1,2,μ-trithio-dicarbonic acid bis-dipropylamide | 2556-41-4

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫基化合物
• 英文名称: 1,2,μ-trithio-dicarbonic acid bis-dipropylamide
• 英文别名: Tetrapropyl-thiuramsulfid；1,2,μ-Trithio-dikohlensaeure-bis-dipropylamid；Bis-(dipropyl-thiocarbamoyl)-sulfan；Tetra propyl thiuram monosulfide；dipropylcarbamothioyl N,N-dipropylcarbamodithioate
• CAS: 2556-41-4
• 化学式: C₁₄H₂₈N₂S₃
• 分子量: 320.588
• InChiKey: INPYKGHCAAJELE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  19
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  96
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N,N-dipropylthiocarbamoyl chloride 、 alkaline earth salt of/the/ methylsulfuric acid 在 水 作用下， 生成 1,2,μ-trithio-dicarbonic acid bis-dipropylamide
  参考文献：
  名称：

  Preparation of thiuram monosulfides

  摘要：

  公开号：

  US02524081A1

文献信息

• Organic polymer solution
  申请人：NITTO DENKO CORPORATION

  公开号：EP0497379A1

  公开（公告）日：1992-08-05

  An organic polymer solution comprising an organic solvent and, dissolved therein, (a) an organic polymer which has an imino-p-phenylene structural unit of the formula as a major repeating unit and is organic solvent-soluble, (b) a protonic acid having a pKa value of 4.8 or less or a derivative thereof, (c) at least one member selected from the group consisting of an oxidizing agent which does not have oxidizing ability at ordinary temperature but has oxidizing ability at temperatures not lower than 60°C, and an oxidation catalyst.

  有机聚合物溶液，包括有机溶剂和溶解在其中的有机聚合物、 (a) 一种有机聚合物，该聚合物具有式为 作为主要重复单元且可溶于有机溶剂的有机聚合物、 (b) pKa 值等于或小于 4.8 的质子酸或其衍生物、 (c) 至少一种选自氧化剂（在常温下不具有氧化能力，但在不低于 60°C 的温度下具有氧化能力）和氧化催化剂的成员。
• METHOD FOR MANUFACTURING RUBBER COMPOSITION
  申请人：Bridgestone Corporation

  公开号：EP2623547A1

  公开（公告）日：2013-08-07

  The present invention provides a method for producing a rubber composition containing a rubber component (A) of at least one selected from natural rubbers and synthetic dienic rubbers, an inorganic filler (B), a silane coupling agent (C) and an acidic compound (D), wherein the rubber composition is kneaded in multiple stages, and in the final stage of kneading, the acidic compound (D) is added, and the highest temperature of the rubber composition in the final stage of kneading is from 60 to 120°C. The production method enables production of a rubber composition having a low-heat-generation property while successfully preventing the coupling function activity of the silane coupling agent from lowering.

  本发明提供了一种橡胶组合物的生产方法，该橡胶组合物含有至少一种选自天然橡胶和合成二元橡胶的橡胶组分（A）、无机填料（B）、硅烷偶联剂（C）和酸性化合物（D），其中橡胶组合物经过多阶段捏合，在捏合的最后阶段加入酸性化合物（D），在捏合的最后阶段橡胶组合物的最高温度为 60 至 120°C。该生产方法既能生产出具有低发热特性的橡胶组合物，又能成功防止硅烷偶联剂的偶联功能活性降低。
• METHOD FOR PRODUCING RUBBER COMPOSITION
  申请人：Bridgestone Corporation

  公开号：EP2703428A1

  公开（公告）日：2014-03-05

  The invention is a process for producing a rubber composition containing at least one rubber component (A) selected from natural rubbers and synthetic diene rubbers, a filler containing an inorganic filler (B), a silane coupling agent (C) and a vulcanization accelerator (D), wherein the rubber composition is kneaded in multiple stages, the rubber component (A), all or a portion of the inorganic filler (B), all or a portion of the silane coupling agent (C) and the vulcanization accelerator (D) are added and kneaded in the first stage of kneading, and the specific energy for kneading in the first stage is from 0.05 to 1.50 kWh/kg. The specific energy is obtained by dividing the power consumption by the motor in the kneading device in the first stage of kneading by the total mass of the rubber composition therein. In the process, the coupling function activity can be further increased and a rubber composition favorably having a low-heat-generation property and having good abrasion resistance can be obtained.

  本发明是一种生产橡胶组合物的工艺，该橡胶组合物含有至少一种选自天然橡胶和合成二烯橡胶的橡胶组分（A）、一种含有无机填料（B）的填料、一种硅烷偶联剂（C）和一种硫化促进剂（D），其中橡胶组合物分多个阶段捏合、在第一阶段混炼中加入并混炼橡胶成分 (A)、全部或部分无机填料 (B)、全部或部分硅烷偶联剂 (C) 和硫化促进剂 (D)，第一阶段混炼的比能量为 0.05 至 1.50 千瓦时/千克。比能量是通过将第一阶段混炼中混炼装置中电机的耗电量除以其中橡胶组合物的总质量得出的。在此过程中，耦合功能活性可进一步提高，并可获得具有低发热特性和良好耐磨性的橡胶组合物。
• PROCESS FOR PRODUCING RUBBER COMPOSITION
  申请人：Bridgestone Corporation

  公开号：EP2695911A1

  公开（公告）日：2014-02-12

  Provided are processes for producing a rubber composition, which enable a suitably low heat-generating rubber composition to be obtained by further improving coupling function activity of a silane coupling agent. More specifically, provided is a process for producing a rubber composition comprising a rubber component (A) comprising at least one selected from natural rubbers and synthetic diene rubbers, a filler containing an inorganic filler (B), a silane coupling agent (C), and at least two kinds of chemical agents (D) and (E) selected from guanidines, sulfenamides, thiazoles, thiurams, dithiocarbamates, thioureas, and xanthates, wherein the rubber composition is kneaded in a plurality of stages wherein, in the first stage (X) of kneading, the rubber component (A), all or a portion of the inorganic filler (B), all or a portion of the silane coupling agent (C), and at least two kinds of the chemical agents (D) and (E) are added and kneaded. Also provided is a process for producing a rubber composition, wherein the rubber composition is kneaded in a kneading step comprising three or more stages wherein, in the first stage (X) of kneading, the rubber component (A), all or a portion of the inorganic filler (B), all or a portion of the silane coupling agent (C) are kneaded; in a stage (Y) after the first stage but before the last stage of kneading, at least two kinds of the chemical agents (D) and (E) are added and kneaded; and, in the last stage (Z) of kneading, a vulcanizing agent is added and kneaded.

  本发明提供了生产橡胶组合物的工艺，通过进一步提高硅烷偶联剂的偶联功能活性，可获得适当低发热量的橡胶组合物。更具体地说，本发明提供了一种生产橡胶组合物的工艺，该橡胶组合物包括至少一种选自天然橡胶和合成二烯橡胶的橡胶组分（A）、一种含有无机填料的填料（B）、一种硅烷偶联剂（C）以及至少两种选自胍类、亚磺酰胺类、噻唑类、噻嗪类、二硫代氨基甲酸乙酯类、二硫代氨基甲酸乙酯类、二硫代氨基甲酸乙酯类、二硫代氨基甲酸乙酯类、二硫代氨基甲酸乙酯类和二硫代氨基甲酸乙酯类的化学剂（D）和（E）、其中，橡胶组合物分多个阶段捏合，在捏合的第一阶段 (X) 中，加入并捏合橡胶组分 (A)、全部或部分无机填料 (B)、全部或部分硅烷偶联剂 (C) 以及至少两种化学剂 (D) 和 (E)。还提供了一种生产橡胶组合物的工艺，其中橡胶组合物的捏合步骤包括三个或三个以上阶段，在捏合的第一阶段（X），捏合橡胶组分（A）、全部或部分无机填料（B）、全部或部分硅烷偶联剂（C）；在第一阶段之后、最后阶段之前的阶段（Y）中，加入并捏合至少两种化学剂（D）和（E）；以及，在最后阶段（Z）中，加入并捏合硫化剂。
• RUBBER COMPOSITION MANUFACTURING METHOD, RUBBER COMPOSITION, AND PNEUMATIC TIRE USING SAME
  申请人：Bridgestone Corporation

  公开号：EP2799467A1

  公开（公告）日：2014-11-05

  The present invention provides a method for producing a rubber composition provided by compounding a rubber component (A) comprising at least one selected from natural rubbers and synthetic diene rubbers, a filler containing an inorganic filler (B), a silane coupling agent (C), and at least one vulcanization accelerator (D) selected from specific compounds, wherein the rubber composition is kneaded in a plurality of stages and wherein, in the first stage (X) of kneading, a portion (A') of the rubber component (A), all or a portion of the inorganic filler (B), all or a portion of the silane coupling agent (C), and all or a portion of the vulcanization accelerator (D) are added and kneaded, and in or after the second stage of kneading, the residual portion (A") of the rubber component (A) is added and kneaded, and the method for producing a rubber composition enables production of a rubber composition capable of suitably having a low-heat-generation property by further improving the coupling function activity of the silane coupling agent therein.

  本发明提供了一种生产橡胶组合物的方法，该方法通过混炼橡胶组分（A）提供，橡胶组分（A）包含至少一种选自天然橡胶和合成二烯橡胶的橡胶、一种包含无机填料（B）的填料、一种硅烷偶联剂（C）和至少一种选自特定化合物的硫化促进剂（D），其中橡胶组合物经过多个阶段混炼，并且其中在混炼的第一阶段（X）中，橡胶组分（A）的一部分（A'）、全部或部分无机填料（B）、全部或部分硅烷偶联剂（C）和全部或部分硫化促进剂（D）被加入、该橡胶组合物生产方法可通过进一步提高其中硅烷偶联剂的偶联功能活性，生产出具有适当低发热特性的橡胶组合物。