1,4-bis(1,1-dimethyl-3-(4-nitrophenyl)-1H-inden-2-yl)benzene | 1418135-94-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1,4-bis(1,1-dimethyl-3-(4-nitrophenyl)-1H-inden-2-yl)benzene
• 英文别名: 2-[4-[1,1-Dimethyl-3-(4-nitrophenyl)inden-2-yl]phenyl]-1,1-dimethyl-3-(4-nitrophenyl)indene；2-[4-[1,1-dimethyl-3-(4-nitrophenyl)inden-2-yl]phenyl]-1,1-dimethyl-3-(4-nitrophenyl)indene
• CAS: 1418135-94-0
• 化学式: C₄₀H₃₂N₂O₄
• 分子量: 604.705
• InChiKey: ZSGOIIDYCVXJNE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.6
• 重原子数：
  46
• 可旋转键数：
  4
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  91.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,4-bis[(2-isopropylphenyl)ethynyl]benzene 、 对硝基苯磺酰氯 在 tris(2,2'-bipyridyl)ruthenium dichloride 、 sodium carbonate 作用下， 以 乙腈 为溶剂， 反应 36.0h， 以32%的产率得到2-(4-((2-isopropylphenyl)ethynyl)phenyl)-1,1-dimethyl-3-(4-nitrophenyl)-1H-indene
  参考文献：
  名称：

  Reusable Visible Light Photoredox Catalysts; Catalyzed Benzylic C(sp3)–H Functionalization/Carbocyclization Reactions

  摘要：

  The C(sp(3))-H functionalization/carbocyclization reaction through the oxidative quenching of visible light photoredox catalysts is established for constructing functionalized 1H-indenes. The process is general for a wide range of benzylic C(sp(3))-H bonds and is highly compatible with common functional groups. Importantly, the visible light photoredox catalysts can be recovered and reused at least three times without loss of catalytic activity.

  DOI：

  10.1055/s-0032-1317349

文献信息

• Reusable Visible Light Photoredox Catalysts; Catalyzed Benzylic C(sp3)–H Functionalization/Carbocyclization Reactions
  作者：Jin-Heng Li、Jia-Dong Xia、Guo-Bo Deng、Ming-Bo Zhou、Wei Liu、Peng Xie

  DOI：10.1055/s-0032-1317349

  日期：——

  The C(sp(3))-H functionalization/carbocyclization reaction through the oxidative quenching of visible light photoredox catalysts is established for constructing functionalized 1H-indenes. The process is general for a wide range of benzylic C(sp(3))-H bonds and is highly compatible with common functional groups. Importantly, the visible light photoredox catalysts can be recovered and reused at least three times without loss of catalytic activity.