diallyl ethane-1,2-diylbis(oxy)bis(ethane-2,1-diyl) bis(carbonate) | 61685-96-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: diallyl ethane-1,2-diylbis(oxy)bis(ethane-2,1-diyl) bis(carbonate)
• 英文别名: 2,5,8,11-tetraoxa-dodecanedioic acid diallyl ester；2,5,8,11-Tetraoxa-dodecandisaeure-diallylester；Triaethylenglykol-bis-allylcarbonat；2-[2-(2-Prop-2-enoxycarbonyloxyethoxy)ethoxy]ethyl prop-2-enyl carbonate
• CAS: 61685-96-9
• 化学式: C₁₄H₂₂O₈
• 分子量: 318.324
• InChiKey: PKCFRBDMMFCGIW-UHFFFAOYSA-N

物化性质

• 沸点：
  384.3±42.0 °C(Predicted)
• 密度：
  1.131-1.140 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  22
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  89.5
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  氯甲酸烯丙酯 、 三乙二醇 在 吡啶 作用下， 生成 diallyl ethane-1,2-diylbis(oxy)bis(ethane-2,1-diyl) bis(carbonate)
  参考文献：
  名称：

  Preparation of carbonic acid esters

  摘要：

  公开号：

  US02370567A1

文献信息

• Introducing the reversible chemistry of CO₂ with diols mediated by organic superbases into polycarbonate synthesis
  作者：Yang Chai、Qin Chen、Caijuan Huang、Qiang Zheng、Michael North、Haibo Xie

  DOI：10.1039/d0gc01197e

  日期：——

  The reversible reaction of CO₂ with alcohols mediated by organic superbases was firstly developed to be a toolbox for capturing CO₂ into polymerizable carbonate monomers applicable for thiol–ene click and ADMET polymerization to produce new libraries of polycarbonates.

  CO2与醇类通过有机超碱介导的可逆反应首次被开发成为一个工具箱，用于将 捕获到可聚合的碳酸酯单体中，适用于硫醇-烯烃点击和ADMET聚合，以生产新的聚碳酸酯库。
• Method for Preparing a Colloidal Zirconia Solution
  申请人：Chaput Frederic

  公开号：US20100144918A1

  公开（公告）日：2010-06-10

  A method for preparing a colloidal solution of non-aggregated zirconia particles, comprising the following steps: a) providing a zirconium hydroxide sol, b) adding to said sol an inorganic acid according to an [inorganic acid]/[Zr] molar ratio of <0.5, c) performing the hydrothermal treatment of said sol, and d) recovering the colloidal solution of zirconia particles.

  一种制备非聚集氧化锆颗粒胶体溶液的方法，包括以下步骤：a)提供氢氧化锆溶胶，b)向所述溶胶中添加无机酸，使其[inorganic acid]/[Zr]摩尔比小于0.5，c)对所述溶胶进行水热处理，d)回收氧化锆颗粒的胶体溶液。
• Compounds That Absorb Ultraviolet Light, Methods of Their Preparation and Optical Lenses Containing Them
  申请人：Kauffman Joel M.

  公开号：US20080064880A1

  公开（公告）日：2008-03-13

  Compounds that absorb ultraviolet light 380 nm to 400 nm range but avoid absorption in the blue light range, thereby imparting yellowness, i.e., 410-420 nm have suitable refractive characteristics useful in the preparation of optical resins or plastics suitable, for example, for the manufacture of ophthalmic lenses. Methods for making the compounds, optic lenses containing the compounds, and methods for making these are also described.

  吸收紫外光380nm到400nm范围内的化合物，但避免在蓝光范围内吸收，从而赋予黄色，即410-420nm具有适合制备光学树脂或塑料的折射特性，例如，用于制造眼科透镜。还描述了制备这些化合物的方法，含有这些化合物的光学透镜以及制造这些化合物的方法。
• ALDIMINES AND COMPOSITIONS COMPRISING ALDIMINE
  申请人：Burckhardt Urs

  公开号：US20100101455A1

  公开（公告）日：2010-04-29

  The present invention relates in a first consideration to aldimines of formula (I). Said aldimines are particularly suitable as latent hardeners in curable compositions, particularly compositions comprising one or two-component isocyanate groups. Due to the presence of the reactive group, they can be converted to compounds of the formulas (X) and (XII) comprising aldimine groups, implementing a further consideration of the present invention. The aldimines, or the compounds comprising aldimine groups, can be used primarily in adhesive and sealant materials, but also in coatings, and can be produced easily from readily available source materials, and have good thermal stability. The tertiary amino group thereof has a surprisingly low alkalinity and can in some cases have a catalytic effect in chemical reaction systems.

  本发明涉及公式(I)的醛胺，首先考虑这些醛胺作为可固化组合物的潜在固化剂，特别是含有一种或两种异氰酸基团的组合物。由于具有反应性基团，它们可以转化为公式(X)和(XII)的化合物，包括醛胺基团，这是本发明的进一步考虑。这些醛胺或含有醛胺基团的化合物主要可用于粘合剂和密封材料，也可用于涂料，并且可以从易得的原料中轻松制备，并具有良好的热稳定性。其中的三级氨基具有惊人的低碱度，在某些情况下可以在化学反应系统中具有催化作用。
• Methods for Making an Article Coated with a Photochromic Film and Use Thereof in Ophthalmological Optics
  申请人：Biteau John

  公开号：US20130108858A1

  公开（公告）日：2013-05-02

  The present invention relates to a method for making a substrate coated with a mesoporous photochromic film, comprising: a) preparing a precursor sol of a mesoporous film comprising an inorganic precursor agent, at least one organic solvent, water, at least one pore-forming agent and one hydrophobic precursor agent bearing at least one hydrophobic group; b) depositing a film of the precursor sol onto a main surface of a substrate; c) removing the pore-forming agent from the film resulting from the previous step at a temperature ≦150° C.; d) impregnating the mesoporous film resulting from step c) with a solution comprising at least one photochromic agent. In an alternative embodiment, the photochromic agent is directly introduced into the precursor sol. In an alternative embodiment of the previous alternative embodiment, the precursor sol does not comprise any hydrophobic precursor agent but the photochromic film is made hydrophobic by a treatment subsequent to its preparation.

  本发明涉及一种制备涂有介孔光致变色薄膜的基板的方法，包括：a）制备介孔膜的前体溶胶，该溶胶包括无机前体剂、至少一种有机溶剂、水、至少一种孔形成剂和至少一种带有至少一个疏水基团的疏水前体剂；b）将前体溶胶的薄膜沉积到基板的主表面上；c）在温度≤150℃下从前一步得到的膜中去除孔形成剂；d）用至少一种光致变色剂的溶液浸渍由步骤c）得到的介孔膜。在另一实施例中，光致变色剂直接引入前体溶胶中。在前一种另一实施例中，前体溶胶不包括任何疏水前体剂，但是在其制备后通过处理使光致变色薄膜疏水。