tetrakis(dimethyldithiocarbamato)tin(IV)

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tetrakis(dimethyldithiocarbamato)tin(IV)
• 英文别名: tris(dimethylcarbamothioylsulfanyl)stannyl N,N-dimethylcarbamodithioate
• 化学式: C₁₂H₂₄N₄S₈Sn
• 分子量: 599.587
• InChiKey: DDNRCFPUXYQECR-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  1.14
• 重原子数：
  25
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  145
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  tin 、 福美双 以 甲苯 为溶剂， 以90%的产率得到tetrakis(dimethyldithiocarbamato)tin(IV)
  参考文献：
  名称：

  COORDINATION COMPOUNDS OF TIN AND BISMUTH. COMPLEXES OF TIN(IV) AND BISMUTH(III) WITH N,N-DIALKYLDITHIOCARBAMATES

  摘要：

  Tin and bismuth metals react with N,N,N,N'-tetraethylthiuramdisulfide, [Et2NC(S)S](2), and N,N,N',N'-tetramcthylthiuramdisulfide, [Mt(2)NC(S)S](2), in refluxing toluene to give the compounds Sn(S2CNR2)(4) (R=Et, Me) in high yield. Under similar conditions bismuth gives Bi(S2CNR2)(3). The reaction of metallic tin with a mixture of iodine and [R2NC(S)S](2) gives the compounds SnI(S2CNR2)(3) and SnI2(S2CNR2)(2). Similarly, with mixtures of [R2NC(S)S](2) and I-2, bismuth yields BiI(S2CNR2)(2) and BiI2(S2CNR2). Adducts of Bi(S2CNR2)(3) with 1,10-phenanthroline and 2.2'-bipyridyl were also prepared. The compounds and adducts were characterized by microanalyses, infrared, UV/Visible spectroscopy and conductivity measurements.

  DOI：

  10.1081/sim-100104783

文献信息

• The electrochemical synthesis of O-ethylxanthato and N,N′-dimethyldithiocarbamato complexes of indium(III), tin(IV), lead(II), bismuth(III) and tellurium(IV)
  作者：Allan T. Casey、Angelica M. Vecchio

  DOI：10.1016/s0020-1693(00)96023-7

  日期：1987.8
• COORDINATION COMPOUNDS OF TIN AND BISMUTH. COMPLEXES OF TIN(IV) AND BISMUTH(III) WITH N,N-DIALKYLDITHIOCARBAMATES
  作者：I. A. Mustafa、Amer A. Taqa

  DOI：10.1081/sim-100104783

  日期：2001.4.30

  Tin and bismuth metals react with N,N,N,N'-tetraethylthiuramdisulfide, [Et2NC(S)S](2), and N,N,N',N'-tetramcthylthiuramdisulfide, [Mt(2)NC(S)S](2), in refluxing toluene to give the compounds Sn(S2CNR2)(4) (R=Et, Me) in high yield. Under similar conditions bismuth gives Bi(S2CNR2)(3). The reaction of metallic tin with a mixture of iodine and [R2NC(S)S](2) gives the compounds SnI(S2CNR2)(3) and SnI2(S2CNR2)(2). Similarly, with mixtures of [R2NC(S)S](2) and I-2, bismuth yields BiI(S2CNR2)(2) and BiI2(S2CNR2). Adducts of Bi(S2CNR2)(3) with 1,10-phenanthroline and 2.2'-bipyridyl were also prepared. The compounds and adducts were characterized by microanalyses, infrared, UV/Visible spectroscopy and conductivity measurements.