1），其中M为锆或铪，Cp为具有环戊二烯基骨架的基团，R′和R″各自为具有1至10个碳原子的碳氢基团，两个X可以相同也可以不同，是卤素原子、氢原子、具有1至20个碳原子的碳氢基团、卤代碳氢基团、烷基氨基基团、烷氧基、苯氧基（式中Ar为芳香环，Y为卤素原子、氢原子、具有1至20个碳原子的碳氢基团、卤代碳氢基团、烷氧基、烷基氨基基团、氰基或硝基，p为1至5的整数），硫代烷基团或硫代芳基团（式中Ar、Y和p如上所述），m和n各自为0至4的整数，但m和n不相等，且m+n为3至6的整数，并使用铝烷氧化物（B）。
• Method of forming cavity between multilayered wirings
  申请人：JSR Corporation

  公开号：US20040132243A1

  公开（公告）日：2004-07-08

  A method of forming a cavity between metallic wirings using a polymer capable of revealing a specific heat resistant temperature and a specific heat decomposition temperature by having a specific repeating unit structure and a specific molecular weight range and of readily forming a cavity structure between metallic wirings in, for example, semiconductors. The method comprises a step of coating the surface of a first dielectric film formed on a semiconductor substrate with a cyclic olefin based addition polymer, a step of patterning the cyclic olefin based addition polymer as a void-forming polymer, a step of forming a metallic wiring in the pattern formed on the void-forming polymer, a step of forming a second dielectric film on the void-forming polymer containing a metallic wiring, and a step of removing the void-forming polymer between the multilayered wirings by heating to form a cavity between the metallic wirings.

  一种利用具有特定重复单元结构和特定分子量范围的聚合物，通过具有特定耐热温度和特定热分解温度的能力来形成金属导线之间空腔的方法，例如在半导体中容易形成空腔结构。该方法包括以下步骤：在半导体衬底上形成第一介电膜的表面上涂覆环状烯基加成聚合物；将环状烯基加成聚合物作为形成空腔的聚合物进行图案化；在形成的空腔聚合物图案上形成金属导线；在包含金属导线的空腔聚合物上形成第二介电膜；通过加热去除多层金属导线之间的空腔聚合物，形成金属导线之间的空腔。
• Cycloolefin addition copolymer and optical transparent material
  申请人：Oshima Noboru

  公开号：US20050171310A1

  公开（公告）日：2005-08-04

  A cyclic olefin addition copolymer obtained by copolymerizing a cyclic olefin compound having a side chain substituent group with a ring structure, such as endo-tricyclo[4.3.0.1 2,5 ]deca-3,7-diene or endo-tricyclo-[4.3.0.1 2,5 ]deca-3-ene, with another cyclic olefin compound such as bicyclo[2.2.1]hept-2-ene, and further with a cyclic olefin compound having a hydrolysable silyl group as needed, or hydrogenating after copolymerization; a composition for crosslinking in which a specific crosslinking agent is incorporated; a crosslinked product obtained by crosslinking the composition; an optical material containing the copolymer, the composition or the crosslinked product; and a method for producing the copolymer in which addition polymerization is conducted using a specific nickel catalyst.

  通过共聚合具有侧链取代基的环烯化合物与另一种环烯化合物共聚合得到的环烯加成共聚物，例如内向三环[4.3.0.1 2,5]癸-3,7-二烯或内向三环[4.3.0.1 2,5]癸-3-烯，再加入需要的具有可水解硅基团的环烯化合物或在共聚合后进行氢化; 包含特定交联剂的交联组合物; 通过交联组合物交联得到的交联产物; 包含共聚物、组合物或交联产物的光学材料; 以及使用特定的镍催化剂进行加成聚合的制备环烯共聚物的方法。