1,3-dihydroxy-5-[10(Z)-pentadecenyl]benzene | 52483-20-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 1,3-dihydroxy-5-[10(Z)-pentadecenyl]benzene
• 英文别名: (Z)-5-(pentadec-10-enyl)benzene-1,3-diol；5-[(Z)-pentadecyl-10-enyl] resorcinol；5-(10'Z-pentadecenyl)resorcinol；5-(10Z-pentadecenyl)-resorcinol；5-(pentadec-10Z-enyl)resorcinol；5-((Z)-pentadec-10-en-1-yl)resorcinol；5-[(Z)-pentadec-10-enyl]benzene-1,3-diol
• CAS: 52483-20-2
• 化学式: C₂₁H₃₄O₂
• 分子量: 318.5
• InChiKey: BGXAZEDJUHQDEM-WAYWQWQTSA-N

物化性质

• 沸点：
  452.2±15.0 °C(Predicted)
• 密度：
  0.973±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  23
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,3-dihydroxy-5-[10(Z)-pentadecenyl]benzene 在 碘 作用下， 以 乙醚 为溶剂， 反应 26.0h， 生成
  参考文献：
  名称：

  Characterisation of triterpenes and new phenolic lipids in Cameroonian propolis

  摘要：

  Chemical investigation of a sample of propolis originating from North-Western Cameroon led to the isolation of thirteen alk(en)ylphenols (1-13) (inseparable mixture) along with alpha-amyrin (14), beta-amyrin (15), lupeol (16), cycloartenol (17), mangiferonic acid (18), ambonic acid (19), mangiferolic acid (20), ambolic acid (21), isomangiferolic acid (22) and nine alk(en)ylresorcinols (23-31) (inseparable mixture). All compounds were identified following analysis of their spectroscopic data and comparison with previously published reports. Compounds (8), (12), (13) and (30) are new natural products. GC-MS analysis carried out on the alk(en)ylphenol and alk(en)ylresorcinol mixtures (dimethyl disulphide trimethylsilyl derivatives) revealed the presence of saturated and mono-unsaturated compounds with side chain lengths ranging from C11 to C19 and C15 to C19, respectively. The position of the double bond in mono-unsaturated derivatives was established from the characteristic fragments resulting from the cleavage of the bond between the two methylthio-substituted carbons. The most abundant compound in each mixture was 3-(12'Z-heptadecenyl)-phenol (10) and 5-(12'Z-heptadecenyl)-resorcinol (29). This study is the first to report the presence of triterpenes (except for lupeol) and phenolic lipids, including eighteen compounds previously unreported in bee glue, in an African sample. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.phytochem.2014.07.016

文献信息

• REDUCED SODIUM FOOD PRODUCT
  申请人：GENERAL MILLS, INC.

  公开号：EP3466930A1

  公开（公告）日：2019-04-10

  The present invention relates to the use of a compound according to Formula B3: where: R1 and R2 are each independently OH or C1-C3 alkoxy, and R3 is selected from the group consisting of (i) C10-C20 unsubstituted straight or branched chain alkenyl with one or more double bonds; and (ii) where X, Y and Z are independently CH, CH2, CO or CHOR5 where R5 is H or C1-C3 alkyl, provided that if one of X or Y are CH then Z is also CH, and where R4 is C1-C8 straight or branched chain unsubstituted alkyl or where n is 1-5, provided that if R4 is C1-C8 straight or branched chain alkyl, then Y is CHOR5 where R5 is C1-C3 alkyl; for substituting sodium chloride in food products.

  本发明涉及根据式 B3 所述化合物的用途： 其中 R1 和 R2 各自独立地为 OH 或 C1-C3 烷氧基，以及 R3 选自以下组别 (i) 具有一个或多个双键的 C10-C20 未取代直链或支链烯基；和 (ii) 其中 X、Y 和 Z 独立地为 CH、CH2、CO 或 CHOR5，其中 R5 为 H 或 C1-C3 烷基，但如果 X 或 Y 之一为 CH，则 Z 也为 CH，且其中 R4 为 C1-C8 未取代的直链或支链烷基，或 其中 n 为 1-5，但如果 R4 为 C1-C8 直链或支链烷基，则 Y 为 CHOR5，其中 R5 为 C1-C3 烷基； 用于替代食品中的氯化钠。
• REDUCED SODIUM FOOD PRODUCTS
  申请人：GENERAL MILLS, INC.

  公开号：EP2954037B1

  公开（公告）日：2018-04-11
• [EN] USE OF CERTAIN TRIOXYGENATED BENZENE DERIVATIVES IN BODY FAT MANAGEMENT<br/>[FR] UTILISATION DE CERTAINS DÉRIVÉS DE BENZÈNE TRIOXIGÉNÉ DANS LA GESTION DE GRAISSE CORPORELLE
  申请人：BIOTROPICS MALAYSIA BERHAD

  公开号：WO2013112040A1

  公开（公告）日：2013-08-01

  The invention primarily relates to the use of certain trioxygenated benzene derivatives of formula (I) or a corresponding plant extract as body fat modulating agents, preferably as anti-cellulite actives and/or for the reduction of the body fat content, in particular for reduction of body weight and/or for the management of obesity. The present invention also relates to corresponding methods and to certain novel compounds of formula (I). The invention further relates to specific plant extract formulations obtainable from a plant of the family Myrsinaceae, preferably from the genus Labisia, and to compositions, in particular cosmetic or pharmaceutical formulations, comprising an effective amount of one or more compounds of formula (I) or of a corresponding plant extract formulation.
• Characterisation of triterpenes and new phenolic lipids in Cameroonian propolis
  作者：M.N. Kardar、T. Zhang、G.D. Coxon、D.G. Watson、J. Fearnley、V. Seidel

  DOI：10.1016/j.phytochem.2014.07.016

  日期：2014.10

  Chemical investigation of a sample of propolis originating from North-Western Cameroon led to the isolation of thirteen alk(en)ylphenols (1-13) (inseparable mixture) along with alpha-amyrin (14), beta-amyrin (15), lupeol (16), cycloartenol (17), mangiferonic acid (18), ambonic acid (19), mangiferolic acid (20), ambolic acid (21), isomangiferolic acid (22) and nine alk(en)ylresorcinols (23-31) (inseparable mixture). All compounds were identified following analysis of their spectroscopic data and comparison with previously published reports. Compounds (8), (12), (13) and (30) are new natural products. GC-MS analysis carried out on the alk(en)ylphenol and alk(en)ylresorcinol mixtures (dimethyl disulphide trimethylsilyl derivatives) revealed the presence of saturated and mono-unsaturated compounds with side chain lengths ranging from C11 to C19 and C15 to C19, respectively. The position of the double bond in mono-unsaturated derivatives was established from the characteristic fragments resulting from the cleavage of the bond between the two methylthio-substituted carbons. The most abundant compound in each mixture was 3-(12'Z-heptadecenyl)-phenol (10) and 5-(12'Z-heptadecenyl)-resorcinol (29). This study is the first to report the presence of triterpenes (except for lupeol) and phenolic lipids, including eighteen compounds previously unreported in bee glue, in an African sample. (C) 2014 Elsevier Ltd. All rights reserved.