dimeric trans-2,5-dihydro-2,5-dimethoxyfuran | 129215-91-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: dimeric trans-2,5-dihydro-2,5-dimethoxyfuran
• 英文别名: 3,5,8,10-tetramethoxy-4,9-dioxatricyclo[5.3.0.02,6]decane
• CAS: 129215-91-4
• 化学式: C₁₂H₂₀O₆
• 分子量: 260.287
• InChiKey: FFDOXSHRNUTNRR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.42
• 重原子数：
  18.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  55.38
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  trans-2,5-Dimethoxy-2,5-dihydro-furan 生成 dimeric trans-2,5-dihydro-2,5-dimethoxyfuran
  参考文献：
  名称：

  MATTAY, JOCHEN;RUMBACH, THOMAS;RUNSINK, JAN, J. ORG. CHEM., 55,(1990) N2, C. 5691-5696

  摘要：

  DOI：

文献信息

• Radical ions and photochemical charge transfer phenomena. 27. Molecular recognition phenomena in the excited state: the meta photocycloaddition of cis- and trans-2,5-dihydro-2,5-dimethoxyfuran and cis-1,4-dimethoxycyclopent-2-ene to anisole
  作者：Jochen Mattay、Thomas Rumbach、Jan Runsink

  DOI：10.1021/jo00309a011

  日期：1990.10
• Thiabowls: synthesis, molecular structure and the solid state architecture of tetrathia-[4]-peristylane
  作者：Goverdhan Mehta、Vanessa Gagliardini、Carsten Schaefer、Rolf Gleiter

  DOI：10.1016/j.tetlet.2003.10.038

  日期：2003.12

  Synthesis of tetrathia-[4]-peristylane, the first thiabowl, from the dimer of cyclooctatetraene has been accomplished. The X-ray crystal structure of the tetrathiabowl indicates significant departure from the expected C-4v symmetry and in the solid state it exhibits a multi-columnar arrangement and a novel 'self-inclusion' phenomenon, directed by a network of S...S and CH...S interactions. (C) 2003 Elsevier Ltd. All rights reserved.