1,10-phenanthroline-2-carboxylic acid chloride hydrochloride | 37067-11-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 1,10-phenanthroline-2-carboxylic acid chloride hydrochloride
• 英文别名: 1,10-phenanthroline-2-carbonyl chloride;hydrochloride
• CAS: 37067-11-1
• 化学式: C₁₃H₇ClN₂O*ClH
• 分子量: 279.125
• InChiKey: DGDXIWZJRSLIDR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.58
• 重原子数：
  18.0
• 可旋转键数：
  1.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  42.85
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  1,10-phenanthroline-2-carboxylic acid chloride hydrochloride 在 磷酸 作用下， 生成 1,10-phenanthroline-2-carbonyl phosphate hydrochloride
  参考文献：
  名称：

  Divalent metal ion catalyzed reactions of acyl phosphates

  摘要：

  DOI：

  10.1021/ja00170a020

文献信息

• Synthesis of 2-Benzyl-1,10-phenanthrolines Substituted by Sulfoxide or Sulfone Groups as Potential Photochromic Compounds
  作者：André Samat、Arnault Heynderickx、Robert Guglielmetti

  DOI：10.1055/s-2002-33644

  日期：——

  New 2-benzyl-1,10-phenanthrolines, substituted at the 2′ position by electron-withdrawing groups, were synthesized through nucleophilic substitution involving 2-chloro-1,10-phenanthroline and substituted benzyllithiums, respectively. The expected reversible photoinduced proton transfer reaction of such compounds were studied.

  通过 2-氯-1,10-菲罗啉和取代的苄基锂分别进行亲核取代，合成了新的 2-苄基-1,10-菲罗啉，它们在 2′位被抽电子基团取代。研究了这类化合物的预期可逆光诱导质子转移反应。
• Holan, George; Wernert, Gregory T., Australian Journal of Chemistry, 1987, vol. 40, # 5, p. 873 - 881
  作者：Holan, George、Wernert, Gregory T.

  DOI：——

  日期：——
• An alcohol recognition motif: Clear evidence of binding site cooperativity in the complexation of cyclohexanediols by neutral polyaza-clefts
  作者：Dwayne A. Bell、Sylvia G. Díaz、Vincent M. Lynch、Eric V. Anslyn

  DOI：10.1016/0040-4039(95)00715-o

  日期：1995.6

  A polyaza-cleft is found to bind a variety of alcohol functional groups via two hydrogen bonds. The tethering of two clefts yields cooperativity between binding sites.
• Divalent metal ion catalyzed reactions of acyl phosphates
  作者：Thomas H. Fife、Mahesh P. Pujari

  DOI：10.1021/ja00170a020

  日期：1990.7