(2R,4S)-4-Methyl-2-nonyl-[1,3]dioxane

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二恶烷
• 英文名称: (2R,4S)-4-Methyl-2-nonyl-[1,3]dioxane
• 英文别名: (2R,4S)-4-methyl-2-nonyl-1,3-dioxane
• 化学式: C₁₄H₂₈O₂
• 分子量: 228.375
• InChiKey: DRHWPDCYULTYSA-UONOGXRCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  癸醛 、 1,3-丁二醇 生成 (2R,4S)-4-Methyl-2-nonyl-[1,3]dioxane
  参考文献：
  名称：

  Mechanism of the Lewis acid mediated cleavage of chiral acetals

  摘要：

  The TiCl4-promoted cleavage of acetals has been shown to proceed by different mechanisms depending on the structure of the acetal, making it difficult to draw firm conclusions about the mechanism of related acetals based on model studies.

  DOI：

  10.1021/jo00037a010

文献信息

• Mechanism of the Lewis acid mediated cleavage of chiral acetals
  作者：Tarek Sammakia、Randall S. Smith

  DOI：10.1021/jo00037a010

  日期：1992.5

  The TiCl4-promoted cleavage of acetals has been shown to proceed by different mechanisms depending on the structure of the acetal, making it difficult to draw firm conclusions about the mechanism of related acetals based on model studies.